Synthesis of Two-Dimensional Materials for Capacitive Energy Storage

Mendoza-Sánchez, Beatriz; Gogotsi, Yury

doi:10.1002/adma.201506133

Title: Synthesis of Two-Dimensional Materials for Capacitive Energy Storage

Journal Article · Thu Jun 02 00:00:00 EDT 2016 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201506133· OSTI ID:1286986

Mendoza-Sánchez, Beatriz ^[1]; Gogotsi, Yury ^[2]

FranÃ§ois Rabelais Univ., Tours (France)
Drexel Univ., Philadelphia, PA (United States)

The unique properties and great variety of two-dimensional (2D) nanomaterials make them highly attractive for energy storage applications. Here, an insight into the progress made towards the application of 2D nanomaterials for capacitive energy storage is provided. Moreover, synthesis methods, and electrochemical performance of various classes of 2D nanomaterials, particularly based on graphene, transition metal oxides, dichalcogenides, and carbides, are presented. Some factors that directly influence capacitive performance are discussed throughout the text and include nanosheet composition, morphology and texture, electrode architecture, and device configuration. Recent progress in the fabrication of 2D-nanomaterials-based microsupercapacitors and flexible and free-standing supercapacitors is presented. The main electrode manufacturing techniques with emphasis on scalability and cost-effectiveness are discussed, and include laser scribing, printing, and roll-to-roll manufacture. Some various issues that prevent the use of the full energy-storage potential of 2D nanomaterials and how they have been tackled are discussed, and include nanosheet aggregation and the low electrical conductivity of some 2D nanomaterials. In particular, the design of hybrid and hierarchical 2D and 3D structures based on 2D nanomaterials is presented. Other challenges and opportunities are discussed and include: control of nanosheets size and thickness, chemical and electrochemical instability, and scale-up of electrode films.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1286986

Journal Information:: Advanced Materials, Vol. 28, Issue 29; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 495 works

