Flexible MOFs under stress: pressure and temperature

Clearfield, Abraham

doi:10.1039/c5dt03228h

Title: Flexible MOFs under stress: pressure and temperature

Journal Article · Mon Nov 09 00:00:00 EST 2015 · Dalton Transactions

DOI:https://doi.org/10.1039/c5dt03228h· OSTI ID:1322354

Clearfield, Abraham ^[1]

Texas A & M Univ., College Station, TX (United States)

In the recent past an enormous number of Metal–Organic Framework type compounds (MOFs) have been synthesized. The novelty resides in their extremely high surface area and the ability to include additional features to their structure either during synthesis or as additives to the MOF. This versatility allows for MOFs to be designed for specific applications. However, the question arises as to whether a particular MOF can withstand the stress that may be encountered in fulfillment of the designated application. Here we describe the behavior of two flexible MOFs under pressure and several others under temperature increase. The pressure study includes both experimental and theoretical calculations. In the thermal processes evidence for colossal negative thermal expansion were encountered.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Robert A. Welch Foundation

OSTI ID:: 1322354

Journal Information:: Dalton Transactions, Vol. 45, Issue 10; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 29 works

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Effect of the Metal within Regioisomeric Paddle‐Wheel‐Type Metal–Organic Frameworks Ha, Hyeonbin; Kim, Youngik; Kim, Dopil Chemistry – A European Journal, Vol. 25, Issue 63 https://doi.org/10.1002/chem.201903210	journal	October 2019
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