Perspective: The first ten years of broadband chirped pulse Fourier transform microwave spectroscopy

Park, G. Barratt; Field, Robert W.

doi:10.1063/1.4952762

Title: Perspective: The first ten years of broadband chirped pulse Fourier transform microwave spectroscopy

Journal Article · Fri May 27 00:00:00 EDT 2016 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4952762· OSTI ID:1547049

^[1];

^[2]

Gottingen Univ. (Germany); Max Planck Inst. for Biophysical Chemistry, Gottingen (Germany)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Since its invention in 2006, the broadband chirped pulse Fourier transform spectrometer has transformed the field of microwave spectroscopy. The technique enables the collection of a ≥10 GHz bandwidth spectrum in a single shot of the spectrometer, which allows broadband, high-resolution microwave spectra to be acquired several orders of magnitude faster than what was previously possible. We report on the advantages and challenges associated with the technique and look back on the first ten years of chirped pulse Fourier transform spectroscopy. In addition to enabling faster-than-ever structure determination of increasingly complex species, the technique has given rise to an assortment of entirely new classes of experiments, ranging from chiral sensing by three-wave mixing to microwave detection of multichannel reaction kinetics. Yet, this is only the beginning. Future generations of microwave experiments will make increasingly creative use of frequency-agile pulse sequences for the coherent manipulation and interrogation of molecular dynamics.

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Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; National Science Foundation (NSF); American Chemical Society Petroleum Research Fund; USDOE

Grant/Contract Number:: FG02-87ER13671; CHE-1361865; 50650-ND6

OSTI ID:: 1547049

Alternate ID(s):: OSTI ID: 1254676; OSTI ID: 1733334; OSTI ID: 1831800

Journal Information:: Journal of Chemical Physics, Vol. 144, Issue 20; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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