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Title: Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications

A redox-active metal-organic composite material shows improved and selective O-2 adsorption over N-2 with respect to individual components (MIL-101 and ferrocene). The O-2 sensitivity of the composite material arises due to the formation of maghemite nanoparticles with the pore of the metal-organic framework material.
Authors:
 [1] ;  [1] ;  [2] ;  [1] ;  [2] ;  [2] ;  [3] ;  [2] ;  [2] ;  [2] ;  [4] ;  [3] ;  [5] ;  [5] ;  [6] ;  [2] ;  [2] ;  [1]
  1. Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA
  2. Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
  3. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland WA 99354 USA
  4. X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne IL 60439 USA
  5. National Security Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA
  6. Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904 1098 XH Amsterdam The Netherlands
Publication Date:
OSTI Identifier:
1275831
DOE Contract Number:
AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Advanced Materials; Journal Volume: 28; Journal Issue: 18
Publisher:
Wiley
Research Org:
Argonne National Laboratory (ANL)
Sponsoring Org:
USDOE Office of Science - Office of Basic Energy Sciences - Materials Sciences and Engineering Division; USDOE Office of Science
Country of Publication:
United States
Language:
English