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Title: Facile P-C/C-H Bond-Cleavage Reactivity of Nickel Bis(diphosphine) Complexes

Unusual cleavage of P-C and C-H bonds of the P2N2 ligand in heteroleptic [Ni(P2N2)(diphosphine)]2+ complexes results in the formation of an iminium formyl nickelate featuring a C,P,P-tridentate coordination mode.
Authors:
 [1] ;  [2] ;  [1] ;  [2] ;  [1]
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  2. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
Publication Date:
OSTI Identifier:
1290404
Report Number(s):
PNNL-SA--115898
Journal ID: ISSN 0947-6539; KC0302010
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Chemistry - A European Journal; Journal Volume: 22; Journal Issue: 28
Publisher:
ChemPubSoc Europe
Research Org:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY nickel complexes; computations