Structural and magnetic characterization of the one-dimensional S = 5/2 antiferromagnetic chain system SrMn(VO4)(OH)

Sanjeewa, Liurukara D.; Garlea, Vasile O.; McGuire, Michael A.; McMillen, Colin D.; Cao, Huibo; Kolis, Joseph W.

doi:10.1103/PhysRevB.93.224407

Title: Structural and magnetic characterization of the one-dimensional S = 5/2 antiferromagnetic chain system SrMn(VO₄)(OH)

Journal Article · Mon Jun 06 00:00:00 EDT 2016 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.93.224407· OSTI ID:1261550

Sanjeewa, Liurukara D. ^[1]; Garlea, Vasile O. ^[2]; McGuire, Michael A. ^[2]; McMillen, Colin D. ^[1]; Cao, Huibo ^[2]; Kolis, Joseph W. ^[1]

Clemson Univ., Clemson, SC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The descloizite-type compound, SrMn(VO₄)(OH), was synthesized as large single crystals (1-2mm) using a high-temperature high-pressure hydrothermal technique. X-ray single crystal structure analysis reveals that the material crystallizes in the acentric orthorhombic space group of P2₁2₁2₁ (no. 19), Z = 4. The structure exhibits a one-dimensional feature, with [MnO₄] chains propagating along the a-axis which are interconnected by VO₄ tetrahedra. Raman and infrared spectra were obtained to identify the fundamental vanadate and hydroxide vibrational modes. Magnetization data reveal a broad maximum at approximately 80 K, arising from one-dimensional magnetic correlations with intrachain exchange constant of J/k_B = 9.97(3) K between nearest Mn neighbors and a canted antiferromagnetic behavior below T_N = 30 K. Single crystal neutron diffraction at 4 K yielded a magnetic structure solution in the lower symmetry of the magnetic space group P2₁ with two unique chains displaying antiferromagnetically ordered Mn moments oriented nearly perpendicular to the chain axis. Lastly, the presence of the Dzyaloshinskii Moriya antisymmetric exchange interaction leads to a slight canting of the spins and gives rise to a weak ferromagnetic component along the chain direction.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261550

Alternate ID(s):: OSTI ID: 1256129

Journal Information:: Physical Review B, Vol. 93, Issue 22; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties Smith Pellizzeri, Tiffany M.; McGuire, Michael A.; McMillen, Colin D. Dalton Transactions, Vol. 47, Issue 8 https://doi.org/10.1039/c7dt04642a	journal	January 2018
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