Nickel hexacyanoferrate, a versatile intercalation host for divalent ions from nonaqueous electrolytes

Lipson, Albert L.; Han, Sang-Don; Kim, Soojeong; Pan, Baofei; Sa, Niya; Liao, Chen; Fister, Timothy T.; Burrell, Anthony K.; Vaughey, John T.; Ingram, Brian J.

doi:10.1016/j.jpowsour.2016.06.019

Title: Nickel hexacyanoferrate, a versatile intercalation host for divalent ions from nonaqueous electrolytes

Journal Article · Sat Jun 25 00:00:00 EDT 2016 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2016.06.019· OSTI ID:1392285

Lipson, Albert L. ^[1];

^[1]; Kim, Soojeong ^[1]; Pan, Baofei ^[1]; Sa, Niya ^[1]; Liao, Chen ^[1]; Fister, Timothy T. ^[1]; Burrell, Anthony K. ^[1]; Vaughey, John T. ^[1];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

We report that new energy storage chemistries based on Mg ions or Ca ions can theoretically improve both the energy density and reduce the costs of batteries. To date there has been limited progress in implementing these systems due to the challenge of finding a high voltage high capacity cathode that is compatible with an electrolyte that can plate and strip the elemental metal. In order to accelerate the discovery of such a system, model systems are needed that alleviate some of the issues of incompatibility. This report demonstrates the ability of nickel hexacyanoferrate to electrochemically intercalate Mg, Ca and Zn ions from a nonaqueous electrolyte. This material has a relatively high insertion potential and low overpotential in the electrolytes used in this study. Furthermore, since it is not an oxide based cathode it should be able to resist attack by corrosive electrolytes such as the chloride containing electrolytes that are often used to plate and strip magnesium. Finally, this makes it an excellent cathode for use in developing and understanding the complex electrochemistry of multivalent ion batteries.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1392285

Alternate ID(s):: OSTI ID: 1325336

Journal Information:: Journal of Power Sources, Vol. 325, Issue C; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 71 works

Citation information provided by
Web of Science

References (27)