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Boron doping and structure control of carbon materials for supercapacitor application: the effect of freeze-drying and air-drying for porosity engineering Chen, Dan Dan; He, Zhi Qiang; Wang, Min Journal of Solid State Electrochemistry, Vol. 24, Issue 3 https://doi.org/10.1007/s10008-020-04498-1	journal	January 2020
Porous lithium titanate nanosheets as an advanced anode material for sodium ion batteries Liang, Kang; He, Hanna; Ren, Yurong Journal of Materials Science https://doi.org/10.1007/s10853-019-04290-1	journal	December 2019
A facile one-pot method to prepare nitrogen and fluorine co-doped three-dimensional graphene-like materials for supercapacitors Duan, Diancheng; Hu, Fang; Ma, Jiaojun Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 21 https://doi.org/10.1007/s10854-019-02316-7	journal	October 2019
Highly sensitive fluorescent sensing for intracellular glutathione based on Ti3C2 quantum dots Xu, Xiumei; Zhang, Haijiao; Diao, Quan Journal of Materials Science: Materials in Electronics, Vol. 31, Issue 1 https://doi.org/10.1007/s10854-019-02682-2	journal	December 2019
Ratiometric photoluminescence sensing based on Ti ₃ C ₂ MXene quantum dots as an intracellular pH sensor Chen, Xu; Sun, Xueke; Xu, Wen Nanoscale, Vol. 10, Issue 3 https://doi.org/10.1039/c7nr06958h	journal	January 2018
Few-layered MoSe ₂ nanosheets as an efficient peroxidase nanozyme for highly sensitive colorimetric detection of H ₂ O ₂ and xanthine Wu, Xiaoju; Chen, Tongming; Wang, Jianxing Journal of Materials Chemistry B, Vol. 6, Issue 1 https://doi.org/10.1039/c7tb02434g	journal	January 2018
From ZIF nanoparticles to hierarchically porous carbon: toward very high surface area and high-performance supercapacitor electrode materials Wang, Fangfang; Zhu, Liangkui; Pan, Ying Inorganic Chemistry Frontiers, Vol. 6, Issue 1 https://doi.org/10.1039/c8qi00832a	journal	January 2019
B/N co-doped carbon nanosphere frameworks as high-performance electrodes for supercapacitors Hao, Jian; Wang, Jiemin; Qin, Si Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/c8ta00683k	journal	January 2018
Binder-free bonding of modularized MXene thin films into thick film electrodes for on-chip micro-supercapacitors with enhanced areal performance metrics Hu, Haibo; Bai, Zhiman; Niu, Ben Journal of Materials Chemistry A, Vol. 6, Issue 30 https://doi.org/10.1039/c8ta04737e	journal	January 2018
Tunable energy storage capacity of two-dimensional Ti ₃ C ₂ T _x modified by a facile two-step pillaring strategy for high performance supercapacitor electrodes Li, Yahui; Deng, Yanan; Zhang, Jianfeng Nanoscale, Vol. 11, Issue 45 https://doi.org/10.1039/c9nr07259d	journal	January 2019
Carbon–metal compound composite electrodes for capacitive deionization: synthesis, development and applications Tang, Kexin; Hong, Terence Zhi Xiang; You, Liming Journal of Materials Chemistry A, Vol. 7, Issue 47 https://doi.org/10.1039/c9ta08663c	journal	January 2019
Sustainable recycling of waste polystyrene into hierarchical porous carbon nanosheets with potential applications in supercapacitors Ma, Changde; Liu, Xiaoguang; Min, Jiakang Nanotechnology, Vol. 31, Issue 3 https://doi.org/10.1088/1361-6528/ab475f	journal	October 2019
Unexpected Stabilization of α -Ni(OH) ₂ Nanoparticles in GO Nanocomposites Gonçalves, Josué M.; Alves, Kamilla M.; Gonzalez-Huila, Manuel F. Journal of Nanomaterials, Vol. 2018 https://doi.org/10.1155/2018/5735609	journal	December 2018
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Toward Superior Capacitive Energy Storage: Recent Advances in Pore Engineering for Dense Electrodes Liu, Congcong; Yan, Xiaojun; Hu, Fei Advanced Materials, Vol. 30, Issue 17 https://doi.org/10.1002/adma.201705713	journal	March 2018
Graphene-Like Nitrogen-Doped Carbon Nanosheet Prepared from Direct Calcination of Dopamine Confined by g-C ₃ N ₄ for Oxygen Reduction Liu, Xinghuan; Kang, Junjie; Dai, Yu Advanced Materials Interfaces, Vol. 5, Issue 14 https://doi.org/10.1002/admi.201800303	journal	May 2018
