skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Semi-solid electrodes having high rate capability

Patent ·
OSTI ID:1255928

Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode and a semi-solid cathode. The semi-solid cathode includes a suspension of an active material of about 35% to about 75% by volume of an active material and about 0.5% to about 8% by volume of a conductive material in a non-aqueous liquid electrolyte. An ion-permeable membrane is disposed between the anode and the semi-solid cathode. The semi-solid cathode has a thickness of about 250 .mu.m to about 2,000 .mu.m, and the electrochemical cell has an area specific capacity of at least about 7 mAh/cm.sup.2 at a C-rate of C/4. In some embodiments, the semi-solid cathode slurry has a mixing index of at least about 0.9.

Research Organization:
24M Technologies, Inc. Cambridge, MA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AR0000102
Assignee:
24M Technologies, Inc. (Cambridge, MA)
Patent Number(s):
9,362,583
OSTI ID:
1255928
Resource Relation:
Patent File Date: 2015 May 22
Country of Publication:
United States
Language:
English

References (149)

Fluoride based electrode materials for advanced energy storage devices journal April 2007
Conjugated dicarboxylate anodes for Li-ion batteries journal January 2009
Carbon-Metal Fluoride Nanocomposites: Structure and Electrochemistry of FeF3 : C journal January 2003
Chromium redox couples for application to redox flow batteries journal December 2002
Development of redox flow batteries. A historical bibliography journal September 1989
Improved fuel utilization in microfluidic fuel cells: A computational study journal April 2005
Evaluation of electrolytes for redox flow battery applications journal January 2007
High-performance lithium battery anodes using silicon nanowires journal December 2007
Solution Redox Couples for Electrochemical Energy Storage journal January 1981
Redox flow cells for energy conversion journal September 2006
Electrochemistry of Tris(β-diketonato)ruthenium(III) Complexes at Platinum Electrodes in Nonaqueous Solutions and Substituent Effects on Their Reversible Half-Wave Potentials journal March 1989
Assessment of the Degree of Mixedness of Filled Polymers journal September 2005
Numerical Model of a Single Phase, Regenerative Fuel Cell conference January 2004
Computational simulation of microfluidics, electrokinetics, and particle transport in biological MEMS devices conference March 1999
A novel in-plane passive microfluidic mixer with modified Tesla structures journal January 2004
Liquid flow in microchannels: experimental observations and computational analyses of microfluidics effects journal May 2003
Effect of channel dimensions and shape in the flow-field distributor on the performance of polymer electrolyte membrane fuel cells journal January 2003
Fabricating Genetically Engineered High-Power Lithium Ion Batteries Using Multiple Virus Genes journal April 2009
Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides journal January 2004
Rechargeable Lithium Batteries with Aqueous Electrolytes journal May 1994
Magnesium-solution phase catholyte semi-fuel cell for undersea vehicles journal October 2004
Modification in the electronic structure of cobalt bronze LixCoO2 and the resulting electrochemical properties journal October 1989
Development and Advances of a V-Flow FC Stack for FCX Clarity journal April 2009
Rechargeable batteries with organic radical cathodes journal June 2002
Virus-Enabled Synthesis and Assembly of Nanowires for Lithium Ion Battery Electrodes journal May 2006
Organic radical battery: nitroxide polymers as a cathode-active material journal November 2004
Iron Oxyfluorides as High Capacity Cathode Materials for Lithium Batteries journal January 2009
Structure and Electrochemistry of Carbon-Metal Fluoride Nanocomposites Fabricated by Solid-State Redox Conversion Reaction journal January 2005
Energy analysis of batteries in photovoltaic systems. Part I: Performance and energy requirements journal July 2005
Efficient Vanadium Redox Flow Cell journal January 1987
Electrochemical technology for environmental treatment and clean energy conversion journal January 2001
Optimizing layout of obstacles for enhanced mixing in microchannels journal September 2002
A study of the Fe(III)/Fe(II)–triethanolamine complex redox couple for redox flow battery application journal May 2006
Means for converting High Energy Radiation to Electrical Energy patent June 1966
Process for Converting Chemical Energy Into Electrical Energy patent December 1967
Redox Fuel Cell patent November 1970
