Three-dimensional PtNi hollow nanochains as an enhanced electrocatalyst for the oxygen reduction reaction

Fu, Shaofang; Zhu, Chengzhou; Song, Junhua; Engelhard, Mark H.; He, Yang; Du, Dan; Wang, Chongmin; Lin, Yuehe

doi:10.1039/C6TA01801G

Title: Three-dimensional PtNi hollow nanochains as an enhanced electrocatalyst for the oxygen reduction reaction

Journal Article · Thu May 05 00:00:00 EDT 2016 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C6TA01801G· OSTI ID:1327101

Fu, Shaofang ^[1]; Zhu, Chengzhou ^[1]; Song, Junhua ^[1]; Engelhard, Mark H. ^[2]; He, Yang ^[3]; Du, Dan ^[1]; Wang, Chongmin ^[2]; Lin, Yuehe ^[4]

Washington State Univ., Pullman, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Univ. of Pittsburgh, PA (United States)
Washington State Univ., Pullman, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Three-dimensional porous PtNi hollow nanochains were successfully synthesized via a galvanic replacement method using Ni nanosponges as sacrificial templates in an aqueous solution. It is found that the composition and shell thickness of 3D PtNi hollow nanochains can be easily controlled by tuning the concentration of Pt precursors. The as-prepared PtNi hollow nanochains with an optimized composition present a high electrochemical surface area (70.8 m² g^–1), which is close to that of commercial Pt/C (83 m² g^–1). Moreover, the PtNi catalyst with a Pt content of ~77% presents superior electrocatalytic performance for the oxygen reduction reaction compared to commercial Pt/C. It shows a mass activity of 0.58 A mg_Pt^–1, which is around 3 times higher than that of Pt/C. Lastly, this strategy may be extended to the preparation of other multimetallic nanocrystals with 3D hollow nanostructures, which are expected to present high catalytic properties.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1327101

Report Number(s):: PNNL-SA-116320; JMCAET; 48877; 48920; KP1704020

Journal Information:: Journal of Materials Chemistry. A, Vol. 4, Issue 22; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 57 works

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References (45)

