Long-range magnetic order and interchain interactions in the chain system (bpy)
Abstract
Here, a compound with very weakly interacting chains, MnCl3(bpy), has attracted a great deal of attention as a possible Haldane chain. However, long-range magnetic order of the chains prevents the Haldane gap from developing below 11.5 K. Based on a four-sublattice model, a description of the antiferromagnetic resonance (AFMR) spectrum up to frequencies of 1.5 THz and magnetic fields up to 50 T indicates that the interchain coupling is indeed quite small but that the Dzaloshinskii-Moriya interaction produced by broken inversion symmetry is substantial (0.12 meV). In addition, the antiferromagnetic, nearest-neighbor interaction within each chain (3.3 meV) is significantly stronger than previously reported. The excitation spectrum of this compound is well described by a 1/S expansion about the classical limit.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Osaka Univ., Osaka (Japan)
- Univ. of Florida, Gainesville, FL (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1330539
- Alternate Identifier(s):
- OSTI ID: 1327070
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 94; Journal Issue: 10; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Fishman, Randy S., Shinozaki, Shin-ichi, Okutani, Akira, Yoshizawa, Daichi, Kida, Takanori, Hagiwara, Masayuki, and Meisel, Mark W. Long-range magnetic order and interchain interactions in the S=2 chain system MnCl3 (bpy). United States: N. p., 2016.
Web. doi:10.1103/PhysRevB.94.104435.
Fishman, Randy S., Shinozaki, Shin-ichi, Okutani, Akira, Yoshizawa, Daichi, Kida, Takanori, Hagiwara, Masayuki, & Meisel, Mark W. Long-range magnetic order and interchain interactions in the S=2 chain system MnCl3 (bpy). United States. https://doi.org/10.1103/PhysRevB.94.104435
Fishman, Randy S., Shinozaki, Shin-ichi, Okutani, Akira, Yoshizawa, Daichi, Kida, Takanori, Hagiwara, Masayuki, and Meisel, Mark W. 2016.
"Long-range magnetic order and interchain interactions in the S=2 chain system MnCl3 (bpy)". United States. https://doi.org/10.1103/PhysRevB.94.104435. https://www.osti.gov/servlets/purl/1330539.
@article{osti_1330539,
title = {Long-range magnetic order and interchain interactions in the S=2 chain system MnCl3 (bpy)},
author = {Fishman, Randy S. and Shinozaki, Shin-ichi and Okutani, Akira and Yoshizawa, Daichi and Kida, Takanori and Hagiwara, Masayuki and Meisel, Mark W.},
abstractNote = {Here, a compound with very weakly interacting chains, MnCl3(bpy), has attracted a great deal of attention as a possible S=2 Haldane chain. However, long-range magnetic order of the chains prevents the Haldane gap from developing below 11.5 K. Based on a four-sublattice model, a description of the antiferromagnetic resonance (AFMR) spectrum up to frequencies of 1.5 THz and magnetic fields up to 50 T indicates that the interchain coupling is indeed quite small but that the Dzaloshinskii-Moriya interaction produced by broken inversion symmetry is substantial (0.12 meV). In addition, the antiferromagnetic, nearest-neighbor interaction within each chain (3.3 meV) is significantly stronger than previously reported. The excitation spectrum of this S=2 compound is well described by a 1/S expansion about the classical limit.},
doi = {10.1103/PhysRevB.94.104435},
url = {https://www.osti.gov/biblio/1330539},
journal = {Physical Review B},
issn = {2469-9950},
number = 10,
volume = 94,
place = {United States},
year = {Wed Sep 28 00:00:00 EDT 2016},
month = {Wed Sep 28 00:00:00 EDT 2016}
}
Web of Science
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Works referencing / citing this record:
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