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Title: Materials Data on Hg4Se4O9 by Materials Project

Abstract

(HgSeO3)3HgSe crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are four inequivalent Hg2+ sites. In the first Hg2+ site, Hg2+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Hg–O bond distances ranging from 2.25–2.85 Å. In the second Hg2+ site, Hg2+ is bonded in a 1-coordinate geometry to one Se+2.50+ and four O2- atoms. The Hg–Se bond length is 2.52 Å. There are a spread of Hg–O bond distances ranging from 2.15–2.91 Å. In the third Hg2+ site, Hg2+ is bonded in a 2-coordinate geometry to three O2- atoms. There are a spread of Hg–O bond distances ranging from 2.30–2.58 Å. In the fourth Hg2+ site, Hg2+ is bonded in a 1-coordinate geometry to three O2- atoms. There are a spread of Hg–O bond distances ranging from 2.20–2.81 Å. There are four inequivalent Se+2.50+ sites. In the first Se+2.50+ site, Se+2.50+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Se–O bond distances ranging from 1.70–1.77 Å. In the second Se+2.50+ site, Se+2.50+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Se–O bond distancesmore » ranging from 1.71–1.79 Å. In the third Se+2.50+ site, Se+2.50+ is bonded in a 2-coordinate geometry to one Hg2+ atom. In the fourth Se+2.50+ site, Se+2.50+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There is one shorter (1.72 Å) and two longer (1.74 Å) Se–O bond length. There are nine inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two Hg2+ and one Se+2.50+ atom. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two Hg2+ and one Se+2.50+ atom. In the third O2- site, O2- is bonded in a 4-coordinate geometry to three Hg2+ and one Se+2.50+ atom. In the fourth O2- site, O2- is bonded in a 1-coordinate geometry to two Hg2+ and one Se+2.50+ atom. In the fifth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Hg2+ and one Se+2.50+ atom. In the sixth O2- site, O2- is bonded in a distorted single-bond geometry to two Hg2+ and one Se+2.50+ atom. In the seventh O2- site, O2- is bonded in a 3-coordinate geometry to two Hg2+ and one Se+2.50+ atom. In the eighth O2- site, O2- is bonded in a distorted water-like geometry to one Hg2+ and one Se+2.50+ atom. In the ninth O2- site, O2- is bonded in a distorted trigonal planar geometry to two Hg2+ and one Se+2.50+ atom.« less

Authors:
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Contributing Org.:
MIT; UC Berkeley; Duke; U Louvain
OSTI Identifier:
1273122
Report Number(s):
mp-565679
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Resource Type:
Data
Resource Relation:
Related Information: https://materialsproject.org/citing
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; crystal structure; Hg4Se4O9; Hg-O-Se

Citation Formats

The Materials Project. Materials Data on Hg4Se4O9 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1273122.
The Materials Project. Materials Data on Hg4Se4O9 by Materials Project. United States. https://doi.org/10.17188/1273122
The Materials Project. 2020. "Materials Data on Hg4Se4O9 by Materials Project". United States. https://doi.org/10.17188/1273122. https://www.osti.gov/servlets/purl/1273122.
@article{osti_1273122,
title = {Materials Data on Hg4Se4O9 by Materials Project},
author = {The Materials Project},
abstractNote = {(HgSeO3)3HgSe crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are four inequivalent Hg2+ sites. In the first Hg2+ site, Hg2+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Hg–O bond distances ranging from 2.25–2.85 Å. In the second Hg2+ site, Hg2+ is bonded in a 1-coordinate geometry to one Se+2.50+ and four O2- atoms. The Hg–Se bond length is 2.52 Å. There are a spread of Hg–O bond distances ranging from 2.15–2.91 Å. In the third Hg2+ site, Hg2+ is bonded in a 2-coordinate geometry to three O2- atoms. There are a spread of Hg–O bond distances ranging from 2.30–2.58 Å. In the fourth Hg2+ site, Hg2+ is bonded in a 1-coordinate geometry to three O2- atoms. There are a spread of Hg–O bond distances ranging from 2.20–2.81 Å. There are four inequivalent Se+2.50+ sites. In the first Se+2.50+ site, Se+2.50+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Se–O bond distances ranging from 1.70–1.77 Å. In the second Se+2.50+ site, Se+2.50+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Se–O bond distances ranging from 1.71–1.79 Å. In the third Se+2.50+ site, Se+2.50+ is bonded in a 2-coordinate geometry to one Hg2+ atom. In the fourth Se+2.50+ site, Se+2.50+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There is one shorter (1.72 Å) and two longer (1.74 Å) Se–O bond length. There are nine inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two Hg2+ and one Se+2.50+ atom. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two Hg2+ and one Se+2.50+ atom. In the third O2- site, O2- is bonded in a 4-coordinate geometry to three Hg2+ and one Se+2.50+ atom. In the fourth O2- site, O2- is bonded in a 1-coordinate geometry to two Hg2+ and one Se+2.50+ atom. In the fifth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Hg2+ and one Se+2.50+ atom. In the sixth O2- site, O2- is bonded in a distorted single-bond geometry to two Hg2+ and one Se+2.50+ atom. In the seventh O2- site, O2- is bonded in a 3-coordinate geometry to two Hg2+ and one Se+2.50+ atom. In the eighth O2- site, O2- is bonded in a distorted water-like geometry to one Hg2+ and one Se+2.50+ atom. In the ninth O2- site, O2- is bonded in a distorted trigonal planar geometry to two Hg2+ and one Se+2.50+ atom.},
doi = {10.17188/1273122},
url = {https://www.osti.gov/biblio/1273122}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Apr 30 00:00:00 EDT 2020},
month = {Thu Apr 30 00:00:00 EDT 2020}
}