Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces

Detwiler, Michael D.; Milligan, Cory A.; Zemlyanov, Dmitry Y.; Delgass, W. Nicholas; Ribeiro, Fabio H.

doi:10.1016/j.susc.2015.12.021

Title: Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces

Journal Article · Wed Jun 01 00:00:00 EDT 2016 · Surface Science

DOI:https://doi.org/10.1016/j.susc.2015.12.021· OSTI ID:1252066

Detwiler, Michael D.; Milligan, Cory A.; Zemlyanov, Dmitry Y.; Delgass, W. Nicholas; Ribeiro, Fabio H.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 1252066

Journal Information:: Surface Science, Journal Name: Surface Science Vol. 648 Journal Issue: C; ISSN 0039-6028

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

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Cited by: 13 works

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References (20)

The Vapor Density and some Other Properties of Formic acid Coolidge, Albert Sprague Journal of the American Chemical Society, Vol. 50, Issue 8 https://doi.org/10.1021/ja01395a015	journal	August 1928
Production of CO-free H2 from formic acid. A comparative study of the catalytic behavior of Pt metals on a carbon support Solymosi, F.; Koós, Á.; Liliom, N. Journal of Catalysis, Vol. 279, Issue 1 https://doi.org/10.1016/j.jcat.2011.01.023	journal	April 2011
Turnover Rate and Reaction Orders for the Complete Oxidation of Methane on a Palladium Foil in Excess Dioxygen Monteiro, R. S.; Zemlyanov, D.; Storey, J. M. Journal of Catalysis, Vol. 199, Issue 2 https://doi.org/10.1006/jcat.2001.3176	journal	April 2001
Surface Structures on the Clean Platinum (100) Surface Hagstrom, S.; Lyon, H. B.; Somorjai, G. A. Physical Review Letters, Vol. 15, Issue 11 https://doi.org/10.1103/PhysRevLett.15.491	journal	September 1965
Surface structure change of a [Pt ₄ (µ-CH ₃ COO) ₈ ]/SiO ₂ catalyst active for the decomposition of formic acid Chun, Wang-Jae; Tomishige, Keiichi; Hamakado, Mamiko J. Chem. Soc., Faraday Trans., Vol. 91, Issue 22 https://doi.org/10.1039/FT9959104161	journal	January 1995
Adsorption of formic acid on clean and oxygen covered Pt(111) Avery, Neil R. Applications of Surface Science, Vol. 11-12 https://doi.org/10.1016/0378-5963(82)90120-9	journal	July 1982
Effect of CO on Pt-catalyzed decomposition of formic acid in ultrahigh vacuum Columbia, M. R.; Crabtree, A. M.; Thiel, P. A. Journal of Electroanalytical Chemistry, Vol. 345, Issue 1-2 https://doi.org/10.1016/0022-0728(93)80471-S	journal	February 1993
Surface reaction modification: The effect of structured overlayers of sulfur on the kinetics and mechanism of the decomposition of formic acid on Pt(111) Abbas, N.; Madix, R. J. Applications of Surface Science, Vol. 16, Issue 3-4 https://doi.org/10.1016/0378-5963(83)90084-3	journal	July 1983
Decomposition of acetic acid monomer, acetic acid dimer, and acetic anhydride on Ni(111) Schoofs, Gregory R.; Benziger, Jay B. Surface Science, Vol. 143, Issue 2-3 https://doi.org/10.1016/0039-6028(84)90547-8	journal	August 1984
Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103 Yeh, J. J.; Lindau, I. Atomic Data and Nuclear Data Tables, Vol. 32, Issue 1 https://doi.org/10.1016/0092-640X(85)90016-6	journal	January 1985
Adsorption study of hydrogen on a stepped Pt (997) surface using low energy recoil scattering Koeleman, B. J. J.; de Zwart, S. T.; Boers, A. L. Nuclear Instruments and Methods in Physics Research, Vol. 218, Issue 1-3 https://doi.org/10.1016/0167-5087(83)90983-3	journal	December 1983
Chemisorption of CO on the Pt(111) surface Ertl, G.; Neumann, M.; Streit, K. M. Surface Science, Vol. 64, Issue 2 https://doi.org/10.1016/0039-6028(77)90052-8	journal	May 1977
Formic acid decomposition on Au catalysts: DFT, microkinetic modeling, and reaction kinetics experiments Singh, Suyash; Li, Sha; Carrasquillo-Flores, Ronald AIChE Journal, Vol. 60, Issue 4 https://doi.org/10.1002/aic.14401	journal	February 2014
Energetics of Formic Acid Conversion to Adsorbed Formates on Pt(111) by Transient Calorimetry Silbaugh, Trent L.; Karp, Eric M.; Campbell, Charles T. Journal of the American Chemical Society, Vol. 136, Issue 10 https://doi.org/10.1021/ja412878u	journal	February 2014
Coupled theoretical and experimental analysis of surface coverage effects in Pt-catalyzed NO and O2 reaction to NO2 on Pt(111) Smeltz, A. D.; Getman, R. B.; Schneider, W. F. Catalysis Today, Vol. 136, Issue 1-2 https://doi.org/10.1016/j.cattod.2007.12.139	journal	July 2008
XPS, EM, and Catalytic Studies of the Accumulation of Carbon on Pt Black Rodriguez, N. M.; Anderson, P. E.; Wootsch, A. Journal of Catalysis, Vol. 197, Issue 2 https://doi.org/10.1006/jcat.2000.3081	journal	January 2001
The interaction of CO and Pt(100). II. Energetic and kinetic parameters Thiel, P. A.; Behm, R. J.; Norton, P. R. The Journal of Chemical Physics, Vol. 78, Issue 12 https://doi.org/10.1063/1.444735	journal	June 1983
Trends in Formic Acid Decomposition on Model Transition Metal Surfaces: A Density Functional Theory study Herron, Jeffrey A.; Scaranto, Jessica; Ferrin, Peter ACS Catalysis, Vol. 4, Issue 12 https://doi.org/10.1021/cs500737p	journal	November 2014
Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV Scofield, J. H. Journal of Electron Spectroscopy and Related Phenomena, Vol. 8, Issue 2 https://doi.org/10.1016/0368-2048(76)80015-1	journal	January 1976
Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis Williams, W. Damion; Shekhar, Mayank; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 132, Issue 40 https://doi.org/10.1021/ja1064262	journal	October 2010

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