Highly luminescent and color-tunable salicylate ionic liquids
Abstract
High quantum yields of up to 40.5 % can be achieved in salicylate-bearing ionic liquids. A range of these ionic liquids have been synthesized and their photoluminescent properties studied in detail. The differences noted can be related back to the structure of the ionic liquid cation and possible interionic interactions. It is found that shifts of emission, particularly in the pyridinium-based ionic liquids, can be related to cation–anion pairing interactions. Furthermore, facile and controlled emission color mixing is demonstrated through combining different ILs, with emission colors ranging from blue to yellow.
- Authors:
-
- Ruhr-Univ. Bochum, Bochum (Germany)
- Ruhr-Univ. Bochum, Bochum (Germany); Univ. of Wroclaw, Wroclaw (Poland)
- Ruhr-Univ. Bochum, Bochum (Germany); Ames Lab., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1240911
- Report Number(s):
- IS-J-8344
Journal ID: ISSN 0947-6539
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 20; Journal Issue: 16; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; photoluminescence; ionic liquids; salicylate
Citation Formats
Campbell, Paul S., Yang, Mei, Pitz, Demian, Cybinska, Joanna, and Mudring, Anja -Verena. Highly luminescent and color-tunable salicylate ionic liquids. United States: N. p., 2014.
Web. doi:10.1002/chem.201301363.
Campbell, Paul S., Yang, Mei, Pitz, Demian, Cybinska, Joanna, & Mudring, Anja -Verena. Highly luminescent and color-tunable salicylate ionic liquids. United States. https://doi.org/10.1002/chem.201301363
Campbell, Paul S., Yang, Mei, Pitz, Demian, Cybinska, Joanna, and Mudring, Anja -Verena. 2014.
"Highly luminescent and color-tunable salicylate ionic liquids". United States. https://doi.org/10.1002/chem.201301363. https://www.osti.gov/servlets/purl/1240911.
@article{osti_1240911,
title = {Highly luminescent and color-tunable salicylate ionic liquids},
author = {Campbell, Paul S. and Yang, Mei and Pitz, Demian and Cybinska, Joanna and Mudring, Anja -Verena},
abstractNote = {High quantum yields of up to 40.5 % can be achieved in salicylate-bearing ionic liquids. A range of these ionic liquids have been synthesized and their photoluminescent properties studied in detail. The differences noted can be related back to the structure of the ionic liquid cation and possible interionic interactions. It is found that shifts of emission, particularly in the pyridinium-based ionic liquids, can be related to cation–anion pairing interactions. Furthermore, facile and controlled emission color mixing is demonstrated through combining different ILs, with emission colors ranging from blue to yellow.},
doi = {10.1002/chem.201301363},
url = {https://www.osti.gov/biblio/1240911},
journal = {Chemistry - A European Journal},
issn = {0947-6539},
number = 16,
volume = 20,
place = {United States},
year = {Tue Mar 11 00:00:00 EDT 2014},
month = {Tue Mar 11 00:00:00 EDT 2014}
}
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