Magnetostructural phase transformations in Tb 1-x Mn 2

Zou, Junding; Paudyal, Durga; Liu, Jing; Mudryk, Yaroslav; Pecharsky, Vitalij K.; Gschneidner, Karl A.

doi:10.1039/C4TC02506G

Title: Magnetostructural phase transformations in Tb _1-x Mn ₂

Journal Article · Fri Jan 16 00:00:00 EST 2015 · Journal of Materials Chemistry C

DOI:https://doi.org/10.1039/C4TC02506G· OSTI ID:1239833

Zou, Junding ^[1]; Paudyal, Durga ^[2]; Liu, Jing ^[3]; Mudryk, Yaroslav ^[2]; Pecharsky, Vitalij K. ^[3]; Gschneidner, Karl A. ^[3]

Zhejiang Univ., Hangzhou (China); Ames Lab., Ames, IA (United States)
Ames Lab., Ames, IA (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

Magnetism and phase transformations in non-stoichiometric Tb_1-xMn₂ (x = 0.056, 0.039) have been studied as functions of temperature and magnetic field using magnetization, heat capacity, and X-ray powder diffraction measurements. Lowering the temperature, the compounds sequentially order ferrimagnetically and antiferromagnetically, and finally, exhibit spin reorientation transitions. Moreover, these structural distortions from room temperature cubic to low temperature rhombohedral structures occur at T_N, and are accompanied by large volume changes reaching ~-1.27% and -1.42%, respectively. First principles electronic structure calculations confirm the phase transformation from the ferrimagnetic cubic structure to the antiferromagnetic rhombohedral structure in TbMn₂.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Ames Lab., Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1239833

Report Number(s):: IS-J 8909; JMCCCX

Journal Information:: Journal of Materials Chemistry C, Vol. 3, Issue 10; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

References (32)

