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Title: Highly luminescent and color-tunable salicylate ionic liquids

Abstract

High quantum yields of up to 40.5 % can be achieved in salicylate-bearing ionic liquids. A range of these ionic liquids have been synthesized and their photoluminescent properties studied in detail. The differences noted can be related back to the structure of the ionic liquid cation and possible interionic interactions. It is found that shifts of emission, particularly in the pyridinium-based ionic liquids, can be related to cation–anion pairing interactions. Furthermore, facile and controlled emission color mixing is demonstrated through combining different ILs, with emission colors ranging from blue to yellow.

Authors:
 [1];  [1];  [1];  [2];  [3]
  1. Ruhr-Univ. Bochum, Bochum (Germany)
  2. Ruhr-Univ. Bochum, Bochum (Germany); Univ. of Wroclaw, Wroclaw (Poland)
  3. Ruhr-Univ. Bochum, Bochum (Germany); Ames Lab., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1240911
Report Number(s):
IS-J-8344
Journal ID: ISSN 0947-6539
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Volume: 20; Journal Issue: 16; Journal ID: ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; photoluminescence; ionic liquids; salicylate

Citation Formats

Campbell, Paul S., Yang, Mei, Pitz, Demian, Cybinska, Joanna, and Mudring, Anja -Verena. Highly luminescent and color-tunable salicylate ionic liquids. United States: N. p., 2014. Web. doi:10.1002/chem.201301363.
Campbell, Paul S., Yang, Mei, Pitz, Demian, Cybinska, Joanna, & Mudring, Anja -Verena. Highly luminescent and color-tunable salicylate ionic liquids. United States. https://doi.org/10.1002/chem.201301363
Campbell, Paul S., Yang, Mei, Pitz, Demian, Cybinska, Joanna, and Mudring, Anja -Verena. 2014. "Highly luminescent and color-tunable salicylate ionic liquids". United States. https://doi.org/10.1002/chem.201301363. https://www.osti.gov/servlets/purl/1240911.
@article{osti_1240911,
title = {Highly luminescent and color-tunable salicylate ionic liquids},
author = {Campbell, Paul S. and Yang, Mei and Pitz, Demian and Cybinska, Joanna and Mudring, Anja -Verena},
abstractNote = {High quantum yields of up to 40.5 % can be achieved in salicylate-bearing ionic liquids. A range of these ionic liquids have been synthesized and their photoluminescent properties studied in detail. The differences noted can be related back to the structure of the ionic liquid cation and possible interionic interactions. It is found that shifts of emission, particularly in the pyridinium-based ionic liquids, can be related to cation–anion pairing interactions. Furthermore, facile and controlled emission color mixing is demonstrated through combining different ILs, with emission colors ranging from blue to yellow.},
doi = {10.1002/chem.201301363},
url = {https://www.osti.gov/biblio/1240911}, journal = {Chemistry - A European Journal},
issn = {0947-6539},
number = 16,
volume = 20,
place = {United States},
year = {Tue Mar 11 00:00:00 EDT 2014},
month = {Tue Mar 11 00:00:00 EDT 2014}
}

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Free Publicly Available Full Text
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Cited by: 33 works
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Works referencing / citing this record:

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