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Title: Crystalline 1H-1,2,3-triazol-5-ylidenes

Patent ·
OSTI ID:1281093
; ; ;

The present invention provides novel and stable crystalline 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of making 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of using 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes in catalytic reactions.

Research Organization:
Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-09ER16069
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Number(s):
9,403,781
Application Number:
13/643,262
OSTI ID:
1281093
Resource Relation:
Patent File Date: 2011 Apr 26
Country of Publication:
United States
Language:
English

References (4)

Ruthenium metal alkylidene complexes coordinated with triazolylidene ligands that exhibit high olefin metathesis activity patent July 2002
Palladium complexes with abnormal N-heterocyclic carbene ligands derived from 1,2,3-triazolium ions and their application in Suzuki coupling journal October 2009
1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals journal October 2008
Stability and reactivity of N-heterocyclic carbene complexes journal December 2004

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Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY