Materials Data on MnSbO4 by Materials Project

Dataset · Fri Jul 21 00:00:00 EDT 2017

DOI:https://doi.org/10.17188/1300756· OSTI ID:1300756

The Materials Project

MnSbO4 crystallizes in the monoclinic P2/m space group. The structure is two-dimensional and consists of one MnSbO4 sheet oriented in the (1, 0, 0) direction. Mn3+ is bonded in a 6-coordinate geometry to six O2- atoms. There are four shorter (1.97 Å) and two longer (2.49 Å) Mn–O bond lengths. Sb5+ is bonded to six O2- atoms to form edge-sharing SbO6 octahedra. There are four shorter (2.02 Å) and two longer (2.04 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal non-coplanar geometry to two equivalent Mn3+ and one Sb5+ atom. In the second O2- site, O2- is bonded in a 3-coordinate geometry to one Mn3+ and two equivalent Sb5+ atoms.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1300756
• Report Number(s): mp-771676
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
MnSbO4
Mn-O-Sb