Scalable Manufacturing of Large and Flexible Sheets of MXene/Graphene Heterostructures Zhao, Meng‐Qiang; Trainor, Nicholas; Ren, Chang E. Advanced Materials Technologies, Vol. 4, Issue 5 https://doi.org/10.1002/admt.201800639	journal	March 2019
Selective Growth of Zn–Co–Se Nanostructures on Various Conductive Substrates for Asymmetric Flexible Hybrid Supercapacitor with Enhanced Performance Chebrolu, Venkata Thulasivarma; Balakrishnan, Balamuralitharan; Chinnadurai, Deviprasath Advanced Materials Technologies, Vol. 5, Issue 2 https://doi.org/10.1002/admt.201900873	journal	December 2019
Liquid-Phase Exfoliated Metallic Antimony Nanosheets toward High Volumetric Sodium Storage Gu, Jianan; Du, Zhiguo; Zhang, Chao Advanced Energy Materials, Vol. 7, Issue 17 https://doi.org/10.1002/aenm.201700447	journal	May 2017
Antimonene: A Novel 2D Nanomaterial for Supercapacitor Applications Martínez-Periñán, Emiliano; Down, Michael P.; Gibaja, Carlos Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702606	journal	December 2017
Scalable Water-Based Production of Highly Conductive 2D Nanosheets with Ultrahigh Volumetric Capacitance and Rate Capability Jeon, Hyeonyeol; Jeong, Jae-Min; Kang, Heon Gyu Advanced Energy Materials, Vol. 8, Issue 18 https://doi.org/10.1002/aenm.201800227	journal	March 2018
Three-Dimensional Architectures Constructed from Transition-Metal Dichalcogenide Nanomaterials for Electrochemical Energy Storage and Conversion Yun, Qinbai; Lu, Qipeng; Zhang, Xiao Angewandte Chemie International Edition, Vol. 57, Issue 3 https://doi.org/10.1002/anie.201706426	journal	December 2017
Molecular-Based Design of Microporous Carbon Nanosheets He, Lei; Li, Wen-Cui; Xu, Shuang Chemistry - A European Journal, Vol. 25, Issue 13 https://doi.org/10.1002/chem.201804747	journal	January 2019
Recent Advances in Layered Ti ₃ C ₂ T _x MXene for Electrochemical Energy Storage Xiong, Dongbin; Li, Xifei; Bai, Zhimin Small, Vol. 14, Issue 17 https://doi.org/10.1002/smll.201703419	journal	February 2018
Surface Modified MXene‐Based Nanocomposites for Electrochemical Energy Conversion and Storage Yu, Hong; Wang, Yonghui; Jing, Yao Small, Vol. 15, Issue 25 https://doi.org/10.1002/smll.201901503	journal	May 2019
A review on metal nitrides/oxynitrides as an emerging supercapacitor electrode beyond oxide Ghosh, Subrata; Jeong, Sang Mun; Polaki, Shyamal Rao Korean Journal of Chemical Engineering, Vol. 35, Issue 7 https://doi.org/10.1007/s11814-018-0089-6	journal	June 2018
Supercapacitor electrode materials with hierarchically structured pores from carbonization of MWCNTs and ZIF-8 composites Li, Xueqin; Hao, Changlong; Tang, Bochong Nanoscale, Vol. 9, Issue 6 https://doi.org/10.1039/c6nr08987a	journal	January 2017
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Rationally designing S/Ti ₃ C ₂ T _x as a cathode material with an interlayer for high-rate and long-cycle lithium–sulfur batteries Jin, Q.; Zhang, N.; Zhu, C. C. Nanoscale, Vol. 10, Issue 35 https://doi.org/10.1039/c8nr05749d	journal	January 2018
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The development of 2D materials for electrochemical energy applications: A mechanistic approach Hynek, David J.; Pondick, Joshua V.; Cha, Judy J. APL Materials, Vol. 7, Issue 3 https://doi.org/10.1063/1.5085187	journal	March 2019
Novel mesoporous electrode materials for symmetric, asymmetric and hybrid supercapacitors Cherusseri, Jayesh; Sambath Kumar, Kowsik; Choudhary, Nitin Nanotechnology, Vol. 30, Issue 20 https://doi.org/10.1088/1361-6528/ab0685	journal	March 2019
Strategies for improving the lithium-storage performance of 2D nanomaterials Mei, Jun; Zhang, Yuanwen; Liao, Ting National Science Review, Vol. 5, Issue 3 https://doi.org/10.1093/nsr/nwx077	journal	July 2017
Flocculant-Assisted Synthesis of Graphene-Like Carbon Nanosheets for Oxygen Reduction Reaction and Supercapacitor Zhang, Yinglin; Shi, Yulin; Yan, Bo Nanomaterials, Vol. 9, Issue 8 https://doi.org/10.3390/nano9081135	journal	August 2019
