Autoignition response of n-butanol and its blend with primary reference fuel constituents of gasoline.

Kumar, Kamal; Zhang, Yu; Sung, Chi -Jen; Pitz, William J.

doi:10.1016/j.combustflame.2015.02.014

Title: Autoignition response of n-butanol and its blend with primary reference fuel constituents of gasoline.

Journal Article · Mon Apr 13 00:00:00 EDT 2015 · Combustion and Flame

DOI:https://doi.org/10.1016/j.combustflame.2015.02.014· OSTI ID:1281683

Kumar, Kamal ^[1]; Zhang, Yu ^[1]; Sung, Chi -Jen ^[1]; Pitz, William J. ^[2]

Univ. of Connecticut, Storrs, CT (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

We study the influence of blending n-butanol on the ignition delay times of n-heptane and iso-octane, the primary reference fuels for gasoline. The ignition delay times are measured using a rapid compression machine, with an emphasis on the low-to-intermediate temperature conditions. The experiments are conducted at equivalence ratios of 0.4 and 1.0, for a compressed pressure of 20 bar, with the temperatures at the end of compression ranging from 613 K to 979 K. The effect of n-butanol addition on the development of the two-stage ignition characteristics for the two primary reference fuels is also examined. The experimental results are compared to predictions obtained using a detailed chemical kinetic mechanism, which has been obtained by a systematic merger of previously reported base models for the combustion of the individual fuel constituents. In conclusion, a sensitivity analysis on the base, and the merged models, is also performed to understand the dependence of autoignition delay times on the model parameters.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Combustion Energy Frontier Research Center (CEFRC); Lawrence Livermore National Lab., Livermore, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC52-07NA27344; SC0001198

OSTI ID:: 1281683

Alternate ID(s):: OSTI ID: 1246735

Report Number(s):: LLNL-JRNL-591474

Journal Information:: Combustion and Flame, Vol. 162, Issue 6; ISSN 0010-2180

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 20 works

Citation information provided by
Web of Science

References (119)

The role of butanol in the development of sustainable fuel technologies Harvey, Benjamin G.; Meylemans, Heather A. Journal of Chemical Technology & Biotechnology, Vol. 86, Issue 1 https://doi.org/10.1002/jctb.2540	journal	December 2010
Fermentative production of butanol—the academic perspective Dürre, Peter Current Opinion in Biotechnology, Vol. 22, Issue 3 https://doi.org/10.1016/j.copbio.2011.04.010	journal	June 2011
Bio-butanol vs. bio-ethanol: A technical and economic assessment for corn and switchgrass fermented by yeast or Clostridium acetobutylicum Pfromm, Peter H.; Amanor-Boadu, Vincent; Nelson, Richard Biomass and Bioenergy, Vol. 34, Issue 4 https://doi.org/10.1016/j.biombioe.2009.12.017	journal	April 2010
Utilization of palm oil alkyl esters as an additive in ethanol–diesel and butanol–diesel blends Chotwichien, Areerat; Luengnaruemitchai, Apanee; Jai-In, Samai Fuel, Vol. 88, Issue 9 https://doi.org/10.1016/j.fuel.2009.02.047	journal	September 2009
Effect of fuel temperature on in-nozzle cavitation and spray formation of liquid hydrocarbons and alcohols from a real-size optical injector for direct-injection spark-ignition engines Aleiferis, P. G.; Serras-Pereira, J.; Augoye, A. International Journal of Heat and Mass Transfer, Vol. 53, Issue 21-22 https://doi.org/10.1016/j.ijheatmasstransfer.2010.06.033	journal	October 2010
Renewable Oxygenate Blending Effects on Gasoline Properties Christensen, Earl; Yanowitz, Janet; Ratcliff, Matthew Energy & Fuels, Vol. 25, Issue 10 https://doi.org/10.1021/ef2010089	journal	October 2011
Vapor Pressures of Alcohol−Gasoline Blends Andersen, V. F.; Anderson, J. E.; Wallington, T. J. Energy & Fuels, Vol. 24, Issue 6 https://doi.org/10.1021/ef100254w	journal	June 2010
Distillation Curves for Alcohol−Gasoline Blends Andersen, V. F.; Anderson, J. E.; Wallington, T. J. Energy & Fuels, Vol. 24, Issue 4 https://doi.org/10.1021/ef9014795	journal	April 2010
Fuel Effects on Reactivity Controlled Compression Ignition (RCCI) Combustion at Low Load Hanson, Reed; Kokjohn, Sage; Splitter, Derek SAE International Journal of Engines, Vol. 4, Issue 1, p. 394-411 https://doi.org/10.4271/2011-01-0361	journal	April 2011
Fuel Reactivity Controlled Compression Ignition (RCCI) Combustion in Light- and Heavy-Duty Engines Kokjohn, Sage; Hanson, Reed; Splitter, Derek SAE International Journal of Engines, Vol. 4, Issue 1, p. 360-374 https://doi.org/10.4271/2011-01-0357	journal	April 2011
Fuel reactivity controlled compression ignition (RCCI): a pathway to controlled high-efficiency clean combustion Kokjohn, S. L.; Hanson, R. M.; Splitter, D. A. International Journal of Engine Research, Vol. 12, Issue 3 https://doi.org/10.1177/1468087411401548	journal	June 2011
Directions in internal combustion engine research Reitz, Rolf D. Combustion and Flame, Vol. 160, Issue 1 https://doi.org/10.1016/j.combustflame.2012.11.002	journal	January 2013
Alcohol combustion chemistry Sarathy, S. Mani; Oßwald, Patrick; Hansen, Nils Progress in Energy and Combustion Science, Vol. 44 https://doi.org/10.1016/j.pecs.2014.04.003	journal	October 2014
Oxidation Kinetics of Mixtures of Iso-Octane with Ethanol or Butanol in a Jet-Stirred Reactor: Experimental and Modeling Study Dagaut, P.; Togbé, C. Combustion Science and Technology, Vol. 184, Issue 7-8 https://doi.org/10.1080/00102202.2012.663993	journal	July 2012
Auto-ignition and combustion characteristics in HCCI and JSR using 1-butanol/n-heptane and ethanol/n-heptane blends Saisirirat, P.; Togbé, C.; Chanchaona, S. Proceedings of the Combustion Institute, Vol. 33, Issue 2 https://doi.org/10.1016/j.proci.2010.07.016	journal	January 2011
Experimental and Modeling Study of the Kinetics of Oxidation of Simple Biodiesel−Biobutanol Surrogates: Methyl Octanoate−Butanol Mixtures Togbé, C.; Dayma, G.; Mzé-Ahmed, A. Energy & Fuels, Vol. 24, Issue 7 https://doi.org/10.1021/ef100484q	journal	July 2010
An experimental and kinetic modeling study of n-butanol combustion Sarathy, S. M.; Thomson, M. J.; Togbé, C. Combustion and Flame, Vol. 156, Issue 4 https://doi.org/10.1016/j.combustflame.2008.11.019	journal	April 2009
Experimental and Modeling Study of the Kinetics of Oxidation of Butanol− n- Heptane Mixtures in a Jet-stirred Reactor Dagaut, Philippe; Togbé, Casimir Energy & Fuels, Vol. 23, Issue 7 https://doi.org/10.1021/ef900261f	journal	July 2009
Oxidation kinetics of butanol–gasoline surrogate mixtures in a jet-stirred reactor: Experimental and modeling study Dagaut, Philippe; Togbé, Casimir Fuel, Vol. 87, Issue 15-16 https://doi.org/10.1016/j.fuel.2008.05.008	journal	November 2008
A shock tube and chemical kinetic modeling study of the pyrolysis and oxidation of butanols Yasunaga, Kenji; Mikajiri, Takahiro; Sarathy, S. Mani Combustion and Flame, Vol. 159, Issue 6 https://doi.org/10.1016/j.combustflame.2012.02.008	journal	June 2012
Multi-species measurements in 1-butanol pyrolysis behind reflected shock waves Stranic, Ivo; Pyun, Sung Hyun; Davidson, David Frank Combustion and Flame, Vol. 159, Issue 11 https://doi.org/10.1016/j.combustflame.2012.06.005	journal	November 2012
