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Title: Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2

Flowing supercritical CO.sub.2 is used to activate metal organic framework materials (MOF). MOFs are activated directly from N,N-dimethylformamide (DMF) thus avoiding exchange with a volatile solvent. Most MCPs display increased surface areas directly after treatment although those with coordinatively unsaturated metal centers benefit from additional heating.
Authors:
; ;
Publication Date:
OSTI Identifier:
1264476
Report Number(s):
9,393,548
14/139,184
DOE Contract Number:
SC0004888
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Dec 23
Research Org:
The Regents Of The University Of Michigan, Ann Arbor, MI (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY