Materials Data on Al(CuO2)3 by Materials Project
Al(CuO2)2CuO2 crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of two copper(ii) hydroxide molecules and one Al(CuO2)2 sheet oriented in the (0, 0, 1) direction. In the Al(CuO2)2 sheet, Cu3+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.74 Å) and one longer (1.78 Å) Cu–O bond length. Al3+ is bonded to six O2- atoms to form edge-sharing AlO6 octahedra. There is two shorter (1.89 Å) and four longer (1.90 Å) Al–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to one Cu3+ and two equivalent Al3+ atoms. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one Cu3+ and one Al3+ atom.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1318126
- Report Number(s):
- mvc-11181
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
Similar Records
Materials Data on Al2(CuO2)3 by Materials Project
Materials Data on MgAl6O10 by Materials Project