Strain control of oxygen vacancies in epitaxial strontium cobaltite films

Jeen, Hyoung Jeen; Choi, Woo Seok; Reboredo, Fernando A.; Freeland, John W.; Eres, Gyula; Lee, Ho Nyung; Petrie, Jonathan R.; Mitra, Chandrima; Meyer, Tricia L.

doi:10.1002/adfm.201504868

Title: Strain control of oxygen vacancies in epitaxial strontium cobaltite films

Journal Article · Mon Jan 25 00:00:00 EST 2016 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.201504868· OSTI ID:1246773

Jeen, Hyoung Jeen ^[1]; Choi, Woo Seok ^[1]; Reboredo, Fernando A. ^[1]; Freeland, John W. ^[2]; Eres, Gyula ^[1]; Lee, Ho Nyung ^[1]; Petrie, Jonathan R. ^[1]; Mitra, Chandrima ^[1]; Meyer, Tricia L. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

In this study, the ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at reduced temperatures hinders the deliberate control of important defects, oxygen vacancies. Here, strontium cobaltite (SrCoO_x) is used to demonstrate that epitaxial strain is a powerful tool for manipulating the oxygen vacancy concentration even under highly oxidizing environments and at annealing temperatures as low as 300 °C. By applying a small biaxial tensile strain (2%), the oxygen activation energy barrier decreases by ≈30%, resulting in a tunable oxygen deficient steady-state under conditions that would normally fully oxidize unstrained cobaltite. These strain-induced changes in oxygen stoichiometry drive the cobaltite from a ferromagnetic metal towards an antiferromagnetic insulator. The ability to decouple the oxygen vacancy concentration from its typical dependence on the operational environment is useful for effectively designing oxides materials with a specific oxygen stoichiometry.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1246773

Journal Information:: Advanced Functional Materials, Vol. 26, Issue 10; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 172 works

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References (48)

