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Title: Materials Data on RhF5 by Materials Project

Abstract

RhF5 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two RhF5 clusters. there are two inequivalent Rh sites. In the first Rh site, Rh is bonded to six F atoms to form corner-sharing RhF6 octahedra. The corner-sharing octahedra tilt angles range from 45–47°. There are a spread of Rh–F bond distances ranging from 1.86–2.04 Å. In the second Rh site, Rh is bonded to six F atoms to form corner-sharing RhF6 octahedra. The corner-sharing octahedra tilt angles range from 45–47°. There are a spread of Rh–F bond distances ranging from 1.86–2.04 Å. There are ten inequivalent F sites. In the first F site, F is bonded in a single-bond geometry to one Rh atom. In the second F site, F is bonded in a single-bond geometry to one Rh atom. In the third F site, F is bonded in a single-bond geometry to one Rh atom. In the fourth F site, F is bonded in a single-bond geometry to one Rh atom. In the fifth F site, F is bonded in a single-bond geometry to one Rh atom. In the sixth F site, F is bonded in a single-bond geometry to one Rh atom.more » In the seventh F site, F is bonded in a single-bond geometry to one Rh atom. In the eighth F site, F is bonded in a single-bond geometry to one Rh atom. In the ninth F site, F is bonded in a distorted bent 150 degrees geometry to two Rh atoms. In the tenth F site, F is bonded in a bent 120 degrees geometry to two Rh atoms.« less

Authors:
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Contributing Org.:
MIT; UC Berkeley; Duke; U Louvain
OSTI Identifier:
1264484
Report Number(s):
mp-540622
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Resource Type:
Data
Resource Relation:
Related Information: https://materialsproject.org/citing
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; crystal structure; RhF5; F-Rh

Citation Formats

The Materials Project. Materials Data on RhF5 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1264484.
The Materials Project. Materials Data on RhF5 by Materials Project. United States. https://doi.org/10.17188/1264484
The Materials Project. 2020. "Materials Data on RhF5 by Materials Project". United States. https://doi.org/10.17188/1264484. https://www.osti.gov/servlets/purl/1264484.
@article{osti_1264484,
title = {Materials Data on RhF5 by Materials Project},
author = {The Materials Project},
abstractNote = {RhF5 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two RhF5 clusters. there are two inequivalent Rh sites. In the first Rh site, Rh is bonded to six F atoms to form corner-sharing RhF6 octahedra. The corner-sharing octahedra tilt angles range from 45–47°. There are a spread of Rh–F bond distances ranging from 1.86–2.04 Å. In the second Rh site, Rh is bonded to six F atoms to form corner-sharing RhF6 octahedra. The corner-sharing octahedra tilt angles range from 45–47°. There are a spread of Rh–F bond distances ranging from 1.86–2.04 Å. There are ten inequivalent F sites. In the first F site, F is bonded in a single-bond geometry to one Rh atom. In the second F site, F is bonded in a single-bond geometry to one Rh atom. In the third F site, F is bonded in a single-bond geometry to one Rh atom. In the fourth F site, F is bonded in a single-bond geometry to one Rh atom. In the fifth F site, F is bonded in a single-bond geometry to one Rh atom. In the sixth F site, F is bonded in a single-bond geometry to one Rh atom. In the seventh F site, F is bonded in a single-bond geometry to one Rh atom. In the eighth F site, F is bonded in a single-bond geometry to one Rh atom. In the ninth F site, F is bonded in a distorted bent 150 degrees geometry to two Rh atoms. In the tenth F site, F is bonded in a bent 120 degrees geometry to two Rh atoms.},
doi = {10.17188/1264484},
url = {https://www.osti.gov/biblio/1264484}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jul 15 00:00:00 EDT 2020},
month = {Wed Jul 15 00:00:00 EDT 2020}
}