Shock tube measurements of ignition delay times for the butanol isomers Stranic, Ivo; Chase, Deanna P.; Harmon, Joseph T. Combustion and Flame, Vol. 159, Issue 2 https://doi.org/10.1016/j.combustflame.2011.08.014	journal	February 2012
Shock Tube Study on the Thermal Decomposition of n -Butanol Rosado-Reyes, Claudette M.; Tsang, Wing The Journal of Physical Chemistry A, Vol. 116, Issue 40 https://doi.org/10.1021/jp305120h	journal	September 2012
Multispecies laser measurements of n-butanol pyrolysis behind reflected shock waves Cook, Robert D.; Davidson, David F.; Hanson, Ronald K. International Journal of Chemical Kinetics, Vol. 44, Issue 5 https://doi.org/10.1002/kin.20713	journal	January 2012
Role of peroxy chemistry in the high-pressure ignition of n-butanol – Experiments and detailed kinetic modelling Vranckx, S.; Heufer, K. A.; Lee, C. Combustion and Flame, Vol. 158, Issue 8 https://doi.org/10.1016/j.combustflame.2010.12.028	journal	August 2011
Shock tube investigations of ignition delays of n-butanol at elevated pressures between 770 and 1250K Heufer, K. A.; Fernandes, R. X.; Olivier, H. Proceedings of the Combustion Institute, Vol. 33, Issue 1 https://doi.org/10.1016/j.proci.2010.06.052	journal	January 2011
Bio-butanol: Combustion properties and detailed chemical kinetic model Black, G.; Curran, H. J.; Pichon, S. Combustion and Flame, Vol. 157, Issue 2 https://doi.org/10.1016/j.combustflame.2009.07.007	journal	February 2010
1-Butanol ignition delay times at low temperatures: An application of the constrained-reaction-volume strategy Zhu, Yangye; Davidson, David Frank; Hanson, Ronald K. Combustion and Flame, Vol. 161, Issue 3 https://doi.org/10.1016/j.combustflame.2013.06.028	journal	March 2014
Experimental and modeling study of the auto-ignition of n-heptane/n-butanol mixtures Zhang, Jiaxiang; Niu, Shaodong; Zhang, Yingjia Combustion and Flame, Vol. 160, Issue 1 https://doi.org/10.1016/j.combustflame.2012.09.006	journal	January 2013
An experimental study on the formation of polycyclic aromatic hydrocarbons in laminar coflow non-premixed methane/air flames doped with four isomeric butanols Jin, Hanfeng; Wang, Yizun; Zhang, Kuiwen Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.05.107	journal	January 2013
NOx formation and flame velocity profiles of iso- and n-isomers of butane and butanol Chung, Gregory A.; Akih-Kumgeh, Benjamin; Watson, Graeme M. G. Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.06.114	journal	January 2013
Evolution of size distribution of nascent soot in n- and i-butanol flames Camacho, Joaquin; Lieb, Sydnie; Wang, Hai Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.05.100	journal	January 2013
Experimental determination of laminar burning velocity for butanol/iso-octane and ethanol/iso-octane blends for different initial pressures Broustail, G.; Halter, F.; Seers, P. Fuel, Vol. 106 https://doi.org/10.1016/j.fuel.2012.10.066	journal	April 2013
Detailed kinetic modeling of the combustion of the four butanol isomers in premixed low-pressure flames Frassoldati, Alessio; Grana, Roberto; Faravelli, Tiziano Combustion and Flame, Vol. 159, Issue 7 https://doi.org/10.1016/j.combustflame.2012.03.002	journal	July 2012
Experimental investigation of bio-butanol laminar non-premixed flamelets Agathou, Maria S.; Kyritsis, Dimitrios C. Applied Energy, Vol. 93 https://doi.org/10.1016/j.apenergy.2011.12.060	journal	May 2012
Flame propagation of butanol isomers/air mixtures Veloo, Peter S.; Egolfopoulos, Fokion N. Proceedings of the Combustion Institute, Vol. 33, Issue 1 https://doi.org/10.1016/j.proci.2010.06.163	journal	January 2011
Combustion of butanol isomers – A detailed molecular beam mass spectrometry investigation of their flame chemistry Oßwald, Patrick; Güldenberg, Hanna; Kohse-Höinghaus, Katharina Combustion and Flame, Vol. 158, Issue 1 https://doi.org/10.1016/j.combustflame.2010.06.003	journal	January 2011
Non-premixed ignition, laminar flame propagation, and mechanism reduction of n-butanol, iso-butanol, and methyl butanoate Liu, Wei; Kelley, Andrew P.; Law, Chung K. Proceedings of the Combustion Institute, Vol. 33, Issue 1 https://doi.org/10.1016/j.proci.2010.05.084	journal	January 2011
A comparative experimental and computational study of methanol, ethanol, and n-butanol flames Veloo, Peter S.; Wang, Yang L.; Egolfopoulos, Fokion N. Combustion and Flame, Vol. 157, Issue 10 https://doi.org/10.1016/j.combustflame.2010.04.001	journal	October 2010
An experimental and kinetic modeling study of combustion of isomers of butanol Grana, Roberto; Frassoldati, Alessio; Faravelli, Tiziano Combustion and Flame, Vol. 157, Issue 11 https://doi.org/10.1016/j.combustflame.2010.05.009	journal	November 2010
Identification of combustion intermediates in isomeric fuel-rich premixed butanol–oxygen flames at low pressure Yang, B.; Oswald, P.; Li, Y. Combustion and Flame, Vol. 148, Issue 4 https://doi.org/10.1016/j.combustflame.2006.12.001	journal	March 2007
