Quantum Coherence and Temperature Dependence of the Anomalous State of Nanoconfined Water in Carbon Nanotubes

Reiter, George F.; Deb, Aniruddha; Sakurai, Y.; Itou, M.; Kolesnikov, A. I.

doi:10.1021/acs.jpclett.6b02057

Title: Quantum Coherence and Temperature Dependence of the Anomalous State of Nanoconfined Water in Carbon Nanotubes

Journal Article · Sun Oct 30 00:00:00 EDT 2016 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.6b02057· OSTI ID:1330471

Reiter, George F. ^[1]; Deb, Aniruddha ^[2]; Sakurai, Y. ^[3]; Itou, M. ^[3]; Kolesnikov, A. I. ^[4]

Physics Department, University of Houston, Houston, Texas 77204, United States
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States
Japan Synchrotron Radiation Research Institute (JASRI)/SPring-8, Sayo-cho, Hyogo 679-5198, Japan
Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States

X-ray Compton scattering measurements of the electron momentum distribution in water confined in both single-walled and double-walled carbon nanotubes (SWNT and DWNT), as a function of temperature and confinement size are presented here together with earlier measurements of the proton momentum distribution in the same systems using neutron Compton scattering. These studies provide a coherent picture of an anomalous state of water that exists because of nanoconfinement. This state cannot be described by the weakly interacting molecule picture. It has unique transport properties for both protons and water molecules. Furthermore, we suggest that knowledge of the excitation spectrum of this state is needed to understand the enhanced flow of water in cylinders with diameters on the order of 20 Å.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Michigan, Ann Arbor, MI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-08ER46486; AC05-00OR22725

OSTI ID:: 1330471

Alternate ID(s):: OSTI ID: 1330556; OSTI ID: 1334167

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Vol. 7 Journal Issue: 22; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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References (17)

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