Uniform second Li ion intercalation in solid state ϵ-LiVOPO4

Wangoh, Linda W.; Sallis, Shawn; Wiaderek, Kamila M.; Lin, Yuh-Chieh; Wen, Bohua; Quackenbush, Nicholas F.; Chernova, Natasha A.; Guo, Jinghua; Ma, Lu; Wu, Tianpin; Lee, Tien-Lin; Schlueter, Christoph; Ong, Shyue Ping; Chapman, Karena W.; Whittingham, M. Stanley; Piper, Louis F.  J.

doi:10.1063/1.4960452

Title: Uniform second Li ion intercalation in solid state ϵ-LiVOPO4

Journal Article · Thu Aug 04 00:00:00 EDT 2016 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4960452· OSTI ID:1387944

Wangoh, Linda W. ^[1]; Sallis, Shawn ^[2]; Wiaderek, Kamila M. ^[3]; Lin, Yuh-Chieh ^[4]; Wen, Bohua ^[5]; Quackenbush, Nicholas F. ^[1]; Chernova, Natasha A. ^[5]; Guo, Jinghua ^[6]; Ma, Lu ^[3]; Wu, Tianpin ^[3]; Lee, Tien-Lin ^[7]; Schlueter, Christoph ^[7]; Ong, Shyue Ping ^[4]; Chapman, Karena W. ^[3]; Whittingham, M. Stanley ^[5];

^[8]

Binghamton Univ., NY (United States). Dept. of Physics, Applied Physics and Astronomy
Binghamton Univ., NY (United States). Materials Science and Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Univ. of California, San Diego, CA (United States). Dept. of NanoEngineering
Binghamton Univ., NY (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Diamond Light Source, Ltd.
Binghamton Univ., NY (United States). Dept. of Physics, Applied Physics and Astronomy, and Materials Science and Engineering

Full, reversible intercalation of two Li⁺ has not yet been achieved in promising VOPO₄ electrodes. A pronounced Li⁺ gradient has been reported in the low voltage window (i.e., second lithium reaction) that is thought to originate from disrupted kinetics in the high voltage regime (i.e., first lithium reaction). Here, we employ a combination of hard and soft x–ray photoelectron and absorption spectroscopy techniques to depth profile solid state synthesized LiVOPO₄ cycled within the low voltage window only. Analysis of the vanadium environment revealed no evidence of a Li⁺ gradient, which combined with almost full theoretical capacity confirms that disrupted kinetics in the high voltage window are responsible for hindering full two lithium insertion. Furthermore, we argue that the uniform Li⁺ intercalation is a prerequisite for the formation of intermediate phases Li1.50VOPO₄ and Li_1.75VOPO₄. The evolution from LiVOPO₄ to Li₂VOPO₄ via the intermediate phases is confirmed by direct comparison between O K–edge absorption spectroscopy and density functional theory.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001294; AC02-05CH11231; SC0012583

OSTI ID:: 1387944

Alternate ID(s):: OSTI ID: 1282420

Journal Information:: Applied Physics Letters, Vol. 109, Issue 5; Related Information: NECCES partners with Stony Brook University (lead); Argonne National Laboratory; Binghamton University; Brookhaven National University; University of California, San Diego; University of Cambridge, UK; Lawrence Berkeley National Laboratory; Massachusetts Institute of Technology; University of Michigan; Rutgers University; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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References (15)

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On the Balance of Intercalation and Conversion Reactions in Battery Cathodes Hannah, Daniel C.; Sai Gautam, Gopalakrishnan; Canepa, Pieremanuele Advanced Energy Materials, Vol. 8, Issue 20 https://doi.org/10.1002/aenm.201800379	journal	April 2018
A Two-Color Beamline for Electron Spectroscopies at Diamond Light Source Lee, Tien-Lin; Duncan, David A. Synchrotron Radiation News, Vol. 31, Issue 4 https://doi.org/10.1080/08940886.2018.1483653	journal	July 2018
Evidence of a second-order Peierls-driven metal-insulator transition in crystalline NbO 2 Wahila, Matthew J.; Paez, Galo; Singh, Christopher N. Physical Review Materials, Vol. 3, Issue 7 https://doi.org/10.1103/physrevmaterials.3.074602	journal	July 2019
Idea of thin-film beam splitters for two-colour beamlines Abe, Hitoshi Journal of Synchrotron Radiation, Vol. 26, Issue 5 https://doi.org/10.1107/s160057751900972x	journal	August 2019
On the Balance of Intercalation and Conversion Reactions in Battery Cathodes Hannah, Daniel C.; Gautam, Gopalakrishnan Sai; Canepa, Pieremanuele arXiv https://doi.org/10.48550/arxiv.1804.06704	text	January 2018

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