The synthesis of PNP-supported low-spin nitro manganese(I) carbonyl complexes

Tondreau, Aaron M.; Boncella, James M.

doi:10.1016/j.poly.2016.04.007

Title: The synthesis of PNP-supported low-spin nitro manganese(I) carbonyl complexes

Journal Article · Thu Sep 01 00:00:00 EDT 2016 · Polyhedron

DOI:https://doi.org/10.1016/j.poly.2016.04.007· OSTI ID:1255273

Tondreau, Aaron M. ^[1]; Boncella, James M. ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

In this study, the coordination chemistry of Mn(CO)₅Br was investigated with a series of PNP-pincer ligands. The ligands ^iPrPONOP (^iPrPONOP = 2,6-bis(diisopropylphosphinito)pyridine) and ^iPrPN^HP (^iPrPN^HP = HN{CH₂CH₂(PiPr₂)}₂) gave the desired organometallic manganese complexes (^iPrPONOP)Mn(CO)₂Br and (^iPrPN^HP)Mn(CO)₂Br, respectively, upon chelation to Mn(CO)₅Br. The reactivity of ^iPrPNNNP (^iPrPNNNP = N,N'-bis(diisopropylphosphino)-2,6-diaminopyridine) with Mn(CO)₅Br yielded a pair of products, [(^iPrPNNNP)Mn(CO)₃][Br] and (^iPrPNNNCO)Mn(CO)₃. The formation of the asymmetric chelate arises from a formal loss of iPr₂PBr and C–N bond formation from a carbonyl ligand and NH, yielding a Mn(I) amide core. The nitration reactions of (^iPrPONOP)Mn(CO)₂Br and (^iPrPN^HP)Mn(CO)₂Br were carried out using silver nitrite, yielding the nitro compounds (^iPrPONOP)Mn(CO)₂(NO₂) and (^iPrPN^HP)Mn(CO)₂(NO₂), respectively. The analogous iron complex (^iPrPONOP)Fe(CO)Cl₂ was nitrated under the same conditions to yield the salt pair [(^iPrPONOP)Fe(CO)₂][FeCl₃NO]. This reactivity underlines the difference between iso-valent iron and manganese centers. The manganese complexes (^iPrPONOP)Mn(CO)₂(NO₂) and (^iPrPN^HP)Mn(CO)₂(NO₂) were ineffective as oxygen atom transfer reagents for a variety of substrates.

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Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1255273

Alternate ID(s):: OSTI ID: 1691771

Report Number(s):: LA-UR-16-20260

Journal Information:: Polyhedron, Journal Name: Polyhedron; ISSN 0277-5387

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 38 works

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