The Synthesis of NiCo2O4–MnO2 Core–Shell Nanowires by Electrodeposition and Its Supercapacitive Properties Yan, Ai-Lan; Wang, Wei-Dong; Chen, Wen-Qiang Nanomaterials, Vol. 9, Issue 10 https://doi.org/10.3390/nano9101398	journal	October 2019
Molecularly Coupled Two‐Dimensional Titanium Oxide and Carbide Sheets for Wearable and High‐Rate Quasi‐Solid‐State Rechargeable Batteries Wu, Jinli; Jiang, Kun; Li, Guohui Advanced Functional Materials, Vol. 29, Issue 30 https://doi.org/10.1002/adfm.201901576	journal	April 2019
Recent Development of Printed Micro‐Supercapacitors: Printable Materials, Printing Technologies, and Perspectives Li, Hongpeng; Liang, Jiajie Advanced Materials, Vol. 32, Issue 3 https://doi.org/10.1002/adma.201805864	journal	April 2019
The Road Towards Planar Microbatteries and Micro‐Supercapacitors: From 2D to 3D Device Geometries Zheng, Shuanghao; Shi, Xiaoyu; Das, Pratteek Advanced Materials https://doi.org/10.1002/adma.201900583	journal	June 2019
Dreidimensionale Architekturen aus Übergangsmetall‐Dichalkogenid‐Nanomaterialien zur elektrochemischen Energiespeicherung und ‐umwandlung Yun, Qinbai; Lu, Qipeng; Zhang, Xiao Angewandte Chemie, Vol. 130, Issue 3 https://doi.org/10.1002/ange.201706426	journal	December 2017
Confined Self-Assembly in Two-Dimensional Interlayer Space: Monolayered Mesoporous Carbon Nanosheets with In-Plane Orderly Arranged Mesopores and a Highly Graphitized Framework Wang, Jie; Xu, Yunling; Ding, Bing Angewandte Chemie International Edition, Vol. 57, Issue 11 https://doi.org/10.1002/anie.201712959	journal	February 2018
Ultrathin Two‐Dimensional Semiconductors for Photocatalysis in Energy and Environment Applications Hu, Sujuan; Zhu, Mingshan ChemCatChem, Vol. 11, Issue 24 https://doi.org/10.1002/cctc.201901597	journal	October 2019
Tracking Ionic Rearrangements and Interpreting Dynamic Volumetric Changes in Two‐Dimensional Metal Carbide Supercapacitors: A Molecular Dynamics Simulation Study Xu, Kui; Lin, Zifeng; Merlet, Céline ChemSusChem, Vol. 11, Issue 12 https://doi.org/10.1002/cssc.201702068	journal	January 2018
Facile synthesis and electrochemical performance of TiO2 nanowires/Ti3C2 composite Lv, Wenjing; Zhu, Jianfeng; Wang, Fen Journal of Materials Science: Materials in Electronics, Vol. 29, Issue 6 https://doi.org/10.1007/s10854-017-8446-5	journal	January 2018
Flexible and integrated supercapacitor with tunable energy storage Shao, Changxiang; Xu, Tong; Gao, Jian Nanoscale, Vol. 9, Issue 34 https://doi.org/10.1039/c7nr04889k	journal	January 2017
Sb ₂ O ₃ /MXene(Ti ₃ C ₂ T _x ) hybrid anode materials with enhanced performance for sodium-ion batteries Guo, Xin; Xie, Xiuqiang; Choi, Sinho Journal of Materials Chemistry A, Vol. 5, Issue 24 https://doi.org/10.1039/c7ta02689g	journal	January 2017
An easily manipulated protocol for patterning of MXenes on paper for planar micro-supercapacitors Hu, Haibo; Hua, Tao Journal of Materials Chemistry A, Vol. 5, Issue 37 https://doi.org/10.1039/c7ta04735e	journal	January 2017
Edge-oriented SnS ₂ nanosheet arrays on carbon paper as advanced binder-free anodes for Li-ion and Na-ion batteries Wang, Jian-Gan; Sun, Huanhuan; Liu, Huanyan Journal of Materials Chemistry A, Vol. 5, Issue 44 https://doi.org/10.1039/c7ta07553g	journal	January 2017
A stepwise crosslinking strategy toward lamellar carbon frameworks with covalently connected alternate layers of porous carbon nanosheets and porous carbon spacers Huang, Junlong; Lin, Yanhuan; Liu, Shaohong Chemical Communications, Vol. 54, Issue 73 https://doi.org/10.1039/c8cc05479g	journal	January 2018
Electronic Properties of Armchair Black Phosphorene Nanoribbons Edge-Modified by Transition Elements V, Cr, and Mn Huang, Jiong-Hua; Wang, Xue-Feng; Liu, Yu-Shen Nanoscale Research Letters, Vol. 14, Issue 1 https://doi.org/10.1186/s11671-019-2971-5	journal	April 2019
Optically Sintered 2D RuO ₂ Nanosheets: Temperature-Controlled NO ₂ Reaction Choi, Seon-Jin; Jang, Ji-Soo; Park, Hee Jung Advanced Functional Materials, Vol. 27, Issue 13 https://doi.org/10.1002/adfm.201606026	journal	February 2017