Porous Dendritic Platinum Nanotubes with Extremely High Activity and Stability for Oxygen Reduction Reaction Zhang, Gaixia; Sun, Shuhui; Cai, Mei Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep01526	journal	March 2013
Function-Led Design of Aerogels: Self-Assembly of Alloyed PdNi Hollow Nanospheres for Efficient Electrocatalysis Cai, Bin; Wen, Dan; Liu, Wei Angewandte Chemie International Edition, Vol. 54, Issue 44 https://doi.org/10.1002/anie.201505307	journal	September 2015
Size-Controlled Synthesis of Platinum-Copper Hierarchical Trigonal Bipyramid Nanoframes Chen, Sheng; Su, Hongyang; Wang, Youcheng Angewandte Chemie International Edition, Vol. 54, Issue 1 https://doi.org/10.1002/anie.201408399	journal	October 2014
Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure Stamenkovic, Vojislav; Mun, Bongjin Simon; Mayrhofer, Karl J. J. Angewandte Chemie International Edition, Vol. 45, Issue 18 https://doi.org/10.1002/anie.200504386	journal	April 2006
A graphene–platinum nanoparticles–ionic liquid composite catalyst for methanol-tolerant oxygen reduction reaction Tan, Yueming; Xu, Chaofa; Chen, Guangxu Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21411c	journal	January 2012
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction Nie, Yao; Li, Li; Wei, Zidong Chemical Society Reviews, Vol. 44, Issue 8 https://doi.org/10.1039/C4CS00484A	journal	January 2015
Porous Platinum Nanotubes for Oxygen Reduction and Methanol Oxidation Reactions Alia, Shaun M.; Zhang, Gang; Kisailus, David Advanced Functional Materials, Vol. 20, Issue 21 https://doi.org/10.1002/adfm.201001035	journal	October 2010
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces Chen, C.; Kang, Y.; Huo, Z. Science, Vol. 343, Issue 6177 https://doi.org/10.1126/science.1249061	journal	February 2014
Ordered Mesoporous Platinum@Graphitic Carbon Embedded Nanophase as a Highly Active, Stable, and Methanol-Tolerant Oxygen Reduction Electrocatalyst Wu, Zhangxiong; Lv, Yingying; Xia, Yongyao Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja209753w	journal	January 2012
Mixed-Metal Pt Monolayer Electrocatalysts for Enhanced Oxygen Reduction Kinetics Zhang, Junliang; Vukmirovic, Miomir B.; Sasaki, Kotaro Journal of the American Chemical Society, Vol. 127, Issue 36 https://doi.org/10.1021/ja053695i	journal	September 2005
Polymeric Micelle Assembly for the Smart Synthesis of Mesoporous Platinum Nanospheres with Tunable Pore Sizes Li, Yunqi; Bastakoti, Bishnu Prasad; Malgras, Victor Angewandte Chemie International Edition, Vol. 54, Issue 38 https://doi.org/10.1002/anie.201505232	journal	August 2015
Ultrasonic enhanced synthesis of multi-walled carbon nanotube supported Pt–Co bimetallic nanoparticles as catalysts for the oxygen reduction reaction Fu, Shaofang; Yang, Guohai; Zhou, Yazhou RSC Advances, Vol. 5, Issue 41 https://doi.org/10.1039/C5RA02549D	journal	January 2015
A Facile Strategy to Pt ₃ Ni Nanocrystals with Highly Porous Features as an Enhanced Oxygen Reduction Reaction Catalyst Huang, Xiaoqing; Zhu, Enbo; Chen, Yu Advanced Materials, Vol. 25, Issue 21 https://doi.org/10.1002/adma.201205315	journal	April 2013
Highly efficient nonprecious metal catalysts towards oxygen reduction reaction based on three-dimensional porous carbon nanostructures Zhu, Chengzhou; Li, He; Fu, Shaofang Chemical Society Reviews, Vol. 45, Issue 3 https://doi.org/10.1039/C5CS00670H	journal	January 2016
Platinum-Coated Palladium Nanotubes as Oxygen Reduction Reaction Electrocatalysts Alia, Shaun M.; Jensen, Kurt O.; Pivovar, Bryan S. ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs200682c	journal	April 2012
Engineering Ordered and Nonordered Porous Noble Metal Nanostructures: Synthesis, Assembly, and Their Applications in Electrochemistry Zhu, Chengzhou; Du, Dan; Eychmüller, Alexander Chemical Reviews, Vol. 115, Issue 16 https://doi.org/10.1021/acs.chemrev.5b00255	journal	July 2015
A Highly Durable Platinum Nanocatalyst for Proton Exchange Membrane Fuel Cells: Multiarmed Starlike Nanowire Single Crystal Sun, Shuhui; Zhang, Gaixia; Geng, Dongsheng Angewandte Chemie International Edition, Vol. 50, Issue 2 https://doi.org/10.1002/anie.201004631	journal	November 2010
Large-Scale Aqueous Synthesis and Growth Mechanism of Single-Crystalline Metal Nanoscrolls at Room Temperature: The Case of Nickel Zhang, Gaixia; Sun, Shuhui; Li, Ruying Chemistry of Materials, Vol. 22, Issue 16 https://doi.org/10.1021/cm101662z	journal	August 2010
Bimetallic Aerogels: High-Performance Electrocatalysts for the Oxygen Reduction Reaction Liu, Wei; Rodriguez, Paramaconi; Borchardt, Lars Angewandte Chemie International Edition, Vol. 52, Issue 37 https://doi.org/10.1002/anie.201303109	journal	July 2013
25th Anniversary Article: Galvanic Replacement: A Simple and Versatile Route to Hollow Nanostructures with Tunable and Well-Controlled Properties Xia, Xiaohu; Wang, Yi; Ruditskiy, Aleksey Advanced Materials, Vol. 25, Issue 44 https://doi.org/10.1002/adma.201302820	journal	September 2013
Mechanistic Studies on the Galvanic Replacement Reaction between Multiply Twinned Particles of Ag and HAuCl₄ in an Organic Medium Lu, Xianmao; Tuan, Hsing-Yu; Chen, Jingyi Journal of the American Chemical Society, Vol. 129, Issue 6, p. 1733-1742 https://doi.org/10.1021/ja067800f	journal	February 2007
Mixing Does the Magic: A Rapid Synthesis of High Surface Area Noble Metal Nanosponges Showing Broadband Nonlinear Optical Response Krishna, Katla Sai; Sandeep, C. S. Suchand; Philip, Reji ACS Nano, Vol. 4, Issue 5 https://doi.org/10.1021/nn100320s	journal	March 2010
