Nano-optical imaging of WSe2 waveguide modes revealing light-exciton interactions

Fei, Z.; Scott, M. E.; Gosztola, D. J.; Foley, IV, J. J.; Yan, J.; Mandrus, D. G.; Wen, H.; Zhou, P.; Zhang, D. W.; Sun, Y.; Guest, J. R.; Gray, S. K.; Bao, W.; Wiederrecht, G. P.; Xu, X.

doi:10.1103/PhysRevB.94.081402

Title: Nano-optical imaging of $WS e_{2}$ waveguide modes revealing light-exciton interactions

Journal Article · Mon Aug 01 00:00:00 EDT 2016 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.94.081402· OSTI ID:1369571

Fei, Z. ^[1]; Scott, M. E. ^[2]; Gosztola, D. J. ^[3]; Foley, IV, J. J. ^[4]; Yan, J. ^[5]; Mandrus, D. G. ^[5]; Wen, H. ^[3]; Zhou, P. ^[6]; Zhang, D. W. ^[6]; Sun, Y. ^[3]; Guest, J. R. ^[3]; Gray, S. K. ^[3]; Bao, W. ^[6]; Wiederrecht, G. P. ^[3]; Xu, X. ^[2]

Argonne National Lab. (ANL), Lemont, IL (United States); Iowa State Univ., Ames, IA (United States)
Univ. of Washington, Seattle, WA (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); William Paterson Univ., Wayne, NJ (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Fudan Univ., Shanghai (China)

We report on a nano-optical imaging study of WS_e2 thin flakes with scanning near-field optical microscopy (NSOM). The NSOM technique allows us to visualize in real space various waveguide photon modes inside WS_e2. By tuning the excitation laser energy, we are able to map the entire dispersion of these waveguide modes both above and below the A exciton energy of WS_e2. We found that all the modes interact strongly with WS_e2 excitons. The outcome of the interaction is that the observed waveguide modes shift to higher momenta right below the A exciton energy. At higher energies, on the other hand, these modes are strongly damped due to adjacent B excitons or band-edge absorptions. Furthermore, the mode-shifting phenomena are consistent with polariton formation in WS_e2.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; AC05-00OR22725

OSTI ID:: 1369571

Alternate ID(s):: OSTI ID: 1280187; OSTI ID: 1376353

Journal Information:: Physical Review B, Vol. 94, Issue 8; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 62 works

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References (33)

Visualizing nanoscale excitonic relaxation properties of disordered edges and grain boundaries in monolayer molybdenum disulfide Bao, Wei; Borys, Nicholas J.; Ko, Changhyun Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8993	journal	August 2015
Exciton-polariton Bose-Einstein condensation Deng, Hui; Haug, Hartmut; Yamamoto, Yoshihisa Reviews of Modern Physics, Vol. 82, Issue 2 https://doi.org/10.1103/RevModPhys.82.1489	journal	May 2010
Characterization of the structural defects in CVD-grown monolayered MoS ₂ using near-field photoluminescence imaging Lee, Yongjun; Park, Seki; Kim, Hyun Nanoscale, Vol. 7, Issue 28 https://doi.org/10.1039/C5NR02897C	journal	January 2015
The optical near-field of an aperture tip Drezet, A.; Nasse, M. J.; Huant, S. Europhysics Letters (EPL), Vol. 66, Issue 1 https://doi.org/10.1209/epl/i2003-10138-7	journal	April 2004
Optical generation of excitonic valley coherence in monolayer WSe2 Jones, Aaron M.; Yu, Hongyi; Ghimire, Nirmal J. Nature Nanotechnology, Vol. 8, Issue 9 https://doi.org/10.1038/nnano.2013.151	journal	August 2013
Exciton–polariton light–semiconductor coupling effects Gibbs, H. M.; Khitrova, G.; Koch, S. W. Nature Photonics, Vol. 5, Issue 5 https://doi.org/10.1038/nphoton.2011.15	journal	March 2011
Emerging Photoluminescence in Monolayer MoS₂ Splendiani, Andrea; Sun, Liang; Zhang, Yuanbo Nano Letters, Vol. 10, Issue 4, p. 1271-1275 https://doi.org/10.1021/nl903868w	journal	April 2010
Electrically tunable excitonic light-emitting diodes based on monolayer WSe2 p–n junctions Ross, Jason S.; Klement, Philip; Jones, Aaron M. Nature Nanotechnology, Vol. 9, Issue 4 https://doi.org/10.1038/nnano.2014.26	journal	March 2014
Spin and pseudospins in layered transition metal dichalcogenides Xu, Xiaodong; Yao, Wang; Xiao, Di Nature Physics, Vol. 10, Issue 5 https://doi.org/10.1038/nphys2942	journal	April 2014
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712 https://doi.org/10.1038/nnano.2012.193	journal	November 2012
Two-dimensional exciton–polariton—light guiding by transition metal dichalcogenide monolayers Khurgin, Jacob B. Optica, Vol. 2, Issue 8 https://doi.org/10.1364/OPTICA.2.000740	journal	January 2015
Quantum-well reflectivity and exciton-polariton dispersion Tassone, F.; Bassani, F.; Andreani, L. C. Physical Review B, Vol. 45, Issue 11 https://doi.org/10.1103/PhysRevB.45.6023	journal	March 1992
Ultrafast charge transfer in atomically thin MoS2/WS2 heterostructures Hong, Xiaoping; Kim, Jonghwan; Shi, Su-Fei Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.167	journal	August 2014
High-spatial-resolution near-field photoluminescence and imaging of whispering-gallery modes in semiconductor microdisks with embedded quantum dots Mintairov, A. M.; Chu, Y.; He, Y. Physical Review B, Vol. 77, Issue 19 https://doi.org/10.1103/PhysRevB.77.195322	journal	May 2008
Ultrafast Carrier Thermalization and Cooling Dynamics in Few-Layer MoS ₂ Nie, Zhaogang; Long, Run; Sun, Linfeng ACS Nano, Vol. 8, Issue 10 https://doi.org/10.1021/nn504760x	journal	October 2014
Optical properties of monolayer transition metal dichalcogenides probed by spectroscopic ellipsometry Liu, Hsiang-Lin; Shen, Chih-Chiang; Su, Sheng-Han Applied Physics Letters, Vol. 105, Issue 20 https://doi.org/10.1063/1.4901836	journal	November 2014
Exciton–polaritons in van der Waals heterostructures embedded in tunable microcavities Dufferwiel, S.; Schwarz, S.; Withers, F. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9579	journal	October 2015
Probing excitonic dark states in single-layer tungsten disulphide Ye, Ziliang; Cao, Ting; O’Brien, Kevin Nature, Vol. 513, Issue 7517 https://doi.org/10.1038/nature13734	journal	August 2014
Observation of the coupled exciton-photon mode splitting in a semiconductor quantum microcavity Weisbuch, C.; Nishioka, M.; Ishikawa, A. Physical Review Letters, Vol. 69, Issue 23 https://doi.org/10.1103/PhysRevLett.69.3314	journal	December 1992
Atomically Thin ${MoS}_{2}$ A New Direct-Gap Semiconductor Mak, Kin Fai; Lee, Changgu; Hone, James Physical Review Letters, Vol. 105, Issue 13, Article No.136805 https://doi.org/10.1103/PhysRevLett.105.136805	journal	September 2010
Strong light–matter coupling in two-dimensional atomic crystals Liu, Xiaoze; Galfsky, Tal; Sun, Zheng Nature Photonics, Vol. 9, Issue 1 https://doi.org/10.1038/nphoton.2014.304	journal	December 2014
Tightly bound trions in monolayer MoS2 Mak, Kin Fai; He, Keliang; Lee, Changgu Nature Materials, Vol. 12, Issue 3 https://doi.org/10.1038/nmat3505	journal	December 2012
Near-unity photoluminescence quantum yield in MoS2 Amani, M.; Lien, D. -H.; Kiriya, D. Science, Vol. 350, Issue 6264 https://doi.org/10.1126/science.aad2114	journal	November 2015
Electrical control of neutral and charged excitons in a monolayer semiconductor Ross, Jason S.; Wu, Sanfeng; Yu, Hongyi Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2498	journal	February 2013
Transient Absorption Microscopy of Monolayer and Bulk WSe ₂ Cui, Qiannan; Ceballos, Frank; Kumar, Nardeep ACS Nano, Vol. 8, Issue 3 https://doi.org/10.1021/nn500277y	journal	February 2014
Exciton polaritons in transition-metal dichalcogenides and their direct excitation via energy transfer Gartstein, Yuri N.; Li, Xiao; Zhang, Chuanwei Physical Review B, Vol. 92, Issue 7 https://doi.org/10.1103/PhysRevB.92.075445	journal	August 2015
Single-layer MoS₂ transistors Radisavljevic, B.; Radenovic, A.; Brivio, J. Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150 https://doi.org/10.1038/nnano.2010.279	journal	January 2011
Monolayer semiconductor nanocavity lasers with ultralow thresholds Wu, Sanfeng; Buckley, Sonia; Schaibley, John R. Nature, Vol. 520, Issue 7545 https://doi.org/10.1038/nature14290	journal	March 2015
High-Performance Single Layered WSe₂ p-FETs with Chemically Doped Contacts Fang, Hui; Chuang, Steven; Chang, Ting Chia Nano Letters, Vol. 12, Issue 7, p. 3788-3792 https://doi.org/10.1021/nl301702r	journal	June 2012
Kramers-Kronig analysis of the reflectivity spectra of 3R-WS ₂ and 2H-WSe ₂ Beal, A. R.; Liang, W. Y.; Hughes, H. P. Journal of Physics C: Solid State Physics, Vol. 9, Issue 12 https://doi.org/10.1088/0022-3719/9/12/027	journal	June 1976
Control of valley polarization in monolayer MoS2 by optical helicity Mak, Kin Fai; He, Keliang; Shan, Jie Nature Nanotechnology, Vol. 7, Issue 8 https://doi.org/10.1038/nnano.2012.96	journal	June 2012
Valley polarization in MoS2 monolayers by optical pumping Zeng, Hualing; Dai, Junfeng; Yao, Wang Nature Nanotechnology, Vol. 7, Issue 8 https://doi.org/10.1038/nnano.2012.95	journal	June 2012
Exciton Dynamics in Suspended Monolayer and Few-Layer MoS ₂ 2D Crystals Shi, Hongyan; Yan, Rusen; Bertolazzi, Simone ACS Nano, Vol. 7, Issue 2 https://doi.org/10.1021/nn303973r	journal	January 2013

