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Title: Relative humidity-dependent viscosity of secondary organic material from toluene photo-oxidation and possible implications for organic particulate matter over megacities

To improve predictions of air quality, visibility, and climate change, knowledge of the viscosities and diffusion rates within organic particulate matter consisting of secondary organic material (SOM) is required. Most qualitative and quantitative measurements of viscosity and diffusion rates within organic particulate matter have focused on SOM particles generated from biogenic volatile organic compounds (VOCs) such as α-pinene and isoprene. In this study, we quantify the relative humidity (RH)-dependent viscosities at 295±1K of SOM produced by photo-oxidation of toluene, an anthropogenic VOC. The viscosities of toluene-derived SOM were 2 × 10₋1 to ~6 ×106Pa s from 30 to 90%RH, and greater than ~2 × 108 Pa s (similar to or greater than the viscosity of tar pitch) for RH ≤ 17%. These viscosities correspond to Stokes–Einstein-equivalent diffusion coefficients for large organic molecules of ~2 ×10₋15cm2s₋1 for 30 % RH, and lower than ~3 × 10₋17cm2s₋1 for RH ≤ 17 %. Based on these estimated diffusion coefficients, the mixing time of large organic molecules within 200 nm toluene-derived SOM particles is 0.1–5 h for 30% RH, and higher than ~100 h for RH ≤ 17%. As a starting point for understanding the mixing times of large organic molecules in organic particulatemore » matter over cities, we applied the mixing times determined for toluene-derived SOM particles to the world's top 15 most populous megacities. If the organic particulate matter in these megacities is similar to the toluene-derived SOM in this study, in Istanbul, Tokyo, Shanghai, and São Paulo, mixing times in organic particulate matter during certain periods of the year may be very short, and the particles may be well-mixed. On the other hand, the mixing times of large organic molecules in organic particulate matter in Beijing, Mexico City, Cairo, and Karachi may be long and the particles may not be well-mixed in the afternoon (15:00–17:00 LT) during certain times of the year.« less
Authors:
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Publication Date:
OSTI Identifier:
1290396
Report Number(s):
PNNL-SA-115516
Journal ID: ISSN 1680-7324; KP1701000
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Atmospheric Chemistry and Physics (Online); Journal Volume: 16; Journal Issue: 14
Publisher:
European Geosciences Union
Research Org:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English