Challenges of modelling real nanoparticles: Ni@Pt electrocatalysts for the oxygen reduction reaction Ramos-Sanchez, G.; Praserthdam, S.; Godinez-Salomon, F. Physical Chemistry Chemical Physics, Vol. 17, Issue 42 https://doi.org/10.1039/C5CP00503E	journal	January 2015
Platinum Multicubes Prepared by Ni ²⁺ -Mediated Shape Evolution Exhibit High Electrocatalytic Activity for Oxygen Reduction Ma, Liang; Wang, Chengming; Xia, Bao Yu Angewandte Chemie International Edition, Vol. 54, Issue 19 https://doi.org/10.1002/anie.201500947	journal	March 2015
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias Nature Materials, Vol. 6, Issue 3, p. 241-247 https://doi.org/10.1038/nmat1840	journal	February 2007
Nickel cobalt oxide hollow nanosponges as advanced electrocatalysts for the oxygen evolution reaction Zhu, Chengzhou; Wen, Dan; Leubner, Susanne Chemical Communications, Vol. 51, Issue 37 https://doi.org/10.1039/C5CC01558H	journal	January 2015
Pt-Based Icosahedral Nanocages: Using a Combination of {111} Facets, Twin Defects, and Ultrathin Walls to Greatly Enhance Their Activity toward Oxygen Reduction Wang, Xue; Figueroa-Cosme, Legna; Yang, Xuan Nano Letters, Vol. 16, Issue 2 https://doi.org/10.1021/acs.nanolett.5b05140	journal	January 2016
Tuning the oxygen reduction activity of the Pt–Ni nanoparticles upon specific anion adsorption by varying heat treatment atmospheres Chung, Young-Hoon; Kim, Soo Jin; Chung, Dong Young Physical Chemistry Chemical Physics, Vol. 16, Issue 27 https://doi.org/10.1039/c4cp00187g	journal	January 2014
FePt Nanoparticles Assembled on Graphene as Enhanced Catalyst for Oxygen Reduction Reaction Guo, Shaojun; Sun, Shouheng Journal of the American Chemical Society, Vol. 134, Issue 5 https://doi.org/10.1021/ja2104334	journal	January 2012
Facile One-Step Synthesis of Three-Dimensional Pd–Ag Bimetallic Alloy Networks and Their Electrocatalytic Activity toward Ethanol Oxidation Fu, Shaofang; Zhu, Chengzhou; Du, Dan ACS Applied Materials & Interfaces, Vol. 7, Issue 25 https://doi.org/10.1021/acsami.5b01963	journal	June 2015
Advanced Platinum Alloy Electrocatalysts for the Oxygen Reduction Reaction Wang, Chao; Markovic, Nenad M.; Stamenkovic, Vojislav R. ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs3000792	journal	April 2012
Recent progress in nanostructured electrocatalysts for PEM fuel cells Zhang, Sheng; Shao, Yuyan; Yin, Geping Journal of Materials Chemistry A, Vol. 1, Issue 15 https://doi.org/10.1039/c3ta01161e	journal	January 2013
Kinetically Controlled Synthesis of PdNi Bimetallic Porous Nanostructures with Enhanced Electrocatalytic Activity Zhu, Chengzhou; Wen, Dan; Oschatz, Martin Small, Vol. 11, Issue 12 https://doi.org/10.1002/smll.201401432	journal	October 2014
Displacement Plating of a Mesoporous Pt Skin onto Co Nanochains in a Low-Concentration Surfactant Solution Li, Cuiling; Imura, Masataka; Yamauchi, Yusuke Chemistry - A European Journal, Vol. 20, Issue 12 https://doi.org/10.1002/chem.201303250	journal	February 2014
Tuning the Performance and the Stability of Porous Hollow PtNi/C Nanostructures for the Oxygen Reduction Reaction Dubau, Laetitia; Asset, Tristan; Chattot, Raphaël ACS Catalysis, Vol. 5, Issue 9 https://doi.org/10.1021/acscatal.5b01248	journal	August 2015
Scalable Bromide-Triggered Synthesis of Pd@Pt Core–Shell Ultrathin Nanowires with Enhanced Electrocatalytic Performance toward Oxygen Reduction Reaction Li, Hui-Hui; Ma, Si-Yue; Fu, Qi-Qi Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b03877	journal	June 2015
Octahedral Pd@Pt _1.8 Ni Core–Shell Nanocrystals with Ultrathin PtNi Alloy Shells as Active Catalysts for Oxygen Reduction Reaction Zhao, Xu; Chen, Sheng; Fang, Zhicheng Journal of the American Chemical Society, Vol. 137, Issue 8 https://doi.org/10.1021/ja511596c	journal	February 2015
Low‐Platinum‐Content Quaternary PtCuCoNi Nanotubes with Markedly Enhanced Oxygen Reduction Activity Liu, Lifeng; Pippel, Eckhard Angewandte Chemie International Edition, Vol. 50, Issue 12 https://doi.org/10.1002/anie.201006644	journal	March 2011
Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets Zhang, L.; Roling, L. T.; Wang, X. Science, Vol. 349, Issue 6246 https://doi.org/10.1126/science.aab0801	journal	July 2015
Supportless Pt and PtPd Nanotubes as Electrocatalysts for Oxygen-Reduction Reactions Chen, Zhongwei; Waje, Mahesh; Li, Wenzhen Angewandte Chemie International Edition, Vol. 46, Issue 22 https://doi.org/10.1002/anie.200700894	journal	May 2007
Graphene-Supported Nanoelectrocatalysts for Fuel Cells: Synthesis, Properties, and Applications Liu, Minmin; Zhang, Ruizhong; Chen, Wei Chemical Reviews, Vol. 114, Issue 10 https://doi.org/10.1021/cr400523y	journal	March 2014
Highly Concave Platinum Nanoframes with High-Index Facets and Enhanced Electrocatalytic Properties Xia, Bao Yu; Wu, Hao Bin; Wang, Xin Angewandte Chemie International Edition, Vol. 52, Issue 47 https://doi.org/10.1002/anie.201307518	journal	September 2013
Nanoarchitectures for Mesoporous Metals Malgras, Victor; Ataee-Esfahani, Hamed; Wang, Hongjing Advanced Materials, Vol. 28, Issue 6 https://doi.org/10.1002/adma.201502593	journal	October 2015
Beyond conventional electrocatalysts: hollow nanoparticles for improved and sustainable oxygen reduction reaction activity Dubau, Laetitia; Lopez-Haro, Miguel; Durst, Julien J. Mater. Chem. A, Vol. 2, Issue 43 https://doi.org/10.1039/C4TA03975K	journal	January 2014
Rapid, General Synthesis of PdPt Bimetallic Alloy Nanosponges and Their Enhanced Catalytic Performance for Ethanol/Methanol Electrooxidation in an Alkaline Medium Zhu, Chengzhou; Guo, Shaojun; Dong, Shaojun Chemistry - A European Journal, Vol. 19, Issue 3 https://doi.org/10.1002/chem.201202909	journal	November 2012

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Single-Atom Electrocatalysts Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong Angewandte Chemie International Edition, Vol. 56, Issue 45 https://doi.org/10.1002/anie.201703864	journal	October 2017
A Review on Recent Developments and Prospects for the Oxygen Reduction Reaction on Hollow Pt-alloy Nanoparticles Asset, Tristan; Chattot, Raphaël; Fontana, Marie ChemPhysChem, Vol. 19, Issue 13 https://doi.org/10.1002/cphc.201800153	journal	May 2018
PtPdAg Hollow Nanodendrites: Template‐Free Synthesis and High Electrocatalytic Activity for Methanol Oxidation Reaction Zhang, Tao; Sun, Yiqiang; Li, Xuejiao Small Methods, Vol. 4, Issue 1 https://doi.org/10.1002/smtd.201900709	journal	November 2019
A one-step structure-switching electrochemical sensor for transcription factor detection enhanced with synergistic catalysis of PtNi@MIL-101 and Exo III-assisted cycling amplification Yu, Hua; Zhang, Wen; Lv, Sicheng Chemical Communications, Vol. 54, Issue 84 https://doi.org/10.1039/c8cc06468g	journal	January 2018
Hierarchical concave layered triangular PtCu alloy nanostructures: rational integration of dendritic nanostructures for efficient formic acid electrooxidation Wu, Fengxia; Lai, Jianping; Zhang, Ling Nanoscale, Vol. 10, Issue 19 https://doi.org/10.1039/c8nr00385h	journal	January 2018
Recent advances in electrocatalysts toward the oxygen reduction reaction: the case of PtNi octahedra Chaudhari, Nitin K.; Joo, Jinwhan; Kim, Byeongyoon Nanoscale, Vol. 10, Issue 43 https://doi.org/10.1039/c8nr06554c	journal	January 2018
Robust graphene-wrapped PtNi nanosponge for enhanced oxygen reduction reaction performance Tran, Quoc Chinh; An, Hyesung; Ha, Hyunwoo Journal of Materials Chemistry A, Vol. 6, Issue 18 https://doi.org/10.1039/c8ta01847b	journal	January 2018

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
three-dimensional morphology
hollow nanostructures
bimetallic alloys
oxygen reduction reaction
fuel cells
Environmental Molecular Sciences Laboratory

Title: Three-dimensional PtNi hollow nanochains as an enhanced electrocatalyst for the oxygen reduction reaction

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