Giant negative magnetoresistance in perovskitelike ${La}_{2 / 3}$ ${Ba}_{1 / 3}$ ${MnO}_{x}$ ferromagnetic films von Helmolt, R.; Wecker, J.; Holzapfel, B. Physical Review Letters, Vol. 71, Issue 14 https://doi.org/10.1103/PhysRevLett.71.2331	journal	October 1993
Thousandfold Change in Resistivity in Magnetoresistive La-Ca-Mn-O Films Jin, S.; Tiefel, T. H.; McCormack, M. Science, Vol. 264, Issue 5157 https://doi.org/10.1126/science.264.5157.413	journal	April 1994
Giant magnetocaloric effect of MnAs1−xSbx Wada, H.; Tanabe, Y. Applied Physics Letters, Vol. 79, Issue 20 https://doi.org/10.1063/1.1419048	journal	November 2001
Giant magnetocaloric effect and soft-mode magneto-structural phase transition in MnAs Zou, J. D.; Wada, H.; Shen, B. G. EPL (Europhysics Letters), Vol. 81, Issue 4 https://doi.org/10.1209/0295-5075/81/47002	journal	January 2008
Transition-metal-based magnetic refrigerants for room-temperature applications Tegus, O.; Brück, E.; Buschow, K. H. J. Nature, Vol. 415, Issue 6868 https://doi.org/10.1038/415150a	journal	January 2002
Large reversible magnetocaloric effect in RMn2 (R=Tb, Dy, Ho, Er) compounds Zuo, Wenliang; Hu, Fengxia; Sun, Jirong Journal of Alloys and Compounds, Vol. 575 https://doi.org/10.1016/j.jallcom.2013.03.185	journal	October 2013
Percolative phase separation underlies colossal magnetoresistance in mixed-valent manganites Uehara, M.; Mori, S.; Chen, C. H. Nature, Vol. 399, Issue 6736 https://doi.org/10.1038/21142	journal	June 1999
Frustration-induced vanishing of magnetic moments in R ${Mn}_{2}$ systems Ballou, R.; Lacroix, C.; Nunez Regueiro, M. D. Physical Review Letters, Vol. 66, Issue 14 https://doi.org/10.1103/PhysRevLett.66.1910	journal	April 1991
Magnetism and spin fluctuations of laves phase manganese compounds Shiga, M. Physica B+C, Vol. 149, Issue 1-3 https://doi.org/10.1016/0378-4363(88)90256-2	journal	March 1988
Magnetic Properties of C14-Laves Phase RMn ₂ Inoue, Kazuko; Nakamura, Yoji; Tsvyashchenko, A. V. Journal of the Physical Society of Japan, Vol. 64, Issue 6 https://doi.org/10.1143/JPSJ.64.2175	journal	June 1995
Magnetism and thermal expansion anomaly of RMn2 (R=Y, Gd, Tb, Ho and Er Shiga, M.; Wada, H.; Nakamura, Y. Journal of Magnetism and Magnetic Materials, Vol. 31-34 https://doi.org/10.1016/0304-8853(83)90179-8	journal	February 1983
Magnetovolume effects in Laves phase intermetallic compounds Nakamura, Y. Journal of Magnetism and Magnetic Materials, Vol. 31-34 https://doi.org/10.1016/0304-8853(83)90702-3	journal	February 1983
X-Ray Study of Crystal Distortions in RMn ₂ Compounds (R: Y, Pr, Nd, Sm and Gd) Tagawa, Yukiharu; Sakurai, Junji; Komura, Yukitomo Journal of the Physical Society of Japan, Vol. 54, Issue 2 https://doi.org/10.1143/JPSJ.54.591	journal	February 1985
On the nature of the phase transition in YMn2 Gaidukova, I. Y. U.; Kelarev, V. V.; Markosyan, A. S. Journal of Magnetism and Magnetic Materials, Vol. 72, Issue 3 https://doi.org/10.1016/0304-8853(88)90234-X	journal	April 1988
Study of the Mn-moment instability in the TbMn2 intermetallic compound by substitutions of Fe for Mn Ballou, R.; Gaydukova, I. Yu.; Markosyan, A. S. Journal of Magnetism and Magnetic Materials, Vol. 104-107 https://doi.org/10.1016/0304-8853(92)90665-B	journal	February 1992
Giant field induced volume magnetostriction in TbMn2 cubic intermetallic compound Ibarra, M. R.; Marquina, C.; García-Orza, L. Solid State Communications, Vol. 87, Issue 8 https://doi.org/10.1016/0038-1098(93)90208-5	journal	August 1993
Field induced first order magnetic transition and associated volume effect in TbMn2 Lelièvre-Berna, E.; Rouchy, J.; Ballou, R. Journal of Magnetism and Magnetic Materials, Vol. 137, Issue 1-2 https://doi.org/10.1016/0304-8853(94)90182-1	journal	October 1994
On the instability of the Mn magnetic moment under applied magnetic field in TbMn2 Marquina, C.; Ibarra, M. R.; de la Fuente, C. Journal of Magnetism and Magnetic Materials, Vol. 140-144 https://doi.org/10.1016/0304-8853(94)01484-1	journal	February 1995
Magnetic and thermal properties of TbMn2 and Tb(Mn1 − xA1x)2 compounds Shiga, M.; Wada, H. Journal of Magnetism and Magnetic Materials, Vol. 151, Issue 1-2 https://doi.org/10.1016/0304-8853(95)00329-0	journal	November 1995
Electronic structure of ${YMn}_{2}$ and $Y_{0.96} {Lu}_{0.04} {Mn}_{2}$ studied by x-ray emission spectroscopy Yamaoka, Hitoshi; Tsujii, Naohito; Jarrige, Ignace Physical Review B, Vol. 80, Issue 11 https://doi.org/10.1103/PhysRevB.80.115110	journal	September 2009
NMR Study of Magnetic State of RMn ₂ Intermetallic Compounds. II. R=Heavy Rare-Earth Yoshimura, Kazuyoshi; Shiga, Masayuki; Nakamura, Yoji Journal of the Physical Society of Japan, Vol. 55, Issue 10 https://doi.org/10.1143/JPSJ.55.3585	journal	October 1986
Low temperature structural distortions in RMn2 compounds Mondal, S.; Cywinski, R.; Kilcoyne, S. H. Physica B: Condensed Matter, Vol. 180-181 https://doi.org/10.1016/0921-4526(92)90409-L	journal	June 1992
Specific heat of TbMn2(H,D)2 Tarnawski, Z.; Kolwicz-Chodak, L.; Figiel, H. Physica B: Condensed Matter, Vol. 355, Issue 1-4 https://doi.org/10.1016/j.physb.2004.10.092	journal	January 2005
X-ray powder diffractometer for in situ structural studies in magnetic fields from 0 to 35 kOe between 2.2 and 315 K Holm, Aaron Patrick; Pecharsky, Vitalij K.; Gschneidner, Karl A. Review of Scientific Instruments, Vol. 75, Issue 4 https://doi.org/10.1063/1.1667253	journal	April 2004
Structural characterization of RNi2 (R ≡ La, Ce) intermetallic compounds and their hydrides Paul-Boncour, V.; Percheron-Guegan, A.; Diaf, M. Journal of the Less Common Metals, Vol. 131, Issue 1-2 https://doi.org/10.1016/0022-5088(87)90518-2	journal	March 1987
A geometric analysis of solubility ranges in Laves phases Thoma, D. J.; Perepezko, J. H. Journal of Alloys and Compounds, Vol. 224, Issue 2 https://doi.org/10.1016/0925-8388(95)01557-4	journal	July 1995
Magnetic and structural studies of rare earth-iron-manganese laves phase ternaries II Ilyushin, A. S.; Wallace, W. E. Journal of Solid State Chemistry, Vol. 17, Issue 4 https://doi.org/10.1016/S0022-4596(76)80005-9	journal	January 1976
NMR Study in Magnetically Ordered State of Rare Earth-Manganese Laves Phase Compounds Shimizu, Kenji Journal of the Physical Society of Japan, Vol. 54, Issue 3 https://doi.org/10.1143/JPSJ.54.1154	journal	March 1985
Magnetic properties of the TbMn2 single crystals Talik, E.; Kulpa, M.; Mydlarz, T. Physica B: Condensed Matter, Vol. 271, Issue 1-4 https://doi.org/10.1016/S0921-4526(99)00206-9	journal	November 1999
Magnetic and structural transitions in ${Dy}_{5} {Si}_{3} Ge$ Nirmala, R.; Mudryk, Ya.; Pecharsky, V. K. Physical Review B, Vol. 76, Issue 10 https://doi.org/10.1103/PhysRevB.76.104417	journal	September 2007
Magnetic and magnetocaloric properties of R6Mn23 (R=Y, Nd, Sm, Gd-Tm, Lu) compounds Lemoine, P.; Vernière, A.; Mazet, T. Journal of Magnetism and Magnetic Materials, Vol. 323, Issue 21 https://doi.org/10.1016/j.jmmm.2011.06.012	journal	November 2011
Explicit, First-Principles Tight-Binding Theory Andersen, O. K.; Jepsen, O. Physical Review Letters, Vol. 53, Issue 27 https://doi.org/10.1103/PhysRevLett.53.2571	journal	December 1984

Cited By (1)

High field induced magnetic transitions in the $Y_{0.7} E r_{0.3} F e_{2} D_{4.2}$ deuteride Paul-Boncour, V.; Guillot, M.; Isnard, O. Physical Review B, Vol. 96, Issue 10 https://doi.org/10.1103/physrevb.96.104440	journal	September 2017

Similar Records

Anisotropy induced anomalies in Dy_1$-$xTb_xAl₂

Journal Article · Mon Jan 02 00:00:00 EST 2017 · Journal of Materials Chemistry. C · OSTI ID:1239833

Khan, M.; Pathak, A. K.; Mudryk, Y.; +1 more

Magnetic structures and magnetic phase diagram of Nd{sub x}Tb{sub 1{minus}x}Mn{sub 2}Ge{sub 2}

Journal Article · Thu May 01 00:00:00 EDT 1997 · Physical Review, B: Condensed Matter · OSTI ID:1239833

Morellon, L; Algarabel, P A; Ibarra, M R; +1 more

Spin reorientation and magnetoelastic coupling in Tb₆Fe_1-xCo_xBi₂ (x = 0, 0.125, 0.25, 0.375) alloy system

Journal Article · Sat Jul 05 00:00:00 EDT 2014 · Journal of Alloys and Compounds · OSTI ID:1239833

Koehler, Michael R.; Garlea, Vasile O.; McGuire, Michael A.; +2 more

Related Subjects

36 MATERIALS SCIENCE

Title: Magnetostructural phase transformations in Tb 1-x Mn 2

Citation Formats

References (32)

Cited By (1)

Similar Records

Related Subjects

Title: Magnetostructural phase transformations in Tb _1-x Mn ₂