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Title: Hierarchically Superstructured Prussian Blue Analogues: Spontaneous Assembly Synthesis and Applications as Pseudocapacitive Materials

Journal Article · · ChemSusChem (Online)
 [1];  [2];  [3];  [1];  [4];  [1];  [5]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. ORNLOak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Univ. of Tennessee, Knoxville, TN (United States)
  4. Wuhan Univ. (China)
  5. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Hierarchically superstructured Prussian blue analogues (hexa- conventional hybrid graphene/MnO2 nanostructured textiles. cyanoferrate, M = NiII, CoII and CuII) are synthesized through Because sodium or potassium ions are involved in energy stor- a spontaneous assembly technique. In sharp contrast to mac- age processes, more environmentally neutral electrolytes can roporous-only Prussian blue analogues, the hierarchically su- be utilized, making the superstructured porous Prussian blue perstructured porous Prussian blue materials are demonstrated analogues a great contender for applications as high-per- to possess a high capacitance, which is similar to those of the formance pseudocapacitors.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1286909
Journal Information:
ChemSusChem (Online), Vol. 8, Issue 1; ISSN 1864-564X
Publisher:
ChemPubSoc EuropeCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 49 works
Citation information provided by
Web of Science

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An advanced aqueous sodium-ion supercapacitor with a manganous hexacyanoferrate cathode and a Fe 3 O 4 /rGO anode journal January 2015
Fabrication of an advanced asymmetric supercapacitor based on a microcubical PB@MnO 2 hybrid and PANI/GNP composite with excellent electrochemical behaviour journal January 2017
Concentration as a trigger to improve electrocatalytic activity of a Prussian blue analogue in glucose oxidation journal January 2019
Prussian Blue Analogue Mesoframes for Enhanced Aqueous Sodium-ion Storage journal January 2018
Facile synthesis of Mesoporouscobalt Hexacyanoferrate Nanocubes for High-Performance Supercapacitors journal August 2017