Multiple Cell Redox Battery patent November 1970
Fuel Cell patent December 1970
Electrically rechargeable REDOX flow cell patent December 1976
Gels as battery separators for soluble electrode cells patent April 1977
Electrochemical generator comprising an electrode in the form of a suspension patent November 1978
Electrochemical cell for rebalancing redox flow system patent June 1979
Catalyst surfaces for the chromous/chromic redox couple patent March 1980
Electrochemical cell patent March 1982
Fuel cell patent March 1982
Lithium cells patent June 1982
Metal/acid ion permeable membrane fuel cell patent October 1982
Chrome-halogen energy storage device and system patent January 1983
Electrochemical cell patent March 1983
Zirconium carbide as an electrocatalyst for the chromous/chromic REDOX couple patent May 1983
Electrochemical cell patent October 1983
Electrochemical cell with a liquid negative electrode patent February 1984
Metal/acid ion permeable membrane fuel cell patent April 1984
Calcium electrochemical reserve cell patent June 1984
Ca Electrochemical cell patent July 1984
Electrically rechargeable anionically active reduction-oxidation electrical storage-supply system patent November 1984
Electrochemical generator operating device with a zinc negative electrode patent May 1985
Method and apparatus for rebalancing a redox flow cell system patent March 1986
Metal-halogen secondary battery patent September 1986
Electrochemical cell patent July 1988
Metal-halogen energy storage device and system patent November 1988
Apparatus and method for regenerating electrolyte of a redox flow battery patent September 1990
Integrated fuel cell stack shunt current prevention arrangement patent January 1992
End block constructions for batteries patent May 1994
Metal suspension half-cell for an accumulator, method for operating such a half-cell and metal suspension accumulator comprising such a half-cell patent November 1994
Electrically recharged battery employing a packed/spouted bed metal particle electrode patent August 1995
Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material patent September 1996
Zinc-bromine battery with non-flowing electrolyte patent January 1997
Capacitor having non-conductive plastic frames patent February 1997
Module for an aqueous battery system patent February 1997
Compact energy storage system patent March 1997
Method of electrode reconditioning patent July 1997
Redox battery patent August 1997
Shares for catalyst carrier elements, and catalyst apparatuses employing same patent October 1997
Liquid-circulating battery patent June 1998
Limited rechargeable lithium battery based on a cathode slurry patent August 1998
Laminar (flat or paper-type) lithium-ion battery with slurry anodes and slurry cathodes patent November 1998
Hydraulically refueled battery employing a packed bed metal particle electrode patent December 1998
Magnetic slurry fueled battery system patent February 1999
Gradient isolator for flow field of fuel cell assembly patent June 1999
Stabilized electrolyte solutions, methods of preparation thereof and redox cells and batteries containing stabilized electrolyte solutions patent November 2000
Long cycle-life alkali metal battery patent March 2001
Alkaline cell with semisolid cathode patent March 2001
Battery circulation system with improved four-way valve patent June 2001
Spill and leak containment system for zinc-bromine battery patent July 2001
Thin lithium battery with slurry cathode patent August 2001
Refuelable electrochemical power source capable of being maintained in a substantially constant full condition and method of using the same patent October 2001
Fuel cell with proton conducting membrane with a pore size less than 30 nm patent September 2002
Recombinator for the re-acidification of an electrolyte stream in a flowing electrolyte zinc-bromine battery patent September 2002
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions patent October 2002
Fuel cell with proton conducting membrane patent December 2002
Electroconversion cell patent December 2002
Thin lithium battery with slurry cathode patent April 2003
Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries patent May 2003
Battery and equipment or device having the battery as part of structure and locally distributed power generation method and power generation device therefor patent February 2004
Redox gel battery patent April 2004
Redox flow battery patent July 2004
Ion conductive matrixes and their use patent November 2004
Colloidal battery patent December 2005
Battery with bifunctional electrolyte patent January 2006