Quantifying the promise of lithium–air batteries for electric vehicles Gallagher, Kevin G.; Goebel, Steven; Greszler, Thomas Energy & Environmental Science, Vol. 7, Issue 5 https://doi.org/10.1039/c3ee43870h	journal	January 2014
A review of lithium deposition in lithium-ion and lithium metal secondary batteries Li, Zhe; Huang, Jun; Yann Liaw, Bor Journal of Power Sources, Vol. 254 https://doi.org/10.1016/j.jpowsour.2013.12.099	journal	May 2014
Prototype systems for rechargeable magnesium batteries Aurbach, D.; Lu, Z.; Schechter, A. Nature, Vol. 407, Issue 6805, p. 724-727 https://doi.org/10.1038/35037553	journal	October 2000
The rechargeable revolution: A better battery Van Noorden, Richard Nature, Vol. 507, Issue 7490 https://doi.org/10.1038/507026a	journal	March 2014
Intercalation of Mg in V2O5 Yu, Wen-hai; Wang, Da-zhi; Zhu, Bin Solid State Communications, Vol. 63, Issue 11 https://doi.org/10.1016/0038-1098(87)90657-0	journal	September 1987
Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host Kim, Chunjoong; Phillips, Patrick J.; Key, Baris Advanced Materials, Vol. 27, Issue 22 https://doi.org/10.1002/adma.201500083	journal	April 2015
Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries Wang, Richard Y.; Wessells, Colin D.; Huggins, Robert A. Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl403669a	journal	October 2013
Reversible Multivalent (Monovalent, Divalent, Trivalent) Ion Insertion in Open Framework Materials Wang, Richard Y.; Shyam, Badri; Stone, Kevin H. Advanced Energy Materials, Vol. 5, Issue 12 https://doi.org/10.1002/aenm.201401869	journal	April 2015
Co-intercalation of Mg ²⁺ and Na ⁺ in Na _0.69 Fe ₂ (CN) ₆ as a High-Voltage Cathode for Magnesium Batteries Kim, Dong-Min; Kim, Youngjin; Arumugam, Durairaj ACS Applied Materials & Interfaces, Vol. 8, Issue 13 https://doi.org/10.1021/acsami.6b01352	journal	March 2016
First-Principles Study of Alkali and Alkaline Earth Ion Intercalation in Iron Hexacyanoferrate: The Important Role of Ionic Radius Ling, Chen; Chen, Jiajun; Mizuno, Fuminori The Journal of Physical Chemistry C, Vol. 117, Issue 41 https://doi.org/10.1021/jp4078689	journal	October 2013
Rechargeable Ca-Ion Batteries: A New Energy Storage System Lipson, Albert L.; Pan, Baofei; Lapidus, Saul H. Chemistry of Materials, Vol. 27, Issue 24 https://doi.org/10.1021/acs.chemmater.5b04027	journal	December 2015
Rechargeable magnesium battery: Current status and key challenges for the future Saha, Partha; Datta, Moni Kanchan; Velikokhatnyi, Oleg I. Progress in Materials Science, Vol. 66 https://doi.org/10.1016/j.pmatsci.2014.04.001	journal	October 2014
Mg rechargeable batteries: an on-going challenge Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279 https://doi.org/10.1039/c3ee40871j	journal	January 2013
Electrochemical Insertion of Magnesium in Metal Oxides and Sulfides from Aprotic Electrolytes Novák, Petr Journal of The Electrochemical Society, Vol. 140, Issue 1 https://doi.org/10.1149/1.2056075	journal	January 1993
A Superior Low-Cost Cathode for a Na-Ion Battery Wang, Long; Lu, Yuhao; Liu, Jue Angewandte Chemie International Edition, Vol. 52, Issue 7 https://doi.org/10.1002/anie.201206854	journal	January 2013
Iron Hexacyanoferrate Nanoparticles as Cathode Materials for Lithium and Sodium Rechargeable Batteries Yu, S. -H.; Shokouhimehr, M.; Hyeon, T. ECS Electrochemistry Letters, Vol. 2, Issue 4 https://doi.org/10.1149/2.008304eel	journal	January 2013
A promising cathode material of sodium iron–nickel hexacyanoferrate for sodium ion batteries Yu, Shenglan; Li, Yong; Lu, Yunhao Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.10.196	journal	February 2015
High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries You, Ya; Wu, Xing-Long; Yin, Ya-Xia Energy Environ. Sci., Vol. 7, Issue 5 https://doi.org/10.1039/C3EE44004D	journal	January 2014
Suppressed Activation Energy for Interfacial Charge Transfer of a Prussian Blue Analog Thin Film Electrode with Hydrated Ions (Li ⁺ , Na ⁺ , and Mg ²⁺ ) Mizuno, Yoshifumi; Okubo, Masashi; Hosono, Eiji The Journal of Physical Chemistry C, Vol. 117, Issue 21 https://doi.org/10.1021/jp311616s	journal	May 2013
Copper hexacyanoferrate with a well-defined open framework as a positive electrode for aqueous zinc ion batteries Jia, Zhijun; Wang, Baoguo; Wang, Yi Materials Chemistry and Physics, Vol. 149-150 https://doi.org/10.1016/j.matchemphys.2014.11.014	journal	January 2015
An Aqueous Zinc-Ion Battery Based on Copper Hexacyanoferrate Trócoli, Rafael; La Mantia, Fabio ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201403143	journal	December 2014
Current Collector Corrosion in Ca-Ion Batteries Lipson, Albert L.; Proffit, Danielle L.; Pan, Baofei Journal of The Electrochemical Society, Vol. 162, Issue 8 https://doi.org/10.1149/2.0811508jes	journal	January 2015
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
The Coupling between Stability and Ion Pair Formation in Magnesium Electrolytes from First-Principles Quantum Mechanics and Classical Molecular Dynamics Rajput, Nav Nidhi; Qu, Xiaohui; Sa, Niya Journal of the American Chemical Society, Vol. 137, Issue 9, p. 3411-3420 https://doi.org/10.1021/jacs.5b01004	journal	February 2015
Lattice contractions and expansions accompanying the electrochemical conversions of Prussian blue and the reversible and irreversible insertion of rubidium and thallium ions Dostal, Aleš; Kauschka, Günther; Reddy, S. Jayarama Journal of Electroanalytical Chemistry, Vol. 406, Issue 1-2 https://doi.org/10.1016/0022-0728(95)04427-2	journal	April 1996
In Situ X-Ray Absorption Spectroscopic Studies of Nickel Oxide Electrodes Pandya, K. I. Journal of The Electrochemical Society, Vol. 137, Issue 2 https://doi.org/10.1149/1.2086450	journal	January 1990
Multiple-scattering resonances and structural effects in the x-ray-absorption near-edge spectra of Fe II and Fe III hexacyanide complexes Bianconi, A.; Dell'Ariccia, M.; Durham, P. J. Physical Review B, Vol. 26, Issue 12 https://doi.org/10.1103/PhysRevB.26.6502	journal	December 1982

Cited By (12)

