Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions

Tang, Wan Si; Unemoto, Atsushi; Zhou, Wei; Stavila, Vitalie; Matsuo, Motoaki; Wu, Hui; Orimo, Shin-ichi; Udovic, Terrence J.

doi:10.1039/c5ee02941d

Title: Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions

Journal Article · Thu Oct 08 00:00:00 EDT 2015 · Energy & Environmental Science

DOI:https://doi.org/10.1039/c5ee02941d· OSTI ID:1327910

Tang, Wan Si ^[1]; Unemoto, Atsushi ^[2]; Zhou, Wei ^[3]; Stavila, Vitalie ^[4]; Matsuo, Motoaki ^[2]; Wu, Hui ^[3]; Orimo, Shin-ichi ^[2]; Udovic, Terrence J. ^[3]

National Institute of Standards and Technology, Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States)
Tohoku Univ., Sendai (Japan)
National Institute of Standards and Technology, Gaithersburg, MD (United States)
Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Solid electrolytes with sufficiently high conductivities and stabilities are the elusive answer to the inherent shortcomings of organic liquid electrolytes prevalent in today's rechargeable batteries. We recently revealed a novel fast-ion-conducting sodium salt, Na₂B₁₂H₁₂, which contains large, icosahedral, divalent B₁₂H₁₂^2– anions that enable impressive superionic conductivity, albeit only above its 529 K phase transition. Its lithium congener, Li₂B₁₂H₁₂, possesses an even more technologically prohibitive transition temperature above 600 K. Here we show that the chemically related LiCB₁₁H₁₂ and NaCB₁₁H₁₂ salts, which contain icosahedral, monovalent CB₁₁H₁₂– anions, both exhibit much lower transition temperatures near 400 K and 380 K, respectively, and truly stellar ionic conductivities (>0.1 S cm^–1) unmatched by any other known polycrystalline materials at these temperatures. Furthermore with proper modifications, we are confident that room-temperature-stabilized superionic salts incorporating such large polyhedral anion building blocks are attainable, thus enhancing their future prospects as practical electrolyte materials in next-generation, all-solid-state batteries.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1327910

Report Number(s):: SAND-2016-9600J; EESNBY; 647755

Journal Information:: Energy & Environmental Science, Vol. 8, Issue 12; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 204 works

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