Bio-inspired Iron Catalysts for Hydrocarbon Oxidations
Stereoselective oxidation of C–H and C=C bonds are catalyzed by nonheme iron enzymes. Inspired by these bioinorganic systems, our group has been exploring the use of nonheme iron complexes as catalysts for the oxidation of hydrocarbons using H2O2 as an environmentally friendly and atom-efficient oxidant in order to gain mechanistic insights into these novel transformations. In particular, we have focused on clarifying the nature of the high-valent iron oxidants likely to be involved in these transformations.
- Publication Date:
- OSTI Identifier:
- Report Number(s):
- DOE Contract Number:
- Resource Type:
- Technical Report
- Resource Relation:
- Related Information: Oloo, W. N.; Que, L., Jr., "Hydrocarbon Oxidations Catalyzed by Bio-Inspired Nonheme Iron and Copper Catalysts.” In Comprehensive Inorganic Chemistry II; Reedijk, J., Poeppelmeier, K., Eds.; Elsevier: Oxford, 2013; Vol. 6, pp 763-778.
- Research Org:
- Univ. of Minnesota, Minneapolis, MN (United States)
- Sponsoring Org:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Country of Publication:
- United States
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY nonheme iron catalysts; oxygen activation; alkane hydroxylation; olefin epoxidation; olefin cis-dihydroxylation
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