Experimental and kinetic modeling study of PAH formation in methane coflow diffusion flames doped with n-butanol Jin, Hanfeng; Cuoci, Alberto; Frassoldati, Alessio Combustion and Flame, Vol. 161, Issue 3 https://doi.org/10.1016/j.combustflame.2013.10.020	journal	March 2014
Sooting behaviors of n-butanol and n-dodecane blends Ghiassi, Hossein; Toth, Pal; Lighty, JoAnn S. Combustion and Flame, Vol. 161, Issue 3 https://doi.org/10.1016/j.combustflame.2013.10.011	journal	March 2014
An experimental and mechanistic study on the laminar flame speed, Markstein length and flame chemistry of the butanol isomers Wu, Fujia; Law, Chung K. Combustion and Flame, Vol. 160, Issue 12 https://doi.org/10.1016/j.combustflame.2013.06.015	journal	December 2013
Development of an n-heptane-n-butanol-PAH mechanism and its application for combustion and soot prediction Wang, Hu; Deneys Reitz, Rolf; Yao, Mingfa Combustion and Flame, Vol. 160, Issue 3 https://doi.org/10.1016/j.combustflame.2012.11.017	journal	March 2013
Experimental and Kinetic Modeling Study of n -Butanol Pyrolysis and Combustion Cai, Jianghuai; Zhang, Lidong; Zhang, Feng Energy & Fuels, Vol. 26, Issue 9 https://doi.org/10.1021/ef3011965	journal	September 2012
Relative Reactivities of the Isomeric Butanols and Ethanol in an Ignition Quality Tester Haas, Francis M.; Ramcharan, Amanda; Dryer, Frederick L. Energy & Fuels, Vol. 25, Issue 9 https://doi.org/10.1021/ef2008024	journal	September 2011
On the Chemical Kinetics of n -Butanol: Ignition and Speciation Studies Karwat, Darshan M. A.; Wagnon, Scott W.; Teini, Paul D. The Journal of Physical Chemistry A, Vol. 115, Issue 19 https://doi.org/10.1021/jp200905n	journal	May 2011
On the Combustion Chemistry of n- Heptane and n- Butanol Blends Karwat, Darshan M. A.; Wagnon, Scott W.; Wooldridge, Margaret S. The Journal of Physical Chemistry A, Vol. 116, Issue 51 https://doi.org/10.1021/jp309358h	journal	December 2012
Autoignition of n-butanol at elevated pressure and low-to-intermediate temperature Weber, Bryan W.; Kumar, Kamal; Zhang, Yu Combustion and Flame, Vol. 158, Issue 5 https://doi.org/10.1016/j.combustflame.2011.02.005	journal	May 2011
Comparative Autoignition Trends in Butanol Isomers at Elevated Pressure Weber, Bryan W.; Sung, Chih-Jen Energy & Fuels, Vol. 27, Issue 3 https://doi.org/10.1021/ef302195c	journal	February 2013
Kinetics of the Hydrogen Atom Abstraction Reactions from 1-Butanol by Hydroxyl Radical: Theory Matches Experiment and More Seal, Prasenjit; Oyedepo, Gbenga; Truhlar, Donald G. The Journal of Physical Chemistry A, Vol. 117, Issue 2 https://doi.org/10.1021/jp310910f	journal	January 2013
Rate constants of hydrogen abstraction by methyl radical from n-butanol and a comparison of CanTherm, MultiWell and Variflex Katsikadakos, D.; Zhou, C. -W.; Simmie, J. M. Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.06.015	journal	January 2013
Rate constants for hydrogen abstraction by HȮ2 from n-butanol Zhou, Chong-Wen; Simmie, John M.; Curran, Henry J. International Journal of Chemical Kinetics, Vol. 44, Issue 3 https://doi.org/10.1002/kin.20708	journal	January 2012
Kinetics of the Hydrogen Abstraction from Carbon-3 of 1-Butanol by Hydroperoxyl Radical: Multi-Structural Variational Transition-State Calculations of a Reaction with 262 Conformations of the Transition State Seal, Prasenjit; Papajak, Ewa; Truhlar, Donald G. The Journal of Physical Chemistry Letters, Vol. 3, Issue 2 https://doi.org/10.1021/jz201546e	journal	January 2012
Hydrogen abstraction from n-butanol by the methyl radical: high level ab initio study of abstraction pathways and the importance of low energy rotational conformers Katsikadakos, D.; Hardalupas, Y.; Taylor, A. M. K. P. Physical Chemistry Chemical Physics, Vol. 14, Issue 27 https://doi.org/10.1039/c2cp24074b	journal	January 2012
Biofuel Combustion. Energetics and Kinetics of Hydrogen Abstraction from Carbon-1 in n -Butanol by the Hydroperoxyl Radical Calculated by Coupled Cluster and Density Functional Theories and Multistructural Variational Transition-State Theory with Multidimensional Tunneling Alecu, I. M.; Zheng, Jingjing; Papajak, Ewa The Journal of Physical Chemistry A, Vol. 116, Issue 50 https://doi.org/10.1021/jp308460y	journal	December 2012
Ab Initio Kinetics for the Decomposition of Hydroxybutyl and Butoxy Radicals of n -Butanol Zhang, Peng; Klippenstein, Stephen J.; Law, Chung K. The Journal of Physical Chemistry A, Vol. 117, Issue 9 https://doi.org/10.1021/jp400155z	journal	February 2013
Statistical thermodynamics of 1-butanol, 2-methyl-1-propanol, and butanal Seal, Prasenjit; Papajak, Ewa; Yu, Tao The Journal of Chemical Physics, Vol. 136, Issue 3 https://doi.org/10.1063/1.3674995	journal	January 2012
Thermochemistry of radicals formed by hydrogen abstraction from 1-butanol, 2-methyl-1-propanol, and butanal Papajak, Ewa; Seal, Prasenjit; Xu, Xuefei The Journal of Chemical Physics, Vol. 137, Issue 10 https://doi.org/10.1063/1.4742968	journal	September 2012
Erratum to “Comprehensive reaction mechanism for n-butanol pyrolysis and combustion” [Combust. Flame 158 (2011) 16–41] Harper, Michael R.; Van Geem, Kevin M.; Pyl, Steven P. Combustion and Flame, Vol. 158, Issue 10 https://doi.org/10.1016/j.combustflame.2011.02.023	journal	October 2011
An Experimental and Kinetic Modeling Study of the Oxidation of the Four Isomers of Butanol Moss, Jeffrey T.; Berkowitz, Andrew M.; Oehlschlaeger, Matthew A. The Journal of Physical Chemistry A, Vol. 112, Issue 43 https://doi.org/10.1021/jp806464p	journal	October 2008
A comprehensive chemical kinetic combustion model for the four butanol isomers Sarathy, S. Mani; Vranckx, Stijn; Yasunaga, Kenji Combustion and Flame, Vol. 159, Issue 6 https://doi.org/10.1016/j.combustflame.2011.12.017	journal	June 2012
An Analysis of the Combustion Behavior of Ethanol, Butanol, Iso -Octane, Gasoline, and Methane in a Direct-Injection Spark-Ignition Research Engine Serras-Pereira, J.; Aleiferis, P. G.; Richardson, D. Combustion Science and Technology, Vol. 185, Issue 3 https://doi.org/10.1080/00102202.2012.728650	journal	February 2013
A study of mechanical variable valve operation with gasoline–alcohol fuels in a spark ignition engine Cairns, Alasdair; Zhao, Hua; Todd, Alan Fuel, Vol. 106 https://doi.org/10.1016/j.fuel.2012.10.041	journal	April 2013
Optical diagnostics of the combustion process in a PFI SI boosted engine fueled with butanol–gasoline blend Tornatore, Cinzia; Marchitto, Luca; Valentino, Gerardo Energy, Vol. 45, Issue 1 https://doi.org/10.1016/j.energy.2012.03.006	journal	September 2012
Emission characteristics of a spark-ignition engine fuelled with gasoline-n-butanol blends in combination with EGR Gu, Xiaolei; Huang, Zuohua; Cai, Jian Fuel, Vol. 93 https://doi.org/10.1016/j.fuel.2011.11.040	journal	March 2012
The possibility of running homogeneous charge compression ignition in spark ignition and compression ignition small-scale engines Wu, Y-Y; Chen, B-C; Tsai, H-C Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy, Vol. 225, Issue 5 https://doi.org/10.1177/0957650911400671	journal	June 2011
Combustion of n-butanol in a spark-ignition IC engine Szwaja, S.; Naber, J. D. Fuel, Vol. 89, Issue 7 https://doi.org/10.1016/j.fuel.2009.08.043	journal	July 2010
Butanol—A Single Cylinder Engine Study: Engine Performance Alasfour, F. N. International Journal of Energy Research, Vol. 21, Issue 1 https://doi.org/10.1002/(SICI)1099-114X(199701)21:1<21::AID-ER231>3.0.CO;2-K	journal	January 1997
Exhaust Gas Emissions of Butanol, Ethanol, and Methanol-Gasoline Blends Rice, R. W.; Sanyal, A. K.; Elrod, A. C. Journal of Engineering for Gas Turbines and Power, Vol. 113, Issue 3 https://doi.org/10.1115/1.2906241	journal	July 1991
Effects of Blending Gasoline With Ethanol and Butanol on Engine Efficiency and Emissions Using a Direct-Injection, Spark-Ignition Engine Cooney, Christopher; Wallner, Thomas; McConnell, Steve ASME 2009 Internal Combustion Engine Division Spring Technical Conference https://doi.org/10.1115/ICES2009-76155	conference	August 2009
Effect of hydrogen on butanol–biodiesel blends in compression ignition engines Sukjit, E.; Herreros, J. M.; Dearn, K. D. International Journal of Hydrogen Energy, Vol. 38, Issue 3 https://doi.org/10.1016/j.ijhydene.2012.11.061	journal	February 2013
PFI (port fuel injection) of n-butanol and direct injection of biodiesel to attain LTC (low-temperature combustion) for low-emissions idling in a compression engine Soloiu, Valentin; Duggan, Marvin; Harp, Spencer Energy, Vol. 52 https://doi.org/10.1016/j.energy.2013.01.023	journal	April 2013
Combustion and emission characteristics of n-butanol/diesel fuel blend in a turbo-charged compression ignition engine Siwale, Lennox; Kristóf, Lukács; Adam, Torok Fuel, Vol. 107 https://doi.org/10.1016/j.fuel.2012.11.083	journal	May 2013
Experimental study on the performance of and emissions from a low-speed light-duty diesel engine fueled with n- butanol–diesel and isobutanol–diesel blends Gu, Xiaolei; Li, Guo; Jiang, Xue Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, Vol. 227, Issue 2 https://doi.org/10.1177/0954407012453231	journal	August 2012
Experimental study on combustion and emission characteristics of a diesel engine fueled with 2,5-dimethylfuran–diesel, n-butanol–diesel and gasoline–diesel blends Chen, Guisheng; Shen, Yinggang; Zhang, Quanchang Energy, Vol. 54 https://doi.org/10.1016/j.energy.2013.02.069	journal	June 2013
Experimental study of n-butanol addition on performance and emissions with diesel low temperature combustion Zhang, Quanchang; Yao, Mingfa; Zheng, Zunqing Energy, Vol. 47, Issue 1 https://doi.org/10.1016/j.energy.2012.09.020	journal	November 2012
Experimental study on performance and emissions of a high speed diesel engine fuelled with n-butanol diesel blends under premixed low temperature combustion Valentino, Gerardo; Corcione, Felice E.; Iannuzzi, Stefano E. Fuel, Vol. 92, Issue 1 https://doi.org/10.1016/j.fuel.2011.07.035	journal	February 2012
