Materials Data on CoSbO4 by Materials Project
CoSbO4 is beta Vanadium nitride-derived structured and crystallizes in the tetragonal I-4m2 space group. The structure is three-dimensional. Co3+ is bonded to six O2- atoms to form CoO6 octahedra that share corners with four equivalent CoO6 octahedra and edges with four equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 20°. There is two shorter (1.89 Å) and four longer (1.99 Å) Co–O bond length. Sb5+ is bonded to six O2- atoms to form distorted SbO6 octahedra that share corners with four equivalent SbO6 octahedra and edges with four equivalent CoO6 octahedra. The corner-sharing octahedral tilt angles are 25°. There is two shorter (1.98 Å) and four longer (2.00 Å) Sb–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a T-shaped geometry to two equivalent Co3+ and one Sb5+ atom. In the second O2- site, O2- is bonded in a distorted T-shaped geometry to one Co3+ and two equivalent Sb5+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1302562
- Report Number(s):
- mp-774401
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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