The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19

Kan, W. H.; Huq, A.; Manthiram, A.

doi:10.1039/C5CC03070F

Title: The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe₃P₅SiO₁₉

Journal Article · Fri May 15 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/C5CC03070F· OSTI ID:1261442

Kan, W. H. ^[1]; Huq, A. ^[2]; Manthiram, A. ^[1]

Univ. of Texas at Austin, Austin, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division

We report the synthesis, structure, and electrochemistry of the first Na⁺-ion cathode with two distinct types of polyanions: Fe₃P₅SiO₁₉. The Fe-based cathode has a reversible capacity of ca. 70 mAh g^-1; ca. 1.7 Na⁺ ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na⁺/Na.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Organization:: USDOE: NSF

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261442

Journal Information:: ChemComm, Vol. 51, Issue 52; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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References (18)

3DBVSMAPPER : a program for automatically generating bond-valence sum landscapes Sale, Matthew; Avdeev, Maxim Journal of Applied Crystallography, Vol. 45, Issue 5 https://doi.org/10.1107/S0021889812032906	journal	August 2012
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Electroceramics: Characterization by Impedance Spectroscopy Irvine, John T. S.; Sinclair, Derek C.; West, Anthony R. Advanced Materials, Vol. 2, Issue 3 https://doi.org/10.1002/adma.19900020304	journal	March 1990
Crystal Structure and Magnetic Properties of a New Iron(III) Silicophosphate Fe3P5SiO19 Studied by Neutron Diffraction and Mössbauer Techniques Elbouaanani, L. K.; Malaman, B.; Gérardin, R. Journal of Solid State Chemistry, Vol. 164, Issue 1 https://doi.org/10.1006/jssc.2001.9449	journal	February 2002
Mo3P5SiO19: A molybdenum phosphate containing a confacial bioctahedral molybdenum(III) dimer with a MoMo bond Wang, S. L.; Wang, C. C.; Lii, K. H. Journal of Solid State Chemistry, Vol. 74, Issue 2 https://doi.org/10.1016/0022-4596(88)90372-6	journal	June 1988
A 3.8-V earth-abundant sodium battery electrode Barpanda, Prabeer; Oyama, Gosuke; Nishimura, Shin-ichi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5358	journal	July 2014
Screening of the alkali-metal ion containing materials from the Inorganic Crystal Structure Database (ICSD) for high ionic conductivity pathways using the bond valence method Avdeev, Max; Sale, Matthew; Adams, Stefan Solid State Ionics, Vol. 225 https://doi.org/10.1016/j.ssi.2012.02.014	journal	October 2012
Materials Challenges and Opportunities of Lithium Ion Batteries Manthiram, Arumugam The Journal of Physical Chemistry Letters, Vol. 2, Issue 3 https://doi.org/10.1021/jz1015422	journal	January 2011
Experimental visualization of lithium diffusion in LixFePO4 Nishimura, Shin-ichi; Kobayashi, Genki; Ohoyama, Kenji Nature Materials, Vol. 7, Issue 9 https://doi.org/10.1038/nmat2251	journal	August 2008
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries Padhi, A. K. Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194 https://doi.org/10.1149/1.1837571	journal	April 1997
Formation of a Complete Solid Solution between the Triphylite and Fayalite Olivine Structures Recham, N.; Casas-Cabanas, M.; Cabana, J. Chemistry of Materials, Vol. 20, Issue 21 https://doi.org/10.1021/cm801817n	journal	November 2008
Crystal Structure Revision and Identification of Li ⁺ -Ion Migration Pathways in the Garnet-like Li ₅ La ₃ M ₂ O ₁₂ (M = Nb, Ta) Oxides Thangadurai, Venkataraman; Adams, Stefan; Weppner, Werner Chemistry of Materials, Vol. 16, Issue 16 https://doi.org/10.1021/cm031176d	journal	August 2004
Lithium insertion into Fe2(SO4)3 frameworks Manthiram, A.; Goodenough, J. B. Journal of Power Sources, Vol. 26, Issue 3-4 https://doi.org/10.1016/0378-7753(89)80153-3	journal	May 1989
VALENCE: a program for calculating bond valences Brown, I. D. Journal of Applied Crystallography, Vol. 29, Issue 4 https://doi.org/10.1107/S002188989600163X	journal	August 1996
V3P5SiO19, a vanadosilicophosphate built up from V2O9 octahedra clusters Leclaire, André; Chahboun, Hassan; Groult, Daniel Journal of Solid State Chemistry, Vol. 65, Issue 2 https://doi.org/10.1016/0022-4596(86)90051-4	journal	November 1986
Research Development on Sodium-Ion Batteries Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500192f	journal	October 2014
A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries Wang, Yuesheng; Yu, Xiqian; Xu, Shuyin Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3365	journal	August 2013

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Evolution of Local Structural Ordering and Chemical Distribution upon Delithiation of a Rock Salt–Structured Li _1.3 Ta _0.3 Mn _0.4 O ₂ Cathode Kan, Wang Hay; Wei, Chenxi; Chen, Dongchang Advanced Functional Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adfm.201808294	journal	February 2019

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Title: The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe₃P₅SiO₁₉