Transformation of amorphous TiO2 to a hydronium oxofluorotitanate and applications as an HF sensor
Journal Article
·
· Sensors and Actuators. B, Chemical
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Center for Integrated Nanotechnologies (CINT-SNL)
We examined amorphous titania thin films for use as the active material in a polarimetry based HF sensor. The amorphous titania films were found to be sensitive to vapor phase HF and the reaction product was identified as a hydronium oxofluorotitanate phase, which has previously only been synthesized in aqueous solution. The extent of reaction varied both with vapor phase HF concentration, relative humidity, and the exposure time. HF concentrations as low as 1 ppm could be detected for exposure times of 120 h.
- Research Organization:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation
- Grant/Contract Number:
- AC04-94AL85000
- OSTI ID:
- 1257988
- Alternate ID(s):
- OSTI ID: 1252543
- Report Number(s):
- SAND-2015-6515J; PII: S0925400515307930
- Journal Information:
- Sensors and Actuators. B, Chemical, Vol. 228, Issue C; ISSN 0925-4005
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 11 works
Citation information provided by
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