Local coexistence of VO2 phases revealed by deep data analysis

Strelcov, Evgheni; Ievlev, Anton; Tselev, Alexander; Kolmakov, Andrei; Kalinin, Sergei V.

doi:10.1038/srep29216

Title: Local coexistence of VO₂ phases revealed by deep data analysis

Journal Article · Thu Jul 07 00:00:00 EDT 2016 · Scientific Reports

DOI:https://doi.org/10.1038/srep29216· OSTI ID:1324095

Strelcov, Evgheni ^[1]; Ievlev, Anton ^[2]; Tselev, Alexander ^[2]; Kolmakov, Andrei ^[3]; Kalinin, Sergei V. ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)

We report a synergistic approach of micro-Raman spectroscopic mapping and deep data analysis to study the distribution of crystallographic phases and ferroelastic domains in a defected Al-doped VO₂ microcrystal. Bayesian linear unmixing revealed an uneven distribution of the T phase, which is stabilized by the surface defects and uneven local doping that went undetectable by other classical analysis techniques such as PCA and SIMPLISMA. This work demonstrates the impact of information recovery via statistical analysis and full mapping in spectroscopic studies of vanadium dioxide systems, which is commonly substituted by averaging or single point-probing approaches, both of which suffer from information misinterpretation due to low resolving power.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1324095

Journal Information:: Scientific Reports, Vol. 6; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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Development of VO ₂ -Nanoparticle-Based Metal-Insulator Transition Electronic Ink Vaseem, Mohammad; Zhen, Su; Yang, Shuai Advanced Electronic Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aelm.201800949	journal	March 2019
VO ₂ as a natural optical metamaterial Eaton, Miller; Catellani, Alessandra; Calzolari, Arrigo Optics Express, Vol. 26, Issue 5 https://doi.org/10.1364/oe.26.005342	journal	January 2018
Synthesis and thermochromic property studies on W doped VO2 films fabricated by sol-gel method Pan, Guoping; Yin, Jinhua; Ji, Keli Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-05229-9	journal	July 2017

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