Perspective on Catalytic Hydrodeoxygenation of Biomass Pyrolysis Oils: Essential Roles of Fe-Based Catalysts

Hong, Yongchun; Hensley, Alyssa; McEwen, Jean-Sabin; Wang, Yong

doi:10.1007/s10562-016-1770-1

Title: Perspective on Catalytic Hydrodeoxygenation of Biomass Pyrolysis Oils: Essential Roles of Fe-Based Catalysts

Journal Article · Mon Jun 27 00:00:00 EDT 2016 · Catalysis Letters

DOI:https://doi.org/10.1007/s10562-016-1770-1· OSTI ID:1324891

Hong, Yongchun; Hensley, Alyssa; McEwen, Jean-Sabin; Wang, Yong

Catalytic fast pyrolysis is the most promising approach for biofuel production, due to its simple process and versatility to handle lignocellulosic biomass feedstocks with varying and complex compositions. Compared with in situ catalytic fast pyrolysis, ex situ catalytic pyrolysis has the flexibility of optimizing the pyrolysis step and catalytic process individually to improve the quality of pyrolysis oil (stability, oxygen content, acid number, etc.) and to maximize the carbon efficiency in the conversion of biomass to pyrolysis oil. Hydrodeoxygenation is one of the key catalytic functions in ex situ catalytic fast pyrolysis. Recently, Fe-based catalysts have been reported to exhibit superior catalytic properties in hydrodeoxygenation of model compounds in pyrolysis oil, which potentially makes the ex situ pyrolysis of biomass commercially viable due to the abundance and low cost of Fe. Here, we briefly summarize the recent progress on Fe-based catalysts for hydrodeoxygenation of biomass, and provide perspectives on how to further improve Fe-based catalysts (activity and stability) for their potential applications in the emerging area of biomass conversion.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1324891

Report Number(s):: PNNL-SA-119147; 48920; KC0302010

Journal Information:: Catalysis Letters, Vol. 146, Issue 9; ISSN 1011-372X

Publisher:: Springer

Country of Publication:: United States

Language:: English

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Nanometric chemical clocks McEwen, J. -S.; Gaspard, P.; de Bocarme, T. V. Proceedings of the National Academy of Sciences, Vol. 106, Issue 9 https://doi.org/10.1073/pnas.0811941106	journal	February 2009
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Experiment-Based Kinetic Monte Carlo Simulations: CO Oxidation over RuO ₂ (110) Farkas, A.; Hess, F.; Over, H. The Journal of Physical Chemistry C, Vol. 116, Issue 1 https://doi.org/10.1021/jp204703p	journal	December 2011
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