Effects of gasoline–diesel and n-butanol–diesel blends on performance and emissions of an automotive direct-injection diesel engine Valentino, Gerardo; Corcione, Felice E.; Iannuzzi, Stefano E. International Journal of Engine Research, Vol. 13, Issue 3 https://doi.org/10.1177/1468087412441879	journal	April 2012
The effect of the addition of individual methyl esters on the combustion and emissions of ethanol and butanol -diesel blends Sukjit, E.; Herreros, J. M.; Dearn, K. D. Energy, Vol. 42, Issue 1 https://doi.org/10.1016/j.energy.2012.03.041	journal	June 2012
Reduction in emissions of nitrogen oxides, particulate matter, and polycyclic aromatic hydrocarbon by adding water-containing butanol into a diesel-fueled engine generator Lin, Sheng-Lun; Lee, Wen-Jhy; Lee, Chia-fon F. Fuel, Vol. 93 https://doi.org/10.1016/j.fuel.2011.11.042	journal	March 2012
Combustion heat release analysis of ethanol or n-butanol diesel fuel blends in heavy-duty DI diesel engine Rakopoulos, D. C.; Rakopoulos, C. D.; Papagiannakis, R. G. Fuel, Vol. 90, Issue 5 https://doi.org/10.1016/j.fuel.2010.12.003	journal	May 2011
The combustion of n -butanol/diesel fuel blends and its cyclic variability in a direct injection diesel engine Rakopoulos, C. D.; Rakopoulos, D. C.; Giakoumis, E. G. Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy, Vol. 225, Issue 3 https://doi.org/10.1177/2041296710394256	journal	May 2011
Study of turbocharged diesel engine operation, pollutant emissions and combustion noise radiation during starting with bio-diesel or n-butanol diesel fuel blends Rakopoulos, C. D.; Dimaratos, A. M.; Giakoumis, E. G. Applied Energy, Vol. 88, Issue 11 https://doi.org/10.1016/j.apenergy.2011.03.051	journal	November 2011
Experimental investigation of fuel properties, engine performance, combustion and emissions of blends containing croton oil, butanol, and diesel on a CI engine Lujaji, Frank; Kristóf, Lukács; Bereczky, Akos Fuel, Vol. 90, Issue 2 https://doi.org/10.1016/j.fuel.2010.10.004	journal	February 2011
The influence of n-butanol/diesel fuel blends utilization on a small diesel engine performance and emissions Doğan, Oğuzhan Fuel, Vol. 90, Issue 7 https://doi.org/10.1016/j.fuel.2011.02.033	journal	July 2011
Experimental study of n-butanol additive and multi-injection on HD diesel engine performance and emissions Yao, Mingfa; Wang, Hu; Zheng, Zunqing Fuel, Vol. 89, Issue 9 https://doi.org/10.1016/j.fuel.2010.04.008	journal	September 2010
Effects of butanol–diesel fuel blends on the performance and emissions of a high-speed DI diesel engine Rakopoulos, D. C.; Rakopoulos, C. D.; Giakoumis, E. G. Energy Conversion and Management, Vol. 51, Issue 10 https://doi.org/10.1016/j.enconman.2010.02.032	journal	October 2010
Performance and emission characteristics of a diesel engine using isobutanol–diesel fuel blends Karabektas, Murat; Hosoz, Murat Renewable Energy, Vol. 34, Issue 6 https://doi.org/10.1016/j.renene.2008.11.003	journal	June 2009
Combustion and emission characteristics of a HCCI engine fuelled with n-butanol–gasoline blends He, Bang-Quan; Liu, Mao-Bin; Yuan, Jie Fuel, Vol. 108 https://doi.org/10.1016/j.fuel.2013.02.026	journal	June 2013
Numerical study of a butanol/heptane fuelled Homogeneous Charge Compression Ignition (HCCI) engine utilizing negative valve overlap Visakhamoorthy, Sona; Wen, John Z.; Sivoththaman, Siva Applied Energy, Vol. 94 https://doi.org/10.1016/j.apenergy.2012.01.047	journal	June 2012
Spectroscopic Measurements of Low-Temperature Heat Release for Homogeneous Combustion Compression Ignition (HCCI) n -Heptane/Alcohol Mixture Combustion Saisirirat, Peerawat; Foucher, Fabrice; Chanchaona, Somchai Energy & Fuels, Vol. 24, Issue 10 https://doi.org/10.1021/ef100938u	journal	October 2010
Autoignition of Binary Fuel Blends of n-Butanol and n-Heptane in a Rapid Compression Machine Zhang, Yu; Kumar, Kamal; Sung, Chih-Jen 49th AIAA Aerospace Sciences Meeting including the New Horizons Forum and Aerospace Exposition https://doi.org/10.2514/6.2011-92	conference	June 2012
Laminar Flame Characteristics of iso -Octane/ n -Butanol Blend–Air Mixtures at Elevated Temperatures Zhang, Xinyi; Tang, Chenglong; Yu, Huibin Energy & Fuels, Vol. 27, Issue 4 https://doi.org/10.1021/ef4001743	journal	March 2013
A Rapid Compression Machine for Chemical Kinetics Studies at Elevated Pressures and Temperatures Mittal, Gaurav; Sung*, Chih-Jen Combustion Science and Technology, Vol. 179, Issue 3 https://doi.org/10.1080/00102200600671898	journal	March 2007
Autoignition of n-decane under elevated pressure and low-to-intermediate temperature conditions Kumar, Kamal; Mittal, Gaurav; Sung, Chih-Jen Combustion and Flame, Vol. 156, Issue 6 https://doi.org/10.1016/j.combustflame.2009.01.009	journal	June 2009
Autoignition of methanol: Experiments and computations: Autoignition of Methanol: Experiments and Computations Kumar, Kamal; Sung, Chih-Jen International Journal of Chemical Kinetics, Vol. 43, Issue 4 https://doi.org/10.1002/kin.20546	journal	February 2011
Development of Isopentanol Reaction Mechanism Reproducing Autoignition Character at High and Low Temperatures Tsujimura, Taku; Pitz, William J.; Gillespie, Fiona Energy & Fuels, Vol. 26, Issue 8 https://doi.org/10.1021/ef300879k	journal	July 2012
A comprehensive experimental and modeling study of iso-pentanol combustion Mani Sarathy, S.; Park, Sungwoo; Weber, Bryan W. Combustion and Flame, Vol. 160, Issue 12 https://doi.org/10.1016/j.combustflame.2013.06.022	journal	December 2013
Autoignition of toluene and benzene at elevated pressures in a rapid compression machine Mittal, Gaurav; Sung, Chih-Jen Combustion and Flame, Vol. 150, Issue 4 https://doi.org/10.1016/j.combustflame.2007.04.014	journal	September 2007
Autoignition of methylcyclohexane at elevated pressures Mittal, Gaurav; Sung, Chih-Jen Combustion and Flame, Vol. 156, Issue 9 https://doi.org/10.1016/j.combustflame.2009.05.009	journal	September 2009
Homogeneous charge compression ignition of binary fuel blends Mittal, Gaurav; Sung, Chih-Jen Combustion and Flame, Vol. 155, Issue 3 https://doi.org/10.1016/j.combustflame.2008.05.003	journal	November 2008
Autoignition of gasoline and its surrogates in a rapid compression machine Kukkadapu, Goutham; Kumar, Kamal; Sung, Chih-Jen Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.06.135	journal	January 2013
A jet fuel surrogate formulated by real fuel properties Dooley, Stephen; Won, Sang Hee; Chaos, Marcos Combustion and Flame, Vol. 157, Issue 12 https://doi.org/10.1016/j.combustflame.2010.07.001	journal	December 2010
The experimental evaluation of a methodology for surrogate fuel formulation to emulate gas phase combustion kinetic phenomena Dooley, Stephen; Won, Sang Hee; Heyne, Joshua Combustion and Flame, Vol. 159, Issue 4 https://doi.org/10.1016/j.combustflame.2011.11.002	journal	April 2012
A comprehensive modeling study of iso-octane oxidation Curran, H. Combustion and Flame, Vol. 129, Issue 3 https://doi.org/10.1016/S0010-2180(01)00373-X	journal	May 2002
Detailed Kinetic Modeling of Low-Temperature Heat Release for PRF Fuels in an HCCI Engine Mehl, M.; Pitz, W. J.; Sjöberg, M. Powertrains, Fuels and Lubricants Meeting, SAE Technical Paper Series https://doi.org/10.4271/2009-01-1806	conference	June 2009
Chemical kinetics of hydrocarbon ignition in practical combustion systems Westbrook, Charles K. Proceedings of the Combustion Institute, Vol. 28, Issue 2 https://doi.org/10.1016/S0082-0784(00)80554-8	journal	January 2000
Autoignition of butane: A burner and a rapid compression machine study Carlier, M.; Corre, C.; Minetti, R. Symposium (International) on Combustion, Vol. 23, Issue 1 https://doi.org/10.1016/S0082-0784(06)80453-4	journal	January 1991
Experimental and modeling study of oxidation and autoignition of butane at high pressure Minetti, R.; Ribaucour, M.; Carlier, M. Combustion and Flame, Vol. 96, Issue 3 https://doi.org/10.1016/0010-2180(94)90009-4	journal	February 1994
Ethanol Oxidation: Kinetics of the α-Hydroxyethyl Radical + O ₂ Reaction da Silva, Gabriel; Bozzelli, Joseph W.; Liang, Long The Journal of Physical Chemistry A, Vol. 113, Issue 31 https://doi.org/10.1021/jp903210a	journal	August 2009
Evaluation of different reaction strategies for the improvement of cetane number in diesel fuels Santana, R.; Do, P.; Santikunaporn, M. Fuel, Vol. 85, Issue 5-6 https://doi.org/10.1016/j.fuel.2005.08.028	journal	March 2006
Biodiesel and renewable diesel: A comparison Knothe, Gerhard Progress in Energy and Combustion Science, Vol. 36, Issue 3 https://doi.org/10.1016/j.pecs.2009.11.004	journal	June 2010
Ignition timing sensitivities of oxygenated biofuels compared to gasoline in a direct-injection SI engine Daniel, Ritchie; Tian, Guohong; Xu, Hongming Fuel, Vol. 99 https://doi.org/10.1016/j.fuel.2012.01.053	journal	September 2012
An Approach for Formulating Surrogates for Gasoline with Application toward a Reduced Surrogate Mechanism for CFD Engine Modeling Mehl, M.; Chen, J. Y.; Pitz, W. J. Energy & Fuels, Vol. 25, Issue 11 https://doi.org/10.1021/ef201099y	journal	November 2011
Gas-Phase Rate Coefficients for the OH + n -, i -, s -, and t -Butanol Reactions Measured Between 220 and 380 K: Non-Arrhenius Behavior and Site-Specific Reactivity McGillen, Max R.; Baasandorj, Munkhbayar; Burkholder, James B. The Journal of Physical Chemistry A, Vol. 117, Issue 22 https://doi.org/10.1021/jp402702u	journal	May 2013
On the rate constants of OH+HO2 and HO2+HO2: A comprehensive study of H2O2 thermal decomposition using multi-species laser absorption Hong, Zekai; Lam, King-Yiu; Sur, Ritobrata Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.06.108	journal	January 2013
Shock wave study of the reaction HO ₂ +HO ₂ →H ₂ O ₂ +O ₂ : Confirmation of a rate constant minimum near 700 K Hippler, H.; Troe, J.; Willner, J. The Journal of Chemical Physics, Vol. 93, Issue 3 https://doi.org/10.1063/1.459102	journal	August 1990

Cited By (1)

Influences of isomeric butanol addition on anti-knock tendency of primary reference fuel and toluene primary reference fuel gasoline surrogates Fan, Yunchu; Duan, Yaozong; Han, Dong International Journal of Engine Research https://doi.org/10.1177/1468087419850704	journal	May 2019

Similar Records

Numerical analysis of soot emissions from gasoline-ethanol and gasoline-butanol blends under gasoline compression ignition conditions

Journal Article · Tue Mar 15 00:00:00 EDT 2022 · Fuel · OSTI ID:1281683

Kalvakala, Krishna C.; Pal, Pinaki; Gonzalez, Jorge Pulpeiro; +8 more

Numerical Study of PAHs and Soot Emissions from Gasoline–Methanol, Gasoline–Ethanol, and Gasoline–n-Butanol Blend Surrogates

Journal Article · Mon Jun 13 00:00:00 EDT 2022 · Energy and Fuels · OSTI ID:1281683

Kalvakala, Krishna C.; Pal, Pinaki; Kukkadapu, Goutham; +2 more

An experimental and modeling study on autoignition of 2-phenylethanol and its blends with n-heptane

Journal Article · Thu Dec 08 00:00:00 EST 2022 · Proceedings of the Combustion Institute · OSTI ID:1281683

Fang, Ruozhou; Kukkadapu, Goutham; Wagnon, Scott W.; +2 more

Related Subjects

30 DIRECT ENERGY CONVERSION
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
n-butanol
iso-octane
n-heptane
autoignition
fuel blend combustion

Title: Autoignition response of n-butanol and its blend with primary reference fuel constituents of gasoline.

Citation Formats

References (119)

Cited By (1)

Similar Records

Related Subjects