Electric devices with improved bipolar electrode patent April 2006
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions patent July 2006
Secondary battery with autolytic dendrites patent May 2007
Lanthanide batteries patent August 2007
Load leveling battery and methods therefor patent September 2007
Battery with gelled electrolyte patent November 2007
Vanadium/polyhalide redox flow battery patent January 2008
Conductive lithium storage electrode patent March 2008
Direct oxidation fuel cell with a divided fuel tank having a movable barrier pressurized by anode effluent gas patent August 2008
High efficiency semi-fuel cell incorporating an ion exchange membrane patent April 2009
Mixed electrolyte battery patent July 2009
Cerium batteries patent December 2009
Electroactive material for charge transport patent January 2012
Fluidic distribution system and related methods patent March 2012
High Energy Density Vanadium Electrolyte Solutions, Methods of Preparation Thereof and All-Vanadium Redox Cells and Batteries Containing High Energy Vanadium Electrolyte Solutions patent-application October 2001
Four-way valve for battery circulation system patent-application December 2001
Pressurre fluctuation prevention tank structure, electrolyte circulation type secondary battery, and redox flow type secondary battery patent-application January 2003
Enzymatic fuel cell patent-application February 2003
Fuel cell with proton conducting membrane patent-application May 2003
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions patent-application July 2003
Fuel-cell based power source having internal series redundancy patent-application November 2003
Electrolyte for redox flow battery, and redox flow battery patent-application September 2004
Fuel cell with proton conducting membrane and with improved water and fuel management patent-application October 2004
Vanadium/polyhalide redox flow battery patent-application November 2004
Vanadium redox battery electrolyte patent-application December 2004
Battery patent-application August 2005
Metal halide redox flow battery patent-application November 2005
Dry particle based electro-chemical device and methods of making same patent-application December 2005
Thin-film cathode for 3-dimensional microbattery and method for preparing such cathode patent-application February 2006
Battery with bifunctional electrolyte patent-application March 2006
Novel vanadium halide redox flow battery patent-application August 2006
Organic fuel cell methods and apparatus patent-application September 2006
Lithium-ion secondary battery and manufacturing method thereof patent-application January 2007
Micromixer Using Integrated Three-Dimensional Porous Structure patent-application April 2008
Multiple metal oxide submicron particles patent-application June 2008
Fuel cell with proton conducting membrane patent-application October 2008
Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries patent-application November 2008
Secondary Battery, Power Supply System Using Same and Usage of Power Supply System patent-application January 2009
Shut-Off Valve Having Two Valve Seats Providing Pressure Equalization patent-application February 2009
Sodium ion based aqueous electrolyte electrochemical secondary energy storage device patent-application October 2009
High Energy Density Redox Flow Device patent-application February 2010
Method of Creating Particle Size Distribution Model, Method of Predicting Degradation of Fuel Cell Catalyst Using the Method of Creating Particle Size Distribution Model, and Method of Controlling Fuel Cell Using the Method of Predicting Degradation of Fuel Cell Catalyst patent-application September 2010
Fuel System Using Redox Flow Battery patent-application December 2010
High Energy Density Redox Flow Device patent-application August 2011
High Energy Density Redox Flow Device patent-application August 2011
Energy Transfer Using Electrochemically Isolated Fluids patent-application November 2011
Stationary, Fluid Redox Electrode patent-application June 2012
Stationary Semi-Solid Battery Module And Method Of Manufacture patent-application March 2013
Semi-Solid Electrode Cell Having A Porous Current Collector And Methods Of Manufacture patent-application March 2013

Similar Records

Semi-solid electrodes having high rate capability
Patent · Tue Nov 28 00:00:00 EST 2017 · OSTI ID:1255928

Semi-solid electrodes having high rate capability
Patent · Tue Jul 05 00:00:00 EDT 2016 · OSTI ID:1255928

Semi-solid electrodes having high rate capability
Patent · Tue Nov 28 00:00:00 EST 2017 · OSTI ID:1255928