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Title: Stabilization of highly polar BiFeO3-like structure: a new interface design route for enhanced ferroelectricity in artificial perovskite superlattices

In ABO3 perovskites, oxygen octahedron rotations are common structural distortions that can promote large ferroelectricity in BiFeO3 with an R3c structure [1] but suppress ferroelectricity in CaTiO3 with a Pbnm symmetry [2]. For many CaTiO3-like perovskites, the BiFeO3 structure is a metastable phase. Here, we report the stabilization of the highly polar BiFeO3-like phase of CaTiO3 in a BaTiO3/CaTiO3 superlattice grown on a SrTiO3 substrate. The stabilization is realized by a reconstruction of oxygen octahedron rotations at the interface from the pattern of nonpolar bulk CaTiO3 to a different pattern that is characteristic of a BiFeO3 phase. The reconstruction is interpreted through a combination of amplitude-contrast sub-0.1-nm high-resolution transmission electron microscopy and first-principles theories of the structure, energetics, and polarization of the superlattice and its constituents. We further predict a number of new artificial ferroelectric materials demonstrating that nonpolar perovskites can be turned into ferroelectrics via this interface mechanism. Therefore, a large number of perovskites with the CaTiO3 structure type, which include many magnetic representatives, are now good candidates as novel highly polar multiferroic materials [3].
Authors:
 [1] ;  [2] ;  [2] ;  [3] ;  [4] ;  [3] ;  [1]
  1. Temple Univ, Philadelphia, PA (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Rutgers Univ., New Brunswick, NJ (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
OSTI Identifier:
1241453
Grant/Contract Number:
AC05-00OR22725; SC0012575; AC02-05CH11231; AC02-06CH11357
Type:
Published Article
Journal Name:
Physical Review. X
Additional Journal Information:
Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2160-3308
Publisher:
American Physical Society
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE