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Title: Late transition metal m-or chemistry and D6 metal complex photoeliminations

With the goal of understanding and controlling photoreductive elimination reactions from d6 transition metal complexes as part of a solar energy storage cycle we have investigated the photochemistry of Pt(IV) bromo, chloro, hydroxo, and hydroperoxo complexes. Photoreductive elimination reactions occur for all of these complexes and appear to involve initial Pt-Br, Pt-Cl, or Pt-O bond fission. In the case of Pt-OH bond fission, the subsequent chemistry can be controlled through hydrogen bonding to the hydroxo group.
Authors:
 [1]
  1. Univ. of Missouri, Columbia, MO (United States)
Publication Date:
OSTI Identifier:
1313940
Report Number(s):
DE--FG02-88ER13880-1
DOE Contract Number:
FG02-88ER13880
Resource Type:
Technical Report
Research Org:
Univ. of Missouri, Columbia, MO (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
30 DIRECT ENERGY CONVERSION; 14 SOLAR ENERGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY