Effect of sealing on the morphology of anodized aluminum oxide
Abstract
Ultra-small angle X-ray scattering (USAXS), small-angle neutron scattering (SANS), X-ray reflectometry (XRR) and neutron reflectometry (NR) were used to probe structure evolution induced by sealing of anodized aluminum. While cold nickel acetate sealing and hot-water sealing decrease pore size, these methods do not alter the cylindrical porous framework of the anodic aluminum oxide layer. Hot nickel acetate both fills the pores and deposits on the air surface (air–oxide interface), leading to low porosity and small mean pore radius (39 Å). Finally, electrochemical impedance spectroscopy and direct current polarization show that samples sealed by hot nickel acetate outperform samples sealed by other sealing methods.
- Authors:
-
- Univ. of Cincinnati, OH (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1836473
- Alternate Identifier(s):
- OSTI ID: 1248435
- Grant/Contract Number:
- AC05-00OR22725; W7405-ENG-36; AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Corrosion Science
- Additional Journal Information:
- Journal Volume: 97; Journal ID: ISSN 0010-938X
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; aluminum; x-ray diffraction; EIS; reflectivity; anodic films; interfaces
Citation Formats
Hu, Naiping, Dong, Xuecheng, He, Xueying, Browning, James F., and Schaefer, Dale W. Effect of sealing on the morphology of anodized aluminum oxide. United States: N. p., 2015.
Web. doi:10.1016/j.corsci.2015.03.021.
Hu, Naiping, Dong, Xuecheng, He, Xueying, Browning, James F., & Schaefer, Dale W. Effect of sealing on the morphology of anodized aluminum oxide. United States. https://doi.org/10.1016/j.corsci.2015.03.021
Hu, Naiping, Dong, Xuecheng, He, Xueying, Browning, James F., and Schaefer, Dale W. 2015.
"Effect of sealing on the morphology of anodized aluminum oxide". United States. https://doi.org/10.1016/j.corsci.2015.03.021. https://www.osti.gov/servlets/purl/1836473.
@article{osti_1836473,
title = {Effect of sealing on the morphology of anodized aluminum oxide},
author = {Hu, Naiping and Dong, Xuecheng and He, Xueying and Browning, James F. and Schaefer, Dale W.},
abstractNote = {Ultra-small angle X-ray scattering (USAXS), small-angle neutron scattering (SANS), X-ray reflectometry (XRR) and neutron reflectometry (NR) were used to probe structure evolution induced by sealing of anodized aluminum. While cold nickel acetate sealing and hot-water sealing decrease pore size, these methods do not alter the cylindrical porous framework of the anodic aluminum oxide layer. Hot nickel acetate both fills the pores and deposits on the air surface (air–oxide interface), leading to low porosity and small mean pore radius (39 Å). Finally, electrochemical impedance spectroscopy and direct current polarization show that samples sealed by hot nickel acetate outperform samples sealed by other sealing methods.},
doi = {10.1016/j.corsci.2015.03.021},
url = {https://www.osti.gov/biblio/1836473},
journal = {Corrosion Science},
issn = {0010-938X},
number = ,
volume = 97,
place = {United States},
year = {Wed Jun 10 00:00:00 EDT 2015},
month = {Wed Jun 10 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Evaluation of different sealing methods for anodized aluminum-silicon carbide (Al/SiC) composites using EIS and SEM techniques
journal, November 2007
- Herrera-Hernandez, H.; Vargas-Garcia, J. R.; Hallen-Lopez, J. M.
- Materials and Corrosion, Vol. 58, Issue 11
Characterization of anodized and sealed aluminium by EIS
journal, March 2003
- Suay, J. J.; Giménez, E.; Rodrı́guez, T.
- Corrosion Science, Vol. 45, Issue 3
The influences of sealing methods on corrosion behavior of anodized aluminum alloys in NaCl solutions
journal, March 2003
- Zuo, Yu; Zhao, Peng-Hui; Zhao, Jing-Mao
- Surface and Coatings Technology, Vol. 166, Issue 2-3
Electrochemical self-assembly of porous alumina templates
journal, January 2005
- Sadasivan, V.; Richter, C. P.; Menon, L.