The value of seeing nothing Mannhart, Jochen; Schlom, Darrell G. Nature, Vol. 430, Issue 7000 https://doi.org/10.1038/430620a	journal	August 2004
Beyond Condensed Matter Physics on the Nanoscale: The Role of Ionic and Electrochemical Phenomena in the Physical Functionalities of Oxide Materials Kalinin, Sergei V.; Borisevich, Albina; Fong, Dillon ACS Nano, Vol. 6, Issue 12 https://doi.org/10.1021/nn304930x	journal	November 2012
Nanoionics: ion transport and electrochemical storage in confined systems Maier, J. Nature Materials, Vol. 4, Issue 11, p. 805-815 https://doi.org/10.1038/nmat1513	journal	November 2005
“Stretching” the energy landscape of oxides—Effects on electrocatalysis and diffusion Yildiz, Bilge MRS Bulletin, Vol. 39, Issue 2 https://doi.org/10.1557/mrs.2014.8	journal	February 2014
Magneto-ionic control of interfacial magnetism Bauer, Uwe; Yao, Lide; Tan, Aik Jun Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4134	journal	November 2014
Room-temperature ferromagnetism observed in undoped semiconducting and insulating oxide thin films Hong, Nguyen Hoa; Sakai, Joe; Poirot, Nathalie Physical Review B, Vol. 73, Issue 13 https://doi.org/10.1103/PhysRevB.73.132404	journal	April 2006
The missing memristor found Strukov, Dmitri B.; Snider, Gregory S.; Stewart, Duncan R. Nature, Vol. 453, Issue 7191 https://doi.org/10.1038/nature06932	journal	May 2008
Suppression of Metal-Insulator Transition in VO2 by Electric Field-Induced Oxygen Vacancy Formation Jeong, J.; Aetukuri, N.; Graf, T. Science, Vol. 339, Issue 6126 https://doi.org/10.1126/science.1230512	journal	March 2013
Possible highT c superconductivity in the Ba?La?Cu?O system Bednorz, J. G.; M�ller, K. A. Zeitschrift f�r Physik B Condensed Matter, Vol. 64, Issue 2 https://doi.org/10.1007/BF01303701	journal	June 1986
Redox-Based Resistive Switching Memories - Nanoionic Mechanisms, Prospects, and Challenges Waser, Rainer; Dittmann, Regina; Staikov, Georgi Advanced Materials, Vol. 21, Issue 25-26, p. 2632-2663 https://doi.org/10.1002/adma.200900375	journal	July 2009
Comparison of the chemical diffusion of undoped and Nb-doped SrTiO₃ Pasierb, P.; Komornicki, S.; Rekas, M. Journal of Physics and Chemistry of Solids, Vol. 60, Issue 11, p. 1835-1844 https://doi.org/10.1016/S0022-3697(99)00193-6	journal	November 1999
Tensile Lattice Strain Accelerates Oxygen Surface Exchange and Diffusion in La _{1– x} Sr _x CoO _3−δ Thin Films Kubicek, Markus; Cai, Zhuhua; Ma, Wen ACS Nano, Vol. 7, Issue 4 https://doi.org/10.1021/nn305987x	journal	April 2013
Electron mobility enhancement in epitaxial multilayer Si‐Si _{1− x} Ge _x alloy films on (100) Si Manasevit, H. M.; Gergis, I. S.; Jones, A. B. Applied Physics Letters, Vol. 41, Issue 5 https://doi.org/10.1063/1.93533	journal	September 1982
Influence of strain and oxygen vacancies on the magnetoelectric properties of multiferroic bismuth ferrite Ederer, Claude; Spaldin, Nicola A. Physical Review B, Vol. 71, Issue 22 https://doi.org/10.1103/PhysRevB.71.224103	journal	June 2005
Doubling the critical temperature of La1.9Sr0.1CuO4 using epitaxial strain Locquet, J. -P.; Perret, J.; Fompeyrine, J. Nature, Vol. 394, Issue 6692 https://doi.org/10.1038/28810	journal	July 1998
Effect of Strain on the Reactivity of Metal Surfaces Mavrikakis, M.; Hammer, B.; Nørskov, J. K. Physical Review Letters, Vol. 81, Issue 13 https://doi.org/10.1103/PhysRevLett.81.2819	journal	September 1998
Strain-Induced Spin States in Atomically Ordered Cobaltites Choi, Woo Seok; Kwon, Ji-Hwan; Jeen, Hyoungjeen Nano Letters, Vol. 12, Issue 9 https://doi.org/10.1021/nl302562f	journal	January 2012
Competing strain effects in reactivity of ${LaCoO}_{3}$ with oxygen Kushima, Akihiro; Yip, Sidney; Yildiz, Bilge Physical Review B, Vol. 82, Issue 11 https://doi.org/10.1103/PhysRevB.82.115435	journal	September 2010
Anisotropic O vacancy formation and diffusion in LaMnO ₃ Gan, Li-Yong; Akande, Salawu Omotayo; Schwingenschlögl, Udo J. Mater. Chem. A, Vol. 2, Issue 46 https://doi.org/10.1039/C4TA04119D	journal	January 2014
Strain-controlled oxygen vacancy formation and ordering in CaMnO $_{3}$ Aschauer, Ulrich; Pfenninger, Reto; Selbach, Sverre M. Physical Review B, Vol. 88, Issue 5 https://doi.org/10.1103/PhysRevB.88.054111	journal	August 2013
Reversible redox reactions in an epitaxially stabilized SrCoOx oxygen sponge Jeen, Hyoungjeen; Choi, Woo Seok; Biegalski, Michael D. Nature Materials, Vol. 12, Issue 11 https://doi.org/10.1038/nmat3736	journal	August 2013
Topotactic Phase Transformation of the Brownmillerite SrCoO _2.5 to the Perovskite SrCoO _3- _δ Jeen, H.; Choi, W. S.; Freeland, J. W. Advanced Materials, Vol. 25, Issue 27 https://doi.org/10.1002/adma.201300531	journal	July 2013
Reversal of the Lattice Structure in ${SrCoO}_{x}$ Epitaxial Thin Films Studied by Real-Time Optical Spectroscopy and First-Principles Calculations Choi, Woo Seok; Jeen, Hyoungjeen; Lee, Jun Hee Physical Review Letters, Vol. 111, Issue 9 https://doi.org/10.1103/PhysRevLett.111.097401	journal	August 2013
Oxygen diffusion pathways in brownmillerite SrCoO _2.5 : Influence of structure and chemical potential Mitra, Chandrima; Meyer, Tricia; Lee, Ho Nyung The Journal of Chemical Physics, Vol. 141, Issue 8 https://doi.org/10.1063/1.4893950	journal	August 2014
Orienting Oxygen Vacancies for Fast Catalytic Reaction Jeen, Hyoungjeen; Bi, Zhonghe; Choi, Woo Seok Advanced Materials, Vol. 25, Issue 44 https://doi.org/10.1002/adma.201302919	journal	October 2013
Thermal and Chemical Expansion of Sr-Doped Lanthanum Cobalt Oxide (La ₁ _- _x Sr _x CoO ₃ _- _δ ) Chemistry of Materials, Vol. 17, Issue 17 https://doi.org/10.1021/cm050905h	journal	August 2005
Time-Resolved in Situ Studies of Oxygen Intercalation into SrCoO_2.5, Performed by Neutron Diffraction and X-ray Absorption Spectroscopy Le Toquin, Ronan; Paulus, Werner; Cousson, Alain Journal of the American Chemical Society, Vol. 128, Issue 40, p. 13161-13174 https://doi.org/10.1021/ja063207m	journal	October 2006
Topotactic Electrochemical Redox Reactions of the Defect Perovskite SrCoO_2.5+x Nemudry, A.; Rudolf, P.; Schollhorn, R. Chemistry of Materials, Vol. 8, Issue 9, p. 2232-2238 https://doi.org/10.1021/cm950504+		September 1996
Finite-size shift of the Curie temperature of ferromagnetic lanthanum cobaltite thin films Fuchs, Dirk; Schwarz, Thorsten; Morán, Oswaldo Physical Review B, Vol. 71, Issue 9 https://doi.org/10.1103/PhysRevB.71.092406	journal	March 2005
Abnormal Poisson's ratio and Linear Compressibility in Perovskite Materials Huang, C. W.; Ren, Wei; Nguyen, Viet Cuong Advanced Materials, Vol. 24, Issue 30 https://doi.org/10.1002/adma.201104676	journal	May 2012
O-K and Co-L XANES Study on Oxygen Intercalation in Perovskite SrCoO_3-δ Karvonen, Lassi; Valkeapaa, Markus; Liu, Ru-Shi Chemistry of Materials, Vol. 22, Issue 1, p. 70-76 https://doi.org/10.1021/cm9021563	journal	January 2010
Spin State of Negative Charge-Transfer Material ${SrCoO}_{3}$ Kuneš, J.; Křápek, V.; Parragh, N. Physical Review Letters, Vol. 109, Issue 11 https://doi.org/10.1103/PhysRevLett.109.117206	journal	September 2012
Specific-heat evidence of strong electron correlations and thermoelectric properties of the ferromagnetic perovskite $Sr Co O_{3 - δ}$ Balamurugan, S.; Yamaura, K.; Karki, A. Physical Review B, Vol. 74, Issue 17, Article No. 172406 https://doi.org/10.1103/PhysRevB.74.172406	journal	November 2006
Difference in spin state and covalence between La1−Sr CoO3 and La2−Sr Li0.5Co0.5O4 Hu, Z.; Grazioli, C.; Knupfer, M. Journal of Alloys and Compounds, Vol. 343, Issue 1-2 https://doi.org/10.1016/S0925-8388(02)00004-X	journal	September 2002
Coupled Magnetic-Ferroelectric Metal-Insulator Transition in Epitaxially Strained ${SrCoO}_{3}$ from First Principles Lee, Jun Hee; Rabe, Karin Physical Review Letters, Vol. 107, Issue 6, Article No. 067601 https://doi.org/10.1103/PhysRevLett.107.067601	journal	August 2011
Magnetic phase separation in SrCoO_x (2.5 ≤ x ≤ 3) Xie, C.; Nie, Y.; Wells, B. Applied Physics Letters, Vol. 99, Issue 5, Article No. 052503 https://doi.org/10.1063/1.3622644	journal	August 2011
Theoretical Investigation of the Activity of Cobalt Oxides for the Electrochemical Oxidation of Water Bajdich, Michal; García-Mota, Mónica; Vojvodic, Aleksandra Journal of the American Chemical Society, Vol. 135, Issue 36 https://doi.org/10.1021/ja405997s	journal	August 2013
Discrepancies between infrared and dc resistivities of ${La}_{0.7}$ ${Ca}_{0.3}$ ${MnO}_{3}$ samples Kim, K. H.; Gu, J. Y.; Choi, H. S. Physical Review B, Vol. 55, Issue 7 https://doi.org/10.1103/PhysRevB.55.4023	journal	February 1997
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points Henkelman, Graeme; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22 https://doi.org/10.1063/1.1323224	journal	December 2000
A climbing image nudged elastic band method for finding saddle points and minimum energy paths Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904 https://doi.org/10.1063/1.1329672	journal	December 2000
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y. Physical Review B, Vol. 57, Issue 3, p. 1505-1509 https://doi.org/10.1103/PhysRevB.57.1505	journal	January 1998
Chemical potential dependence of defect formation energies in GaAs: Application to Ga self-diffusion Zhang, S.; Northrup, John Physical Review Letters, Vol. 67, Issue 17 https://doi.org/10.1103/PhysRevLett.67.2339	journal	October 1991
Voltage- and time-dependent valence state transition in cobalt oxide catalysts during the oxygen evolution reaction Zhou, Jing; Zhang, Linjuan; Huang, Yu-Cheng Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15925-2	journal	April 2020
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-58835-5	journal	February 2020
Strain-controlled oxygen vacancy formation and ordering in CaMnO₃ Spaldin, Nicola A.; Grande, Tor; Selbach, Sverre M. American Physical Society https://doi.org/10.7892/boris.72980	text	January 2013
Orienting oxygen vacancies for fast catalytic reaction Jeen, Hyoungjeen; Bi, Zhonghe; Choi, Woo Seok arXiv https://doi.org/10.48550/arxiv.1310.0984	text	January 2013
Oxygen diffusion pathways in brownmillerite SrCoO2.5: Influence of structure and chemical potential Mitra, Chandrima; Meyer, Tricia; Lee, Ho Nyung arXiv https://doi.org/10.48550/arxiv.1408.7077	text	January 2014

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