Qualitative change in structural dynamics of some glass-forming systems

Novikov, Vladimir N.; Sokolov, Alexei P.

doi:10.1103/PhysRevE.92.062304

Title: Qualitative change in structural dynamics of some glass-forming systems

Journal Article · Mon Dec 14 00:00:00 EST 2015 · Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics

DOI:https://doi.org/10.1103/PhysRevE.92.062304· OSTI ID:1266011

Novikov, Vladimir N. ^[1]; Sokolov, Alexei P. ^[2]

Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Analysis of the temperature dependence of the structural relaxation time _Τα(T) in supercooled liquids revealed a qualitatively distinct feature a sharp, cusplike maximum in the second derivative of log _Τα(T) at some T_max. It suggests that the super-Arrhenius temperature dependence of _Τα(T) in glass-forming liquids eventually crosses over to an Arrhenius behavior at T < T_max, and there is no divergence of _Τα(T) at nonzero T . T_max can be above or below T_g, depending on the sensitivity of τ(T) to a change in the liquid's density quantified by the exponent γ in the scaling _Τα(T) ~exp(A/Tρ^–γ). Lastly, these results might turn the discussion of the glass transition in a different direction toward the origin of the limiting activation energy for structural relaxation at low T.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1266011

Journal Information:: Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics, Vol. 92, Issue 6; ISSN 1539-3755

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 24 works

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