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Title: Adsorption of two gas molecules at a single metal site in a metal–organic framework

One strategy to markedly increase the gas storage capacity of metal–organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules—specifically hydrogen, methane, or carbon dioxide.
Authors:
 [1] ;  [1] ;  [1] ;  [2] ;  [3] ;  [1]
  1. Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  2. National Inst. of Standards and Technology, Gaithersburg, MD (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)
  3. National Inst. of Standards and Technology, Gaithersburg, MD (United States); Univ. of Delaware, Newark, DE (United States)
Publication Date:
OSTI Identifier:
1274748
Resource Type:
Journal Article
Resource Relation:
Journal Name: ChemComm; Journal Volume: 52; Journal Issue: 53
Research Org:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY