U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on MnSb2F12 by Materials Project
Abstract
MnSb2F12 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one MnSb2F12 sheet oriented in the (0, 0, 1) direction. Mn2+ is bonded in a 4-coordinate geometry to six F1- atoms. There are a spread of Mn–F bond distances ranging from 1.76–2.79 Å. Sb5+ is bonded in a 6-coordinate geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.64–2.43 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a 2-coordinate geometry to one Mn2+ and one Sb5+ atom. In the fourth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Mn2+ and one Sb5+ atom. In the fifth F1- site, F1- is bonded in a distorted bent 120 degrees geometry to one Mn2+ and one Sb5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.
- Authors:
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Org.:
- MIT; UC Berkeley; Duke; U Louvain
- OSTI Identifier:
- 1268598
- Report Number(s):
- mp-555052
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Resource Type:
- Data
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; crystal structure; MnSb2F12; F-Mn-Sb
Citation Formats
The Materials Project. Materials Data on MnSb2F12 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1268598.
The Materials Project. Materials Data on MnSb2F12 by Materials Project. United States. https://doi.org/10.17188/1268598
The Materials Project. 2020.
"Materials Data on MnSb2F12 by Materials Project". United States. https://doi.org/10.17188/1268598. https://www.osti.gov/servlets/purl/1268598.
@article{osti_1268598,
title = {Materials Data on MnSb2F12 by Materials Project},
author = {The Materials Project},
abstractNote = {MnSb2F12 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one MnSb2F12 sheet oriented in the (0, 0, 1) direction. Mn2+ is bonded in a 4-coordinate geometry to six F1- atoms. There are a spread of Mn–F bond distances ranging from 1.76–2.79 Å. Sb5+ is bonded in a 6-coordinate geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.64–2.43 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a 2-coordinate geometry to one Mn2+ and one Sb5+ atom. In the fourth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Mn2+ and one Sb5+ atom. In the fifth F1- site, F1- is bonded in a distorted bent 120 degrees geometry to one Mn2+ and one Sb5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.},
doi = {10.17188/1268598},
url = {https://www.osti.gov/biblio/1268598},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 09 00:00:00 EDT 2020},
month = {Sat May 09 00:00:00 EDT 2020}
}