Controllable deposition of platinum layers on oxide surfaces for the synthesis of fuel cell catalysts
Abstract
Abstract Reducing the amount of Pt, the most costly component of both anode and cathode fuel cell catalysts, has attracted considerable attention from the research community. An approach is reported herein to deposit sub‐monolayer to multilayer amounts of Pt and other noble metals on metal oxides and oxidized carbon materials. The process is exemplified by Pt deposition on RuO 2 (110). The Pt deposit consists of Pt atoms arranged in a c (2×2) array, that is, a 0.25 monolayer (ML). The deposit has lower catalytic activity for the oxygen reduction reaction (ORR) and similar activity for the hydrogen oxidation reaction compared to Pt(111). These activities are explained by a large calculated upshift of the d‐band center of Pt atoms and larger Pt–Pt interatomic distances than those of Pt(111). A catalyst with Pt coverage larger than 0.25 ML on oxide surfaces and oxidized carbon materials is shown to be active for the ORR as well as for other electrocatalytic reactions. A PtRhSnO 2 /C catalyst shows high activity for ethanol oxidation as a result of its ability to effectively cleave the C−C bond in ethanol. Pt deposited on reduced graphene oxide shows high Pt mass ORR activity and good stability.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States); Jinan Univ., Guangdong (China)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1326755
- Alternate Identifier(s):
- OSTI ID: 1401479
- Report Number(s):
- BNL-112650-2016-JA
Journal ID: ISSN 2196-0216; R&D Project: MA510MAEA; KC0302010
- Grant/Contract Number:
- SC00112704; SC0012704
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- ChemElectroChem
- Additional Journal Information:
- Journal Name: ChemElectroChem; Journal ID: ISSN 2196-0216
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Vukmirovic, Miomir B., Kuttiyiel, Kurian A., Meng, Hui, and Adzic, Radoslav R. Controllable deposition of platinum layers on oxide surfaces for the synthesis of fuel cell catalysts. United States: N. p., 2016.
Web. doi:10.1002/celc.201600255.
Vukmirovic, Miomir B., Kuttiyiel, Kurian A., Meng, Hui, & Adzic, Radoslav R. Controllable deposition of platinum layers on oxide surfaces for the synthesis of fuel cell catalysts. United States. https://doi.org/10.1002/celc.201600255
Vukmirovic, Miomir B., Kuttiyiel, Kurian A., Meng, Hui, and Adzic, Radoslav R. 2016.
"Controllable deposition of platinum layers on oxide surfaces for the synthesis of fuel cell catalysts". United States. https://doi.org/10.1002/celc.201600255. https://www.osti.gov/servlets/purl/1326755.
@article{osti_1326755,
title = {Controllable deposition of platinum layers on oxide surfaces for the synthesis of fuel cell catalysts},
author = {Vukmirovic, Miomir B. and Kuttiyiel, Kurian A. and Meng, Hui and Adzic, Radoslav R.},
abstractNote = {Abstract Reducing the amount of Pt, the most costly component of both anode and cathode fuel cell catalysts, has attracted considerable attention from the research community. An approach is reported herein to deposit sub‐monolayer to multilayer amounts of Pt and other noble metals on metal oxides and oxidized carbon materials. The process is exemplified by Pt deposition on RuO 2 (110). The Pt deposit consists of Pt atoms arranged in a c (2×2) array, that is, a 0.25 monolayer (ML). The deposit has lower catalytic activity for the oxygen reduction reaction (ORR) and similar activity for the hydrogen oxidation reaction compared to Pt(111). These activities are explained by a large calculated upshift of the d‐band center of Pt atoms and larger Pt–Pt interatomic distances than those of Pt(111). A catalyst with Pt coverage larger than 0.25 ML on oxide surfaces and oxidized carbon materials is shown to be active for the ORR as well as for other electrocatalytic reactions. A PtRhSnO 2 /C catalyst shows high activity for ethanol oxidation as a result of its ability to effectively cleave the C−C bond in ethanol. Pt deposited on reduced graphene oxide shows high Pt mass ORR activity and good stability.},
doi = {10.1002/celc.201600255},
url = {https://www.osti.gov/biblio/1326755},
journal = {ChemElectroChem},
issn = {2196-0216},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 13 00:00:00 EDT 2016},
month = {Tue Sep 13 00:00:00 EDT 2016}
}
Web of Science
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