- AIChE Journal, Vol. 51, Issue 2
Corrosion inhibitors for anodised aluminium
journal, July 2013
- Whelan, M.; Barton, K.; Cassidy, J.
- Surface and Coatings Technology, Vol. 227
Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS)
journal, December 2008
- Huang, Yuelong; Shih, Hong; Huang, Huochuan
- Corrosion Science, Vol. 50, Issue 12
On the Growth of Highly Ordered Pores in Anodized Aluminum Oxide
journal, September 1998
- Li, Feiyue; Zhang, Lan; Metzger, Robert M.
- Chemistry of Materials, Vol. 10, Issue 9
Co-refinement of multiple-contrast neutron/X-ray reflectivity data using MOTOFIT
journal, March 2006
- Nelson, Andrew
- Journal of Applied Crystallography, Vol. 39, Issue 2
The duplex nature of anodic barrier films formed on aluminium in aqueous borate and borate-glycol solutions
journal, October 1981
- Shimizu, K.; Thompson, G. E.; Wood, G. C.
- Thin Solid Films, Vol. 85, Issue 1
Evaluation of the properties of anodized aluminum 6061 subjected to thermal cycling treatment using electrochemical impedance spectroscopy (EIS)
journal, October 2009
- Huang, Yuelong; Shih, Hong; Daugherty, John
- Corrosion Science, Vol. 51, Issue 10
Hexagonal pore arrays with a 50–420 nm interpore distance formed by self-organization in anodic alumina
journal, December 1998
- Li, A. P.; Müller, F.; Birner, A.
- Journal of Applied Physics, Vol. 84, Issue 11
A comparative study of corrosion performance of sealed anodized layers of conventionally colored and interference-colored aluminium
journal, June 2012
- Hakimizad, A.; Raeissi, K.; Ashrafizadeh, F.
- Surface and Coatings Technology, Vol. 206, Issue 22
RETRACTED: Cr2O3 Sealing of Anodized Aluminium Alloy by Heat Treatment
journal, January 2011
- Lee, Junghoon; Kim, Yonghwan; Jang, Heuiun
- Procedia Engineering, Vol. 10
Overaging of sealed and unsealed aluminium oxide films
journal, June 1997
- Gonzalez, J. A.; Lopez, V.; Otero, E.
- Corrosion Science, Vol. 39, Issue 6
Self-ordered pore structure of anodized aluminum on silicon and pattern transfer
journal, January 2000
- Crouse, D.; Lo, Yu-Hwa; Miller, A. E.
- Applied Physics Letters, Vol. 76, Issue 1
Sol–gel sealing characteristics for corrosion resistance of anodised aluminium
journal, November 2013
- Whelan, M.; Cassidy, J.; Duffy, B.
- Surface and Coatings Technology, Vol. 235
Comparative studies on corrosion behaviour of sealed aluminium with cerium salt under bidirectional pulse electric field
journal, May 2012
- Zhao, J. M.; Chen, S. L.; Huo, P.
- Corrosion Engineering, Science and Technology, Vol. 47, Issue 3
EIS evolution of anodised aluminium by cerium salt sealing in NaCl solution with exposure time
journal, February 2013
- Zhao, J. M.; Liu, H. X.; Chen, S. L.
- Corrosion Engineering, Science and Technology, Vol. 48, Issue 1
Characterization of aluminum anodized layers modified in sulfuric and phosphoric acid baths and their effect on conventional electrolytic coloring
journal, January 2012
- Hakimizad, A.; Raeissi, K.; Ashrafizadeh, F.
- Surface and Coatings Technology, Vol. 206, Issue 8-9
Evaluation of the scale integrity in the Al2O3/MA956 system at different polarisation by using EIS
journal, July 2001
- García-Alonso, M. C.; Escudero, M. L.; González-Carrasco, J. L.
- Materials and Corrosion, Vol. 52, Issue 7
The sealing of porous anodic oxide films on aluminium
journal, May 1962
- Hoar, T. P.; Wood, G. C.
