Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes

Goldman, Alan; Ahuja, Ritu; Schinski, William

Title: Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes

Patent · Tue Apr 05 00:00:00 EDT 2016

OSTI ID:1245597

Goldman, Alan; Ahuja, Ritu; Schinski, William

The invention provides methods and compositions useful for synthesizing alkylaromatics from an n-alkanes.

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Research Organization:: Rutgers, The State Univ. of New Jersey, New Brunswick, NJ (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-93ER14353

Assignee:: Rutgers, The State University of New Jersey (New Brunswick, NJ)

Patent Number(s):: 9,302,954

Application Number:: 13/657,723

OSTI ID:: 1245597

Resource Relation:: Patent File Date: 2012 Oct 22

Country of Publication:: United States

Language:: English

References (10)

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Comparative studies of dehydrocyclization of n-octane and iso-octane on bifunctional and monofunctional Pt/Al₂O₃ catalysts Ako, Churchill T.; Susu, Alfred A. Chemical Engineering & Technology, Vol. 16, Issue 1, p. 10-16 https://doi.org/10.1002/ceat.270160103	journal	February 1993
Hydrogen Storage in Microporous Metal-Organic Frameworks Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed Science, Vol. 300, Issue 5622, p. 1127-1129 https://doi.org/10.1126/science.1083440	journal	May 2003
Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes Ahuja, Ritu; Punji, Benudhar; Findlater, Michael Nature Chemistry, Vol. 3, Issue 2 https://doi.org/10.1038/nchem.946	journal	December 2010
Thermodynamic Properties for Solution of Hydrogen in Palladium-Based Binary Alloys Sakamoto, Y.; Chen, F. L.; Ura, M. Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 99, Issue 6, p. 807-820 https://doi.org/10.1002/bbpc.19950990605	journal	June 1995
Highly Effective Pincer-Ligated Iridium Catalysts for Alkane Dehydrogenation. DFT Calculations of Relevant Thermodynamic, Kinetic, and Spectroscopic Properties Zhu, Keming; Achord, Patrick D.; Zhang, Xiawei Journal of the American Chemical Society, Vol. 126, Issue 40 https://doi.org/10.1021/ja047356l	journal	October 2004
Membrane reactors for hydrogenation and dehydrogenation processes based on supported palladium Dittmeyer, Roland; Höllein, Volker; Daub, Kristian Journal of Molecular Catalysis A: Chemical, Vol. 173, Issue 1-2, p. 135-184 https://doi.org/10.1016/S1381-1169(01)00149-2	journal	September 2001
Water-Tolerant Solid Acid Catalysts Okuhara, Toshio Chemical Reviews, Vol. 102, Issue 10 https://doi.org/10.1021/cr0103569	journal	October 2002
Periphery-functionalized organometallic dendrimers for homogeneous catalysis van Koten, Gerard; Jastrzebski, Johann T. B. H. Journal of Molecular Catalysis A: Chemical, Vol. 146, Issue 1-2, p. 317-323 https://doi.org/10.1016/S1381-1169(99)00091-6	journal	October 1999
Ligand exchanges and selective catalytic hydrogenation in molecular single crystals Huang, Zheng; White, Peter S.; Brookhart, Maurice Nature, Vol. 465, Issue 7298 https://doi.org/10.1038/nature09085	journal	June 2010

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