Large Fermi Surface of Heavy Electrons at the Border of Mott Insulating State in NiS2

Friedemann, S.; Chang, H.; Gamża, M. B.; Reiss, P.; Chen, X.; Alireza, P.; Coniglio, W. A.; Graf, D.; Tozer, S.; Grosche, F. M.

doi:10.1038/srep25335

Title: Large Fermi Surface of Heavy Electrons at the Border of Mott Insulating State in NiS₂

Journal Article · Thu May 12 00:00:00 EDT 2016 · Scientific Reports

DOI:https://doi.org/10.1038/srep25335· OSTI ID:1282120

Friedemann, S. ^[1]; Chang, H. ^[2]; Gamża, M. B. ^[3]; Reiss, P. ^[2]; Chen, X. ^[2]; Alireza, P. ^[2]; Coniglio, W. A. ^[4]; Graf, D. ^[4]; Tozer, S. ^[4]; Grosche, F. M. ^[2]

Univ. of Bristol, Bristol (United Kingdom). HH Wills Laboratory
Univ. of Cambridge, Cambridge (United Kingdom). Cavendish Laboratory
Univ. of Central Lancashire, Preston (United Kingdom). Jeremiah Horrocks Inst. for Mathematics, Physics and Astronomy; Univ. of London, Egham (United Kingdom). Dept. of Physics, Royal Holloway
Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)

One early triumph of quantum physics is the explanation why some materials are metallic whereas others are insulating. While a treatment based on single electron states is correct for most materials this approach can fail spectacularly, when the electrostatic repulsion between electrons causes strong correlations. Not only can these favor new and subtle forms of matter, such as magnetism or superconductivity, they can even cause the electrons in a half-filled energy band to lock into position, producing a correlated, or Mott insulator. The transition into the Mott insulating state raises important fundamental questions. Foremost among these is the fate of the electronic Fermi surface and the associated charge carrier mass, as the Mott transition is approached. We report the first direct observation of the Fermi surface on the metallic side of a Mott insulating transition by high pressure quantum oscillatory measurements in NiS₂. We find our results point at a large Fermi surface consistent with Luttinger's theorem and a strongly enhanced quasiparticle effective mass. These two findings are in line with central tenets of the Brinkman-Rice picture of the correlated metal near the Mott insulating state and rule out alternative scenarios in which the carrier concentration vanishes continuously at the metal-insulator transition.

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Research Organization:: Florida State Univ., Tallahassee, FL (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0001979; DMR-1157490; EP/K012894/1

OSTI ID:: 1282120

Journal Information:: Scientific Reports, Vol. 6; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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References (45)

Electronic Properties of NiS _{2- x} Se _x Single Crystals: From Magnetic Mott−Hubbard Insulators to Normal Metals Honig, J. M.; Spałek, Jozef Chemistry of Materials, Vol. 10, Issue 10 https://doi.org/10.1021/cm9803509	journal	October 1998
Spin Structure and Magnetic Properties of NiS ₂ Kikuchi, Katsuya; Miyadai, Tomonao; Fukui, Tsunaomi Journal of the Physical Society of Japan, Vol. 44, Issue 2 https://doi.org/10.1143/jpsj.44.410	journal	February 1978
Pressure effects on the magnetic transition temperatures of NiS2 Mori, N.; Watanabe, T. Solid State Communications, Vol. 27, Issue 5 https://doi.org/10.1016/0038-1098(78)90396-4	journal	August 1978
Atomic diffusion in the surface state of Mott insulator NiS2 Clark, C.; Friedemann, S. Journal of Magnetism and Magnetic Materials, Vol. 400 https://doi.org/10.1016/j.jmmm.2015.08.012	journal	February 2016
Metal-insulator transition in NiS ₂ Wilson, J. A.; Pitt, G. D. The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics, Vol. 23, Issue 186 https://doi.org/10.1080/14786437108217003	journal	June 1971
Quantum oscillations and the Fermi surface in an underdoped high-Tc superconductor Doiron-Leyraud, Nicolas; Proust, Cyril; LeBoeuf, David Nature, Vol. 447, Issue 7144 https://doi.org/10.1038/nature05872	journal	May 2007
Antiferromagnetic metallic state of NiS2 Panissod, P.; Krill, G.; Vettier, C. Solid State Communications, Vol. 29, Issue 2 https://doi.org/10.1016/0038-1098(79)91104-9	journal	January 1979
Growth of nickel dichalcogenides crystals with pyrite structure from tellurium melts [NiS2, NiS2−xSex (x ≤ 0.7)] Yao, Xiaoqiang; Honig, Jurgen M. Materials Research Bulletin, Vol. 29, Issue 7 https://doi.org/10.1016/0025-5408(94)90195-3	journal	July 1994
Metal-insulator transition and magnetic properties in the NiS2−xSex system Sudo, S. Journal of Magnetism and Magnetic Materials, Vol. 114, Issue 1-2 https://doi.org/10.1016/0304-8853(92)90332-i	journal	August 1992
Insulator-metal transition in NiO Kawai, Naoto; Mochizuki, Sho-suke Solid State Communications, Vol. 9, Issue 16 https://doi.org/10.1016/0038-1098(71)90403-0	journal	August 1971
Patterned anvils for high pressure measurements at low temperature Welzel, Oliver P.; Grosche, F. Malte Review of Scientific Instruments, Vol. 82, Issue 3 https://doi.org/10.1063/1.3541793	journal	March 2011
Magnetic properties of pyrite type NiS2−xSex Miyadai, T.; Sudo, S.; Tazuke, Y. Journal of Magnetism and Magnetic Materials, Vol. 31-34 https://doi.org/10.1016/0304-8853(83)90270-6	journal	February 1983
Electron correlations in narrow energy bands Hubbard, J. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 276, Issue 1365, p. 238-257 https://doi.org/10.1098/rspa.1963.0204	journal	November 1963
Magnetotransport studies of the organic superconductor kappa -(BEDT-TTF) ₂ Cu(NCS) ₂ under pressure: the relationship between carrier effective mass and critical temperature Caulfield, J.; Lubczynski, W.; Pratt, F. L. Journal of Physics: Condensed Matter, Vol. 6, Issue 15 https://doi.org/10.1088/0953-8984/6/15/013	journal	April 1994
Ab initio density functional studies of transition-metal sulphides: II. Electronic structure Raybaud, P.; Hafner, J.; Kresse, G. Journal of Physics: Condensed Matter, Vol. 9, Issue 50 https://doi.org/10.1088/0953-8984/9/50/014	journal	December 1997
Electronic and magnetic properties of the pyrite-structure compound NiS ₂ : influence of vacancies and copper impurities Krill, G.; Lapierre, M. F.; Robert, C. Journal of Physics C: Solid State Physics, Vol. 9, Issue 5 https://doi.org/10.1088/0022-3719/9/5/016	journal	March 1976
Electronic and magnetic properties of NiS2, NiSSe and NiSe2 by a combination of theoretical methods Schuster, Cosima; Gatti, Matteo; Rubio, Angel The European Physical Journal B, Vol. 85, Issue 9 https://doi.org/10.1140/epjb/e2012-30384-7	journal	September 2012
The Basis of the Electron Theory of Metals, with Special Reference to the Transition Metals Mott, N. F. Proceedings of the Physical Society. Section A, Vol. 62, Issue 7 https://doi.org/10.1088/0370-1298/62/7/303	journal	July 1949
Electronic structure of 3d pyrite- and marcasite-type sulphides Bullett, D. W. Journal of Physics C: Solid State Physics, Vol. 15, Issue 30 https://doi.org/10.1088/0022-3719/15/30/010	journal	October 1982
Susceptibility measurements at high pressures using a microcoil system in an anvil cell Alireza, Patricia Lebre; Julian, Stephen R. Review of Scientific Instruments, Vol. 74, Issue 11 https://doi.org/10.1063/1.1614861	journal	November 2003
Metal-insulator transitions Imada, Masatoshi; Fujimori, Atsushi; Tokura, Yoshinori Reviews of Modern Physics, Vol. 70, Issue 4, p. 1039-1263 https://doi.org/10.1103/RevModPhys.70.1039	journal	October 1998
Evolution of the spectral function in Mott-Hubbard systems with $d^{1}$ configuration Fujimori, A.; Hase, I.; Namatame, H. Physical Review Letters, Vol. 69, Issue 12 https://doi.org/10.1103/PhysRevLett.69.1796	journal	September 1992
Hubbard model in infinite dimensions Georges, Antoine; Kotliar, Gabriel Physical Review B, Vol. 45, Issue 12 https://doi.org/10.1103/PhysRevB.45.6479	journal	March 1992
Application of Gutzwiller's Variational Method to the Metal-Insulator Transition Brinkman, W. F.; Rice, T. M. Physical Review B, Vol. 2, Issue 10 https://doi.org/10.1103/PhysRevB.2.4302	journal	November 1970
Dynamical mean-field theory of strongly correlated fermion systems and the limit of infinite dimensions Georges, Antoine; Kotliar, Gabriel; Krauth, Werner Reviews of Modern Physics, Vol. 68, Issue 1 https://doi.org/10.1103/RevModPhys.68.13	journal	January 1996
Lattice Contraction Driven Insulator-Metal Transition in the $d = \infty$ Local Approximation Majumdar, Pinaki; Krishnamurthy, H. R. Physical Review Letters, Vol. 73, Issue 11 https://doi.org/10.1103/PhysRevLett.73.1525	journal	September 1994
Fermi Surface and Some Simple Equilibrium Properties of a System of Interacting Fermions Luttinger, J. M. Physical Review, Vol. 119, Issue 4 https://doi.org/10.1103/PhysRev.119.1153	journal	August 1960
Metal-insulator crossover behavior at the surface of ${NiS}_{2}$ Sarma, D. D.; Krishnakumar, S. R.; Weschke, E. Physical Review B, Vol. 67, Issue 15 https://doi.org/10.1103/PhysRevB.67.155112	journal	April 2003
Electronic structure and the metal-insulator transition in $Ni S_{2 - x} {Se}_{x}$ Matsuura, A. Y.; Shen, Z. -X.; Dessau, D. S. Physical Review B, Vol. 53, Issue 12 https://doi.org/10.1103/PhysRevB.53.R7584	journal	March 1996
Metal-insulator transition in ${NiS}_{2 - x} {Se}_{x}$ and the local impurity self-consistent approximation model Matsuura, A. Y.; Watanabe, H.; Kim, C. Physical Review B, Vol. 58, Issue 7 https://doi.org/10.1103/PhysRevB.58.3690	journal	August 1998
Resonant photoemission study of pyrite-type ${NiS}_{2}$ , ${CoS}_{2}$ and ${FeS}_{2}$ Fujimori, A.; Mamiya, K.; Mizokawa, T. Physical Review B, Vol. 54, Issue 23 https://doi.org/10.1103/PhysRevB.54.16329	journal	December 1996
Photoemission study of the metal-insulator transition in ${NiS}_{2 - x} {Se}_{x}$ Mamiya, K.; Mizokawa, T.; Fujimori, A. Physical Review B, Vol. 58, Issue 15 https://doi.org/10.1103/PhysRevB.58.9611	journal	October 1998
Direct Observation of the Bandwidth Control Mott Transition in the ${NiS}_{2 - x} {Se}_{x}$ Multiband System Xu, H. C.; Zhang, Y.; Xu, M. Physical Review Letters, Vol. 112, Issue 8 https://doi.org/10.1103/PhysRevLett.112.087603	journal	February 2014
Neutron Diffraction Study of NiS ₂ with Pyrite Structure Miyadai, Tomonao; Takizawa, Kôichi; Nagata, Hideo Journal of the Physical Society of Japan, Vol. 38, Issue 1 https://doi.org/10.1143/JPSJ.38.115	journal	January 1975
Electrical and Optical Properties of Ni $S_{2}$ Kautz, R. L.; Dresselhaus, M. S.; Adler, D. Physical Review B, Vol. 6, Issue 6 https://doi.org/10.1103/PhysRevB.6.2078	journal	September 1972
Metal-insulator transition in ${NiS}_{2 - x} {Se}_{x}$ Kuneš, J.; Baldassarre, L.; Schächner, B. Physical Review B, Vol. 81, Issue 3 https://doi.org/10.1103/PhysRevB.81.035122	journal	January 2010
Magnetism, structure, and charge correlation at a pressure-induced Mott-Hubbard insulator-metal transition Feng, Yejun; Jaramillo, R.; Banerjee, A. Physical Review B, Vol. 83, Issue 3 https://doi.org/10.1103/PhysRevB.83.035106	journal	January 2011
The electronic structures of the pyrite-type disulphides (MS2, where M = Mn, Fe, Co, Ni, Cu, Zn) and the bulk properties of pyrite from local density approximation (LDA) band structure calculations Temmerman, W. M.; Durham, P. J.; Vaughan, D. J. Physics and Chemistry of Minerals, Vol. 20, Issue 4 https://doi.org/10.1007/BF00208138	journal	September 1993
Band gaps and electronic structure of transition-metal compounds Zaanen, J.; Sawatzky, G. A.; Allen, J. W. Physical Review Letters, Vol. 55, Issue 4 https://doi.org/10.1103/PhysRevLett.55.418	journal	July 1985
Metal-Insulator Transition and Itinerant Antiferromagnetism in NiS _{2 - x} Se _x Pyrite Miyasaka, Shigeki; Takagi, Hidenori; Sekine, Yoshiaki Journal of the Physical Society of Japan, Vol. 69, Issue 10 https://doi.org/10.1143/JPSJ.69.3166	journal	October 2000
Metal-insulator transitions Paesler, Michael Journal of Non-Crystalline Solids, Vol. 130, Issue 1 https://doi.org/10.1016/0022-3093(91)90162-y	journal	June 1991
Research data supporting "Large Fermi Surface of Heavy Electrons at the Border of Mott Insulating State in NiS2" Friedemann, S.; Chang, H.; Gamża, M. B. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.68973	dataset	January 2016
Quantum oscillations and the Fermi surface in an underdoped high-Tc superconductor Doiron-Leyraud, Nicolas; Proust, Cyril; LeBoeuf, David arXiv https://doi.org/10.48550/arxiv.0801.1281	text	January 2008
Metal-insulator transition in NiS$_{2-x}$Se$_x$ Kunes, J.; Baldassarre, L.; Schachner, B. arXiv https://doi.org/10.48550/arxiv.0907.1745	text	January 2009
Atomic Diffusion in the Surface State of Mott Insulator NiS2 Clark, C.; Friedemann, S. arXiv https://doi.org/10.48550/arxiv.1508.05020	text	January 2015

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Silica Restricting the Sulfur Volatilization of Nickel Sulfide for High‐Performance Lithium‐Ion Batteries Li, Qidong; Li, Li; Wu, Peijie Advanced Energy Materials, Vol. 9, Issue 43 https://doi.org/10.1002/aenm.201901153	journal	October 2019
Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials Kim, So Yeun; Lee, Min-Cheol; Han, Garam Advanced Materials, Vol. 30, Issue 42 https://doi.org/10.1002/adma.201704777	journal	May 2018
Strain-engineering Mott-insulating $La_2CuO_4$ Ivashko, O.; Horio, M.; Wan, W. Nature Publishing Group https://doi.org/10.5167/uzh-171139	text	January 2019

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Title: Large Fermi Surface of Heavy Electrons at the Border of Mott Insulating State in NiS2

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Title: Large Fermi Surface of Heavy Electrons at the Border of Mott Insulating State in NiS₂