Materials Data on Ag9(PbO3)4 by Materials Project
Ag9(PbO3)4 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are eighteen inequivalent Ag+1.11+ sites. In the first Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. There are one shorter (2.13 Å) and one longer (2.14 Å) Ag–O bond lengths. In the second Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.14 Å. In the third Ag+1.11+ site, Ag+1.11+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.25–2.35 Å. In the fourth Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.14 Å. In the fifth Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.14 Å. In the sixth Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.14 Å. In the seventh Ag+1.11+ site, Ag+1.11+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are one shorter (2.25 Å) and two longer (2.34 Å) Ag–O bond lengths. In the eighth Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.14 Å. In the ninth Ag+1.11+ site, Ag+1.11+ is bonded in a trigonal planar geometry to three O2- atoms. All Ag–O bond lengths are 2.31 Å. In the tenth Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.15 Å. In the eleventh Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. There are one shorter (2.14 Å) and one longer (2.15 Å) Ag–O bond lengths. In the twelfth Ag+1.11+ site, Ag+1.11+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.25–2.35 Å. In the thirteenth Ag+1.11+ site, Ag+1.11+ is bonded in a distorted trigonal non-coplanar geometry to three O2- atoms. There are two shorter (2.31 Å) and one longer (2.33 Å) Ag–O bond lengths. In the fourteenth Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.14 Å. In the fifteenth Ag+1.11+ site, Ag+1.11+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.14 Å. In the sixteenth Ag+1.11+ site, Ag+1.11+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.25–2.34 Å. In the seventeenth Ag+1.11+ site, Ag+1.11+ is bonded in a trigonal planar geometry to three O2- atoms. There are one shorter (2.30 Å) and two longer (2.32 Å) Ag–O bond lengths. In the eighteenth Ag+1.11+ site, Ag+1.11+ is bonded in a trigonal planar geometry to three O2- atoms. There are one shorter (2.31 Å) and two longer (2.32 Å) Ag–O bond lengths. There are eight inequivalent Pb+3.50+ sites. In the first Pb+3.50+ site, Pb+3.50+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb–O bond distances ranging from 2.20–2.29 Å. In the second Pb+3.50+ site, Pb+3.50+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb–O bond distances ranging from 2.21–2.28 Å. In the third Pb+3.50+ site, Pb+3.50+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb–O bond distances ranging from 2.20–2.28 Å. In the fourth Pb+3.50+ site, Pb+3.50+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb–O bond distances ranging from 2.21–2.28 Å. In the fifth Pb+3.50+ site, Pb+3.50+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb–O bond distances ranging from 2.20–2.28 Å. In the sixth Pb+3.50+ site, Pb+3.50+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb–O bond distances ranging from 2.20–2.28 Å. In the seventh Pb+3.50+ site, Pb+3.50+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb–O bond distances ranging from 2.21–2.28 Å. In the eighth Pb+3.50+ site, Pb+3.50+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb–O bond distances ranging from 2.21–2.28 Å. There are twenty-four inequivalent O2- sites. In the first O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the second O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the third O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the fourth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the fifth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the sixth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the seventh O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the eighth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form corner-sharing OAg2Pb2 tetrahedra. In the ninth O2- site, O2- is bonded in a trigonal non-coplanar geometry to one Ag+1.11+ and two Pb+3.50+ atoms. In the tenth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form corner-sharing OAg2Pb2 tetrahedra. In the eleventh O2- site, O2- is bonded in a trigonal non-coplanar geometry to one Ag+1.11+ and two Pb+3.50+ atoms. In the twelfth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the thirteenth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the fourteenth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the fifteenth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the sixteenth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the seventeenth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the eighteenth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the nineteenth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the twentieth O2- site, O2- is bonded in a trigonal non-coplanar geometry to one Ag+1.11+ and two Pb+3.50+ atoms. In the twenty-first O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form corner-sharing OAg2Pb2 tetrahedra. In the twenty-second O2- site, O2- is bonded in a trigonal non-coplanar geometry to one Ag+1.11+ and two Pb+3.50+ atoms. In the twenty-third O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form corner-sharing OAg2Pb2 tetrahedra. In the twenty-fourth O2- site, O2- is bonded to two Ag+1.11+ and two Pb+3.50+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1282663
- Report Number(s):
- mp-675327
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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