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Title: Adsorption Kinetics in Nanoscale Porous Coordination Polymers

Nanoscale porous coordination polymers were synthesized using simple wet chemical method. The effect of various polymer surfactants on colloidal stability and shape selectivity was investigated. Our results suggest that the nanoparticles exhibited significantly improved adsorption kinetics compared to bulk crystals due to decreased diffusion path lengths and preferred crystal plane interaction.
Authors:
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Publication Date:
OSTI Identifier:
1274884
Report Number(s):
PNNL-SA-104104
Journal ID: ISSN 1944-8244; GT0200000
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: ACS Applied Materials and Interfaces; Journal Volume: 7; Journal Issue: 39
Publisher:
American Chemical Society
Research Org:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Geothermal Technologies Office (EE-4G)
Country of Publication:
United States
Language:
English
Subject:
coordination polymers; kinetics; nanofluids; nanomaterials; nanoscale; organic rankime cycle; working fluids and frameworks