Materials Data on RbCaSb by Materials Project
RbCaSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Rb1+ is bonded in a 5-coordinate geometry to five equivalent Sb3- atoms. There are one shorter (3.76 Å) and four longer (4.09 Å) Rb–Sb bond lengths. Ca2+ is bonded to four equivalent Sb3- atoms to form a mixture of corner and edge-sharing CaSb4 tetrahedra. All Ca–Sb bond lengths are 3.18 Å. Sb3- is bonded in a 9-coordinate geometry to five equivalent Rb1+ and four equivalent Ca2+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1316582
- Report Number(s):
- mp-9846
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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