- Electrochimica Acta, Vol. 7, Issue 3
Self-Ordering of Cell Configuration of Anodic Porous Alumina with Large-Size Pores in Phosphoric Acid Solution
journal, November 1998
- Masuda, Hideki; Yada, Kouichi; Osaka, Atsushi
- Japanese Journal of Applied Physics, Vol. 37, Issue Part 2, No. 11A
Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009
- Ilavsky, Jan; Jemian, Peter R.
- Journal of Applied Crystallography, Vol. 42, Issue 2
Sealing of Anodized Aluminum Alloys with Rare Earth Metal Salt Solutions
journal, August 1998
- Mansfeld, F.; Chen, C.; Breslin, C. B.
- Journal of The Electrochemical Society, Vol. 145, Issue 8
Evaluation of Anodized Aluminum Surfaces with Electrochemical Impedance Spectroscopy
journal, April 1988
- Mansfeld, F.; Kendig, M. W.
- Journal of The Electrochemical Society, Vol. 135, Issue 4
Sealing processes of anodic coatings—Past, present, and future
journal, December 2000
- Hao, Ling; Cheng, B. Rachel
- Metal Finishing, Vol. 98, Issue 12
Self-organized formation of hexagonal pore arrays in anodic alumina
journal, March 1998
- Jessensky, O.; Müller, F.; Gösele, U.
- Applied Physics Letters, Vol. 72, Issue 10
The response of anodized materials sealed in acetate-containing baths to atmospheric exposure
journal, April 1998
- López, V.; González, J. A.; Bautista, A.
- Corrosion Science, Vol. 40, Issue 4-5
Works referencing / citing this record:
Application of experimental design for AA6351 aluminum alloy anodization and coloring
journal, October 2018
- Alves, Guilherme José Turcatel; Maia, Guilherme Arielo Rodrigues; Antunes, Sandra Regina Masetto
- Materials Research Express, Vol. 6, Issue 1
Effect of NaAlO 2 sealing on corrosion resistance of 2024 aluminum alloy anodized film
journal, July 2018
- Yang, Yingshuo; Cheng, Jie; Liu, Shengli
- Materials and Corrosion, Vol. 70, Issue 1
Influence of Concentration and pH of Hexafluorozirconic Acid on Corrosion Resistance of Anodized AA7075-T6
journal, January 2019
- Pinheiro, Jéssica Salles; Regio, Gabriel; Cardoso, Henrique Ribeiro Piaggio
- Materials Research, Vol. 22, Issue suppl 1
The Effect of Electrolyte Temperature and Sealing Solution in Anodizing Operation on Hardness and wear Behavior of 7075 -t6 Aluminum Alloy
journal, February 2019
- Niyazbakhsh, Saeed; Amini, Kamran; Gharavi, Farhad
- Surface Review and Letters, Vol. 26, Issue 02
Effect of concentration of Ce(NO 3 ) 3 · 6H 2 O and temperature on the corrosion resistance of Al 2 O 3 /cerium oxide composite films on 1060 Al alloy
journal, January 2019
- Li, Zeyuan; Ying, Lixia; Jin, Qiu
- Materials and Corrosion, Vol. 70, Issue 7
Nanoparticles deposition effects on 1050A aluminum alloy anodic layers
journal, January 2020
- Gaber, Gh A.; Hussein, W. A.; Ghanem, W. A.
- Materials Research Express, Vol. 7, Issue 1
Corrosion and mechanical properties of plasma electrolytic oxidation‐coated AZ80 magnesium alloy
journal, May 2019
- Pezzato, Luca; Coelho, Leonardo Bertolucci; Bertolini, Rachele
- Materials and Corrosion, Vol. 70, Issue 11
Determination of the dye penetration rate in porous aluminum oxide using Raman spectroscopy
journal, May 2019
- Matijošius, Tadas; Asadauskas, Svajus J.; Bikulčius, Gedvidas
- Coloration Technology, Vol. 135, Issue 4