Materials Data on V4OF11 by Materials Project
V4OF11 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are four inequivalent V+3.25+ sites. In the first V+3.25+ site, V+3.25+ is bonded in a 2-coordinate geometry to one O2- and five F1- atoms. The V–O bond length is 1.59 Å. There are a spread of V–F bond distances ranging from 1.65–2.45 Å. In the second V+3.25+ site, V+3.25+ is bonded in a distorted square co-planar geometry to six F1- atoms. There are a spread of V–F bond distances ranging from 1.64–2.56 Å. In the third V+3.25+ site, V+3.25+ is bonded in a 2-coordinate geometry to six F1- atoms. There are a spread of V–F bond distances ranging from 1.64–2.44 Å. In the fourth V+3.25+ site, V+3.25+ is bonded in a 4-coordinate geometry to one O2- and four F1- atoms. The V–O bond length is 1.37 Å. There are a spread of V–F bond distances ranging from 1.69–2.50 Å. O2- is bonded in a distorted bent 150 degrees geometry to two V+3.25+ atoms. There are eleven inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two V+3.25+ atoms. In the second F1- site, F1- is bonded in a 2-coordinate geometry to two V+3.25+ atoms. In the third F1- site, F1- is bonded in a 2-coordinate geometry to two V+3.25+ atoms. In the fourth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two V+3.25+ atoms. In the fifth F1- site, F1- is bonded in a bent 120 degrees geometry to two V+3.25+ atoms. In the sixth F1- site, F1- is bonded in a bent 120 degrees geometry to two V+3.25+ atoms. In the seventh F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two V+3.25+ atoms. In the eighth F1- site, F1- is bonded in a 2-coordinate geometry to two V+3.25+ atoms. In the ninth F1- site, F1- is bonded in a 1-coordinate geometry to one V+3.25+ atom. In the tenth F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two V+3.25+ atoms. In the eleventh F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two V+3.25+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1294377
- Report Number(s):
- mp-764086
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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Materials Data on V4OF11 by Materials Project
Materials Data on V4OF11 by Materials Project