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Polariton Photonics Using Structured Metals and 2D Materials Cai, Ziqiang; Xu, Yihao; Wang, Chuangtang Advanced Optical Materials, Vol. 8, Issue 5 https://doi.org/10.1002/adom.201901090	journal	October 2019
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Polaritons in layered two-dimensional materials Low, Tony; Chaves, Andrey; Caldwell, Joshua D. Nature Materials, Vol. 16, Issue 2 https://doi.org/10.1038/nmat4792	journal	November 2016
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Near-field exciton imaging of chemically treated MoS ₂ monolayers Kim, Youngbum; Lee, Yongjun; Kim, Hyun Nanoscale, Vol. 10, Issue 18 https://doi.org/10.1039/c8nr00606g	journal	January 2018
Two-path self-interference in PTCDA active waveguides maps the dispersion and refraction of a single waveguide mode Schörner, C.; Neuber, C.; Hildner, R. APL Photonics, Vol. 4, Issue 1 https://doi.org/10.1063/1.5068761	journal	January 2019
Ultrafast nonequilibrium dynamics of strongly coupled resonances in the intrinsic cavity of $W S_{2}$ nanotubes Višić, Bojana; Yadgarov, Lena; Pogna, Eva A. A. Physical Review Research, Vol. 1, Issue 3 https://doi.org/10.1103/physrevresearch.1.033046	journal	October 2019
Transient exciton-polariton dynamics in WSe ₂ by ultrafast near-field imaging Mrejen, M.; Yadgarov, L.; Levanon, A. Science Advances, Vol. 5, Issue 2 https://doi.org/10.1126/sciadv.aat9618	journal	February 2019
Polaritons in van der Waals materials Basov, D. N.; Fogler, M. M.; Garcia de Abajo, F. J. Science, Vol. 354, Issue 6309 https://doi.org/10.1126/science.aag1992	journal	October 2016
Strong interaction of quantum emitters with a WS ₂ layer enhanced by a gold substrate Karanikolas, Vasilios; Thanopulos, Ioannis; Paspalakis, Emmanuel Optics Letters, Vol. 44, Issue 8 https://doi.org/10.1364/ol.44.002049	journal	January 2019
Polariton hyperspectral imaging of two-dimensional semiconductor crystals Gebhardt, Christian; Förg, Michael; Yamaguchi, Hisato Karlsruhe https://doi.org/10.5445/ir/1000098461	text	January 2019

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