A critical review of cathodes for rechargeable Mg batteries Mao, Minglei; Gao, Tao; Hou, Singyuk Chemical Society Reviews, Vol. 47, Issue 23 https://doi.org/10.1039/c8cs00319j	journal	January 2018
Calcium-Ion Batteries: Current State-of-the-Art and Future Perspectives Gummow, Rosalind J.; Vamvounis, George; Kannan, M. Bobby Advanced Materials, Vol. 30, Issue 39 https://doi.org/10.1002/adma.201801702	journal	July 2018
Opportunities and Challenges in the Development of Cathode Materials for Rechargeable Mg Batteries Bitenc, Jan; Dominko, Robert Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00634	journal	December 2018
Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors Dong, Liubing; Yang, Wang; Yang, Wu Journal of Materials Chemistry A, Vol. 7, Issue 23 https://doi.org/10.1039/c9ta02678a	journal	January 2019
Room‐Temperature Rechargeable Ca‐Ion Based Hybrid Batteries with High Rate Capability and Long‐Term Cycling Life Lang, Jihui; Jiang, Chunlei; Fang, Yue Advanced Energy Materials, Vol. 9, Issue 29 https://doi.org/10.1002/aenm.201901099	journal	June 2019
Four decades of electrochemical investigation of Prussian blue Ivanov, Vladimir D. Ionics, Vol. 26, Issue 2 https://doi.org/10.1007/s11581-019-03292-y	journal	November 2019
On the Scope of XPS as Sensor in Coordination Chemistry of Transition Metal Hexacyanometallates: On the Scope of XPS as Sensor in Coordination Chemistry of Transition Metal Hexacyanometallates Cano, Arely; Rodríguez-Hernández, Joelis; Reguera, Leslie European Journal of Inorganic Chemistry, Vol. 2019, Issue 13 https://doi.org/10.1002/ejic.201801556	journal	March 2019
Exploring the high-voltage Mg 2+ /Na + co-intercalation reaction of Na 3 VCr(PO 4 ) 3 in Mg-ion batteries Rubio, Saúl; Liu, Rui; Liu, Xiangsi Journal of Materials Chemistry A, Vol. 7, Issue 30 https://doi.org/10.1039/c9ta05608d	journal	January 2019
Reversible S ⁰ /MgS _x Redox Chemistry in a MgTFSI ₂ /MgCl ₂ /DME Electrolyte for Rechargeable Mg/S Batteries Gao, Tao; Hou, Singyuk; Wang, Fei Angewandte Chemie, Vol. 129, Issue 43 https://doi.org/10.1002/ange.201708241	journal	September 2017
Charge Redistribution Effects in Hexacyanometallates Evaluated from XPS Data: Charge Redistribution Effects in Hexacyanometallates Evaluated from XPS Data Cano, Arely; Reguera, Leslie; Avila, Manuel European Journal of Inorganic Chemistry, Vol. 2020, Issue 1 https://doi.org/10.1002/ejic.201900907	journal	December 2019
Eco-compatible oxides enabling energy storage via Li ⁺ /Mg ²⁺ co-intercalation Veleva, Sv.; Ivanova, Sv.; Półrolniczak, P. Dalton Transactions, Vol. 48, Issue 36 https://doi.org/10.1039/c9dt02966d	journal	January 2019
Reversible S ⁰ /MgS _x Redox Chemistry in a MgTFSI ₂ /MgCl ₂ /DME Electrolyte for Rechargeable Mg/S Batteries Gao, Tao; Hou, Singyuk; Wang, Fei Angewandte Chemie International Edition, Vol. 56, Issue 43 https://doi.org/10.1002/anie.201708241	journal	September 2017

Figures / Tables (5)

Similar Records

Anion Association Strength as a Unifying Descriptor for the Reversibility of Divalent Metal Deposition in Nonaqueous Electrolytes

Journal Article · Wed Jul 15 00:00:00 EDT 2020 · ACS Applied Materials and Interfaces · OSTI ID:1392285

Connell, Justin G.; Zorko, Milena; Agarwal, Garvit; +5 more

Quantifying and Suppressing Proton Intercalation to Enable High-Voltage Zn-Ion Batteries

Journal Article · Mon Oct 04 00:00:00 EDT 2021 · Advanced Energy Materials · OSTI ID:1392285

Wang, Fei; Blanc, Lauren E.; Li, Qin; +9 more

Rechargeable Ca-Ion Batteries: A New Energy Storage System

Journal Article · Tue Nov 24 00:00:00 EST 2015 · Chemistry of Materials · OSTI ID:1392285

Lipson, Albert L.; Pan, Baofei; Lapidus, Saul H.; +3 more

Related Subjects

25 ENERGY STORAGE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Nickel Hexacyanoferrate
Nonaqueous
XANES
calcium battery
magnesium battery