Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries

Malliakas, Christos D.; Leung, Kevin; Pupek, Krzysztof Z.; Shkrob, Ilya A.; Abraham, Daniel P.

doi:10.1039/c6cp01157h

Title: Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries

Journal Article · Thu Mar 31 00:00:00 EDT 2016 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/c6cp01157h· OSTI ID:1249078

Malliakas, Christos D. ^[1]; Leung, Kevin ^[2]; Pupek, Krzysztof Z. ^[3]; Shkrob, Ilya A. ^[3]; Abraham, Daniel P. ^[3]

Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Fluorinated carbonate solvents are pursued as liquid electrolytes for high-voltage Li-ion batteries. We report aggregation of [Li⁺(FEC)₃]_n polymer species from fluoroethylene carbonate containing electrolytes and scrutinized the causes for this behavior.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC04-94AL85000; SC0001160; AC02-06CH11357

OSTI ID:: 1249078

Report Number(s):: SAND-2016-1267J; PPCPFQ; 619516

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 18, Issue 16; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries Wu, Zhenzhen; Xie, Jian; Xu, Zhichuan J. Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/c8ta11994e	journal	January 2019
Layered Oxide, Graphite and Silicon-Graphite Electrodes for Lithium-Ion Cells: Effect of Electrolyte Composition and Cycling Windows Klett, Matilda; Gilbert, James A.; Pupek, Krzysztof Z. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0131701jes	journal	October 2016

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