U.S. Department of EnergyOffice of Scientific and Technical Information
Low-temperature CO oxidation over a ternary oxide catalyst with high resistance to hydrocarbon inhibition
Abstract
Platinum group metal (PGM) catalysts are the current standard for control of pollutants in automotive exhaust streams. Aside from their high cost, PGM catalysts struggle with CO oxidation at low temperatures (<200 °C) due to inhibition by hydrocarbons in exhaust streams. Here we present a ternary mixed oxide catalyst composed of copper oxide, cobalt oxide, and ceria (dubbed CCC) that outperforms synthesized and commercial PGM catalysts for CO oxidation in simulated exhaust streams while showing no signs of inhibition by propene. Diffuse reflectance IR (DRIFTS) and light-off data both indicate low interaction between propene and the CO oxidation active site on this catalyst, and a separation of adsorption sites is proposed as the cause of this inhibition resistance. In conclusion, this catalyst shows great potential as a low-cost component for low temperature exhaust streams that are expected to be a characteristic of future automotive systems.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1247937
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 45; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CO oxidation; emissions control; heterogeneous catalysis; IR spectroscopy; transition metals
Citation Formats
Binder, Andrew J., Toops, Todd J., Unocic, Raymond R., Parks, II, James E., and Dai, Sheng. Low-temperature CO oxidation over a ternary oxide catalyst with high resistance to hydrocarbon inhibition. United States: N. p., 2015.
Web. doi:10.1002/anie.201506093.
Binder, Andrew J., Toops, Todd J., Unocic, Raymond R., Parks, II, James E., & Dai, Sheng. Low-temperature CO oxidation over a ternary oxide catalyst with high resistance to hydrocarbon inhibition. United States. https://doi.org/10.1002/anie.201506093
Binder, Andrew J., Toops, Todd J., Unocic, Raymond R., Parks, II, James E., and Dai, Sheng. 2015.
"Low-temperature CO oxidation over a ternary oxide catalyst with high resistance to hydrocarbon inhibition". United States. https://doi.org/10.1002/anie.201506093. https://www.osti.gov/servlets/purl/1247937.
@article{osti_1247937,
title = {Low-temperature CO oxidation over a ternary oxide catalyst with high resistance to hydrocarbon inhibition},
author = {Binder, Andrew J. and Toops, Todd J. and Unocic, Raymond R. and Parks, II, James E. and Dai, Sheng},
abstractNote = {Platinum group metal (PGM) catalysts are the current standard for control of pollutants in automotive exhaust streams. Aside from their high cost, PGM catalysts struggle with CO oxidation at low temperatures (<200 °C) due to inhibition by hydrocarbons in exhaust streams. Here we present a ternary mixed oxide catalyst composed of copper oxide, cobalt oxide, and ceria (dubbed CCC) that outperforms synthesized and commercial PGM catalysts for CO oxidation in simulated exhaust streams while showing no signs of inhibition by propene. Diffuse reflectance IR (DRIFTS) and light-off data both indicate low interaction between propene and the CO oxidation active site on this catalyst, and a separation of adsorption sites is proposed as the cause of this inhibition resistance. In conclusion, this catalyst shows great potential as a low-cost component for low temperature exhaust streams that are expected to be a characteristic of future automotive systems.},
doi = {10.1002/anie.201506093},
url = {https://www.osti.gov/biblio/1247937},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 45,
volume = 54,
place = {United States},
year = {Fri Sep 11 00:00:00 EDT 2015},
month = {Fri Sep 11 00:00:00 EDT 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 75 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Reactivity controlled compression ignition and conventional diesel combustion: A comparison of methods to meet light-duty NOx and fuel economy targets
journal, June 2013
- Kokjohn, Sage L.; Reitz, Rolf D.
- International Journal of Engine Research, Vol. 14, Issue 5
Reactivity controlled compression ignition combustion on a multi-cylinder light-duty diesel engine
journal, April 2012
- Curran, Scott J.; Hanson, Reed M.; Wagner, Robert M.
- International Journal of Engine Research, Vol. 13, Issue 3
Low-temperature CO oxidation over supported Pt, Pd catalysts: Particular role of FeOx support for oxygen supply during reactions
journal, August 2010
- Liu, Lequan; Zhou, Feng; Wang, Liguo
- Journal of Catalysis, Vol. 274, Issue 1
New Pd/CexZr1−xO2/Al2O3 three-way catalysts prepared by microemulsion
journal, April 2001
- Martı́nez-Arias, A.; Fernández-Garcı́a, M.; Iglesias-Juez, A.
- Applied Catalysis B: Environmental, Vol. 31, Issue 1
Competitive no, co and hydrocarbon oxidation reactions over a diesel oxidation catalyst
journal, October 2011
- AL-Harbi, Meshari; Hayes, Robert; Votsmeier, Martin
- The Canadian Journal of Chemical Engineering, Vol. 90, Issue 6
Strontium-Doped Perovskites Rival Platinum Catalysts for Treating NOx in Simulated Diesel Exhaust
journal, March 2010
- Kim, C. H.; Qi, G.; Dahlberg, K.
- Science, Vol. 327, Issue 5973, p. 1624-1627
Preparation and characterization of CuO/CeO2 catalysts and their applications in low-temperature CO oxidation
journal, November 2005
- Zheng, Xiucheng; Zhang, Xiaoli; Wang, Xiangyu
- Applied Catalysis A: General, Vol. 295, Issue 2
Mesoporous Co3O4–CeO2 and Pd/Co3O4–CeO2 catalysts: Synthesis, characterization and mechanistic study of their catalytic properties for low-temperature CO oxidation
journal, March 2008
- Luo, J.; Meng, M.; Li, X.
- Journal of Catalysis, Vol. 254, Issue 2
Catalytic oxidation of benzene over nanostructured porous Co3O4-CeO2 composite catalysts
journal, December 2011
- Ma, Chunyan; Mu, Zhen; He, Chi
- Journal of Environmental Sciences, Vol. 23, Issue 12
Total oxidation of propene at low temperature over Co3O4–CeO2 mixed oxides: Role of surface oxygen vacancies and bulk oxygen mobility in the catalytic activity
journal, September 2008
- Liotta, L. F.; Ousmane, M.; Di Carlo, G.
- Applied Catalysis A: General, Vol. 347, Issue 1
Identification of the Active Sites for CO and C 3 H 8 Total Oxidation over Nanostructured CuO−CeO 2 and Co 3 O 4 −CeO 2 Catalysts
journal, May 2008
- Luo, Jin-Yong; Meng, Ming; Zha, Yu-Qing
- The Journal of Physical Chemistry C, Vol. 112, Issue 23
Influence of calcination temperature on the structure and catalytic performance of CuOx-CoOy-CeO2 ternary mixed oxide for CO oxidation
journal, January 2013
- Liu, Zhi-Gang; Chai, Song-Hai; Binder, Andrew
- Applied Catalysis A: General, Vol. 451
Origin of Active Oxygen in a Ternary CuO x /Co 3 O 4 –CeO 2 Catalyst for CO Oxidation
journal, November 2014
- Liu, Zhigang; Wu, Zili; Peng, Xihong
- The Journal of Physical Chemistry C, Vol. 118, Issue 48
Identification of CuO Species in High Surface Area CuO−CeO 2 Catalysts and Their Catalytic Activities for CO Oxidation
journal, August 2007
- Luo, Meng-Fei; Song, Yu-Peng; Lu, Ji-Qing
- The Journal of Physical Chemistry C, Vol. 111, Issue 34
Use of noble metals in automobile exhaust catalysts
journal, September 1986
- Kummer, J. T.
- The Journal of Physical Chemistry, Vol. 90, Issue 20
Adsorption of propylene on platinum-group metals
journal, July 1976
- Beketaeva, L. A.; Zakumbaeva, G. D.; Kalanova, Sh. M.
- Reaction Kinetics and Catalysis Letters, Vol. 5, Issue 1
Comparative in Situ DRIFTS-MS Study of 12 CO- and 13 CO-TPR on CuO/CeO 2 Catalyst
journal, May 2009
- Bera, Parthasarathi; Cámara, Antonio López; Hornés, Aitor
- The Journal of Physical Chemistry C, Vol. 113, Issue 24
Kinetic considerations of three-way catalysis in automobile exhaust converters
journal, August 2001
- Botas, Juan A.; Gutiérrez-Ortiz, Miguel A.; González-Marcos, M. Pilar
- Applied Catalysis B: Environmental, Vol. 32, Issue 4
Co3O4 nanocrystals and Co3O4–MOx binary oxides for CO, CH4 and VOC oxidation at low temperatures: a review
journal, January 2013
- Liotta, Leonarda Francesca; Wu, Hongjing; Pantaleo, Giuseppe
- Catalysis Science & Technology, Vol. 3, Issue 12
Comparative Study on Catalytic Performances for Low-temperature CO Oxidation of Cu–Ce–O and Cu–Co–Ce–O Catalysts
journal, April 2008
- Su, Yan; Wang, Shuping; Zhang, Tongying
- Catalysis Letters, Vol. 124, Issue 3-4
Ternary composite oxide catalysts CuO/Co3O4–CeO2 with wide temperature-window for the preferential oxidation of CO in H2-rich stream
journal, December 2013
- Chen, Yena; Liu, Dongsheng; Yang, Lijuan
- Chemical Engineering Journal, Vol. 234
Light-off curve of catalytic reaction and kinetics
journal, March 2002
- Duprat, Françoise
- Chemical Engineering Science, Vol. 57, Issue 6
Mechanism studies of the catalytic oxidation of propylene
journal, December 1964
- Adams, C.
- Journal of Catalysis, Vol. 3, Issue 6
Kinetic Studies as a Method to Differentiate between Oxygen Species Involved in the Oxidation of Propene
journal, March 2000
- Haber, Jerzy; Turek, Wincenty
- Journal of Catalysis, Vol. 190, Issue 2
New Pd/CexZr1−xO2/Al2O3 three-way catalysts prepared by microemulsion
journal, April 2001
- Fernández-Garcı́a, M.; Martı́nez-Arias, A.; Iglesias-Juez, A.
- Applied Catalysis B: Environmental, Vol. 31, Issue 1
Works referencing / citing this record:
Mesoporous Co‐Al oxide nanosheets as highly efficient catalysts for CO oxidation
journal, February 2020
- Zhang, Jian; Wang, Liang; Wu, Zhiyi
- AIChE Journal, Vol. 66, Issue 5
Copper-Cobalt-Cerium Ternary Oxide as an Additive to a Conventional Platinum-Group-Metal Catalyst for Automotive Exhaust Catalysis
journal, February 2018
- Binder, Andrew J.; Toops, Todd J.; Parks, James E.
- ChemCatChem, Vol. 10, Issue 6
Highly Efficient Removal of CO in Effluent Streams from Real‐Life Propane Oxidation Process over CuO−CeO 2 −Based Catalysts
journal, August 2018
- Chu, Wenling; Liu, Yanchun; Wang, Hongkui
- ChemCatChem, Vol. 10, Issue 19
Demonstrating the Potential of Chemiluminescence as a Tool to Characterize Heterogeneous Catalysis Using CO Oxidation on Copper‐Based Catalysts as an Example
journal, April 2019
- Kato, Satoru; Ito, Yoshihiko; Ikuta, Yasuhiro
- ChemCatChem, Vol. 11, Issue 10
Preparation and Characterization of UiO-66-Supported Cu–Ce Bimetal Catalysts for Low-Temperature CO Oxidation
journal, January 2019
- Yu, Jihang; Yu, Jun; Wei, Zhecheng
- Catalysis Letters, Vol. 149, Issue 2
Sensitivity of Three-Way Catalyst Light-Off Temperature to Air-Fuel Ratio
journal, June 2018
- Getsoian, Andrew Bean; Theis, Joseph R.; Lambert, Christine K.
- Emission Control Science and Technology, Vol. 4, Issue 3
Porous hollow manganites with robust composite shells for oxidation of CO at low temperature
journal, January 2016
- Yoo, Jung Bo; Bang, Sora; Kim, Kyungtae
- RSC Advances, Vol. 6, Issue 114
CO oxidation on SnO 2 surfaces enhanced by metal doping
journal, January 2018
- Bae, Junemin; Kim, Jiwhan; Jeong, Hojin
- Catalysis Science & Technology, Vol. 8, Issue 3
Pt NPs immobilized on a N-doped graphene@Al 2 O 3 hybrid support as robust catalysts for low temperature CO oxidation
journal, January 2018
- Jia, Zhimin; Huang, Fei; Diao, Jiangyong
- Chemical Communications, Vol. 54, Issue 79
Litchi-peel-like hierarchical hollow copper-ceria microspheres: aerosol-assisted synthesis and high activity and stability for catalytic CO oxidation
journal, January 2018
- Li, Wenge; Hu, Yanjie; Jiang, Hao
- Nanoscale, Vol. 10, Issue 48
Theoretical investigation of the ORR on boron–silicon nanotubes (B–SiNTs) as acceptable catalysts in fuel cells
journal, January 2019
- Razavi, Razieh; Najafi, Meysam
- RSC Advances, Vol. 9, Issue 54
Gaseous CO and toluene co-oxidation over monolithic core–shell Co 3 O 4 -based hetero-structured catalysts
journal, January 2019
- Mo, Shengpeng; Zhang, Qi; Sun, Yuhai
- Journal of Materials Chemistry A, Vol. 7, Issue 27
Activation of surface lattice oxygen in single-atom Pt/CeO 2 for low-temperature CO oxidation
journal, December 2017
- Nie, Lei; Mei, Donghai; Xiong, Haifeng
- Science, Vol. 358, Issue 6369
Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis
journal, November 2016
- Tang, Wen-Xiang; Gao, Pu-Xian
- MRS Communications, Vol. 6, Issue 04
Deactivation of a Pd/Pt Bimetallic Oxidation Catalyst Used in a Biogas-Powered Euro VI Heavy-Duty Engine Installation
journal, December 2019
- Englund, Johanna; Xie, Kunpeng; Dahlin, Sandra
- Catalysts, Vol. 9, Issue 12
Activating low-temperature diesel oxidation by single-atom Pt on TiO2 nanowire array
journal, February 2020
- Hoang, Son; Guo, Yanbing; Binder, Andrew J.
- Nature Communications, Vol. 11, Issue 1