Functionalized Hybridization of 2D Nanomaterials Guan, Guijian; Han, Ming‐Yong Advanced Science, Vol. 6, Issue 23 https://doi.org/10.1002/advs.201901837	journal	September 2019
Fluorine-free preparation of titanium carbide MXene quantum dots with high near-infrared photothermal performances for cancer therapy Yu, Xinghua; Cai, Xingke; Cui, Haodong Nanoscale, Vol. 9, Issue 45 https://doi.org/10.1039/c7nr05997c	journal	January 2017
Photochemical and oxidative cyclisation of tetraphenylpyrroles Ferguson, Jayne L.; Squire, Marie A.; Fitchett, Christopher M. Organic & Biomolecular Chemistry, Vol. 15, Issue 44 https://doi.org/10.1039/c7ob02537h	journal	January 2017
Scalable transfer of vertical graphene nanosheets for flexible supercapacitor applications Sahoo, Gopinath; Ghosh, Subrata; Polaki, S. R. Nanotechnology, Vol. 28, Issue 41 https://doi.org/10.1088/1361-6528/aa8252	journal	September 2017
Synthesis of Nitrogen-Doped Two-Dimensional Ti ₃ C ₂ with Enhanced Electrochemical Performance Tang, Yi; Zhu, Jianfeng; Wu, Wenling Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.0041706jes	journal	January 2017
Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries Xu, Xiaoming; Xiong, Fangyu; Meng, Jiashen Advanced Functional Materials, Vol. 30, Issue 10 https://doi.org/10.1002/adfm.201904398	journal	January 2020
Extraordinary Areal and Volumetric Performance of Flexible Solid-State Micro-Supercapacitors Based on Highly Conductive Freestanding Ti ₃ C ₂ T _x Films Huang, Haichao; Su, Hai; Zhang, Haitao Advanced Electronic Materials, Vol. 4, Issue 8 https://doi.org/10.1002/aelm.201800179	journal	June 2018
Emergent Pseudocapacitance of 2D Nanomaterials Yu, Xu; Yun, Sol; Yeon, Jeong Seok Advanced Energy Materials, Vol. 8, Issue 13 https://doi.org/10.1002/aenm.201702930	journal	February 2018
Automated Scalpel Patterning of Solution Processed Thin Films for Fabrication of Transparent MXene Microsupercapacitors Salles, Pol; Quain, Evan; Kurra, Narendra Small, Vol. 14, Issue 44 https://doi.org/10.1002/smll.201802864	journal	October 2018
Amorphous 2D materials containing a conjugated-polymer network Yano, Shoichiro; Sato, Kosuke; Suzuki, Jumpei Communications Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/s42004-019-0201-9	journal	August 2019
Recent advances in inorganic 2D materials and their applications in lithium and sodium batteries Shi, Le; Zhao, Tianshou Journal of Materials Chemistry A, Vol. 5, Issue 8 https://doi.org/10.1039/c6ta09831b	journal	January 2017
Two dimensional oxygen-vacancy-rich Co ₃ O ₄ nanosheets with excellent supercapacitor performances Xiang, Kun; Xu, Zhicheng; Qu, Tingting Chemical Communications, Vol. 53, Issue 92 https://doi.org/10.1039/c7cc07515d	journal	January 2017
Ultrathin VO ₂ nanosheets self-assembled into 3D micro/nano-structured hierarchical porous sponge-like micro-bundles for long-life and high-rate Li-ion batteries Liu, Pengcheng; Xu, Yuan; Zhu, Kongjun Journal of Materials Chemistry A, Vol. 5, Issue 18 https://doi.org/10.1039/c7ta00270j	journal	January 2017
Self-assembled two-dimensional copper oxide nanosheet bundles as an efficient oxygen evolution reaction (OER) electrocatalyst for water splitting applications Pawar, Sambhaji M.; Pawar, Bharati S.; Hou, Bo Journal of Materials Chemistry A, Vol. 5, Issue 25 https://doi.org/10.1039/c7ta02835k	journal	January 2017
Silicon quantum dot-assisted synthesis of MoS ₂ /rGO sandwich structures with excellent supercapacitive performance Wu, Jinzhu; Li, Beibei; Feng, Yaxiu New Journal of Chemistry, Vol. 43, Issue 22 https://doi.org/10.1039/c9nj01232j	journal	January 2019
Modulation of the electronic properties of pristine and AlP-codoped stanene monolayers by the adsorption of CH ₂ O and CH ₄ molecules: a DFT study Abbasi, Amirali Materials Research Express, Vol. 6, Issue 7 https://doi.org/10.1088/2053-1591/ab1199	journal	April 2019
A Review on Flexible and Transparent Energy Storage System Li, Jie; Jiang, Qianqian; Yuan, Nannan Materials, Vol. 11, Issue 11 https://doi.org/10.3390/ma11112280	journal	November 2018

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