skip to main content

This content will become publicly available on March 22, 2016

Title: Characterization of uranium tetrafluoride (UF4) with Raman spectroscopy

The Raman spectrum of uranium tetrafluoride (UF4) is unambiguously characterized with multiple Raman excitation laser sources for the first time. Across different laser excitation wavelengths, UF4 demonstrates 16 distinct Raman bands within the 50-400 cm-1 region. The observed Raman bands are representative of various F-F vibrational modes. UF4 also shows intense fluorescent bands in the 325 – 750 nm spectral region. Comparison of the UF4 spectrum with the ZrF4 spectrum, its crystalline analog, demonstrates a similar Raman band structure consistent with group theory predictions for expected Raman bands. Additionally, a demonstration of combined scanning electron microscopy (SEM) and in situ Raman spectroscopy microanalytical measurements of UF4 particulates shows that despite the inherent weak intensity of Raman bands, identification and characterization are possible for micron-sized particulates with modern instrumentation. The published well characterized UF4 spectrum is extremely relevant to nuclear materials and nuclear safeguard applications.
 [1] ;  [1]
  1. Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
Publication Date:
OSTI Identifier:
Report Number(s):
Journal ID: ISSN 0377-0486
Grant/Contract Number:
Accepted Manuscript
Journal Name:
Journal of Raman Spectroscopy
Additional Journal Information:
Journal Name: Journal of Raman Spectroscopy; Journal ID: ISSN 0377-0486
Research Org:
Savannah River Site (SRS), Aiken, SC (United States)
Sponsoring Org:
Country of Publication:
United States
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; uranium tetrafluoride; nuclear forensics; in situ SEM/Raman spectroscopy